Theoretical prediction of the host–guest interactions between novel photoresponsive nanorings and C60: A strategy for facile encapsulation and release of fullerene

A series of photoresponsive‐group‐containing nanorings hosts with 12～14 Å in diameter is designed by introducing different number of azo groups as the structural composition units. And the host–guest interactions between fullerene C₆₀ and those nanoring hosts were investigated theoretically at M06‐2X/6‐31G(d)//M06‐L/MIDI! and wB97X‐D/6‐31G(d) levels. Analysis on geometrical characteristics and host–guest binding energies revealed that the designed nanoring molecule (labeled as 7 ) which is composed by seven azo groups and seven phenyls is the most feasible host for encapsulation of C₆₀ guest among all candidates. Moreover, inferring from the simulated UV‐vis‐NIR spectroscopy, the C₆₀ guest could be facilely released from the cavity of the host 7 via configuration transformation between trans‐form and cis‐form of the host under the 563 nm photoirradiation. Additionally, the frontier orbital features, weak interaction regions, infrared, and NMR spectra of the C₆₀@7 host–guest complex have also been investigated theoretically. © 2015 Wiley Periodicals, Inc.     

On Some Properties of $c$-Frames

In this paper we discuss about $c$-frames, namely continuous frames. Since, $c$-frames are generalizations of discrete frames, we generalize some results of discrete frames to continuous version. We explain some results about relations of projections in Hilbert spaces and $c$-frames to characterize these frames. Also, we will specify (precisely) the synthesis and frame operators of Bochner integrable $c$-frames. Finally, we classify Hilbert-Schmidt operators by $c$-frames and express some new identities for Parseval $c$-frames.     

NORM RETRIEVAL BY PROJECTIONS ON INFINITE-DIMENSIONAL HILBERT SPACES

We study the norm retrieval by projections on an infinite-dimensional Hilbert space H. Let {e_i}_(i∈I)be an orthonormal basis in H and W_i= {e_i}~⊥for all i ∈ I. We show that {W_i}_(i∈I)does norm retrieval if and only if I is an infinite subset of N. We also give some properties of norm retrieval by projections.     

Flag Hilbert schemes and moduli spaces of torsion plane sheaves

We find certain relations between flag Hilbert schemes of points on plane curves and moduli spaces of one-dimensional plane sheaves. We show that some of these moduli spaces are stably rational.     

基于Hilbert变换的LFM检测与估计

LFM(线性调频)信号是一类重要的非平稳信号,其完全被初始频率和调频斜率两个参量表征,而LFM信号的检测与估计问题是信号处理中最为重要的研究热点之一.由于调频信号在时频平面内有较好的聚集性,通常使用时频分析的方法对其进行检测和估计.线性正则变换是经典时频分布的广义形式,对LFM信号具有很好的能量聚集特性,在现有的线性正则域Hilbert变换的基础上,提出了一种不需要谱峰搜索而快速检测LFM信号和估计其参数的方法,并且通过仿真实例验证了所提出方法的优越性.     

构造杂交应力单元的柔度矩阵H对角化方法

证明了杂交元柔度矩阵 H非奇异的充分必要条件是假设应力模式线性无关 ;以及等价应力模式形成相同的杂交元。在此基础上建立了假设应力模式的 Hilbert子空间 ,从而可以利用 Schmidt方法简单地得到等价的正交应力模式 ,实现了柔度矩阵 H对角化 ,使得杂交元形成过程中完全避免了繁杂的矩阵求逆运算 ,提高了杂交元分析的计算效率 ,特别在柔度矩阵不容易显式求逆的材料非线性分析中更具有实际意义     

Commuting Toeplitz operators on the Segal-Bargmann space

Consider two Toeplitz operators Tg, Tf on the Segal-Bargmann space over the complex plane. Let us assume that g is a radial function and both operators commute. Under certain growth condition at infinity of f and g we show that f must be radial, as well. We give a counterexample of this fact in case of bounded Toeplitz operators but a fast growing radial symbol g. In this case the vanishing commutator [Tg,Tf]=0 does not imply the radial dependence of f. Finally, we consider Toeplitz operators on the Segal-Bargmann space over Cn and n>1, where the commuting property of Toeplitz operators can be realized more easily.     

Potential theory of infinite dimensional Lévy processes

We study the potential theory of a large class of infinite dimensional Lévy processes, including Brownian motion on abstract Wiener spaces. The key result is the construction of compact Lyapunov functions, i.e., excessive functions with compact level sets. Then many techniques from classical potential theory carry over to this infinite dimensional setting. Thus a number of potential theoretic properties and principles can be proved, answering long standing open problems even for the Brownian motion on abstract Wiener space, as, e.g., formulated by R. Carmona in 1980. In particular, we prove the analog of the known result, that the Cameron-Martin space is polar, in the Lévy case and apply the technique of controlled convergence to solve the Dirichlet problem with general (not necessarily continuous) boundary data.     

A Proper Generalized Decomposition for the solution of elliptic problems in abstract form by using a functional Eckart-Young approach

The Proper Generalized Decomposition (PGD) is a methodology initially proposed for the solution of partial differential equations (PDE) defined in tensor product spaces. It consists in constructing a separated representation of the solution of a given PDE. In this paper we consider the mathematical analysis of this framework for a larger class of problems in an abstract setting. In particular, we introduce a generalization of Eckart and Young theorem which allows to prove the convergence of the so-called progressive PGD for a large class of linear problems defined in tensor product Hilbert spaces.     

Explicit solution of the finite time L2-norm polynomial approximation problem

The aim of this paper is to present a new approach to the finite time L₂-norm polynomial approximation problem. A new formulation of this problem leads to an equivalent linear system whose solution can be investigated analytically. Such a solution is then specialized for a polynomial expressed in terms of Laguerre and Bernstein basis.