微波消解样品-石墨炉原子吸收光谱法测定双黄连口服液及其药材中重金属元素

双黄连口服液及其中药材金银花、连翘和黄芩苷样品用硝酸-过氧化氢(3+1)混合溶液浸泡过夜,微波消解。并用石墨炉原子吸收光谱法(GF-AAS)测定了铅、镉、铬、铜、铁和锌的含量。磷酸二氢铵、8-羟基喹啉和硒(Ⅱ)分别被用作测定铅,镉,铜和铁、铬以及锌的基体改进剂。在优化的试验条件下,方法的回收率在90.4%～106.0%之间,相对标准偏差(n=5)在1.8%～4.6%之间。试验结果表明,双黄连口服液及其中药材中铁、锌、铜的含量较为丰富,铅和镉含量低于"药用植物及制剂外经贸绿色行业标准"。     

Complexes of Di‐ and Triazacrown Ethers with Heavy Metal Ions in Water Solution

This research concerns the analysis of the metal ion binding of benzo‐ and pyridine‐azacrown ether compounds of different structures and sizes by potentiometric method. The ligands are able to form 1 : 1 complexes with heavy metal ions (Cu⁺², Pb⁺², Cd⁺², Ag⁺, Ni⁺², Zn⁺²) in water of middle or high stability. To understand the selectivity in cation binding, different factors were considered.     

All Solid State Nickel(II)‐Selective Potentiometric Sensor Based on an Upper Rim Substituted Calixarene

A new ionophore, i.e. p‐(2‐thiazolazo)calix[4]arene ( I ) has been explored for its selective behavior towards Ni(II) ions. A poly(vinyl chloride) based membrane containing ( I ) as an electroactive material along with sodiumtetraphenylborate (NaTPB), and nitrophenyloctyl ether in the ratio 10 : 100 : 3 : 150 (I:PVC:NaTPB:NPOE) (w/w) was used to fabricate an all solid state nickel(II)‐selective sensor. The developed sensor exhibited a working concentration range of 1.0×10^?6–1.0×10^?1 M, with a Nernstian slope of 28.9±1.0 mV/decade of activity and a response time of 10–15 s. This sensor shows a detection limit of 9.0×10^?7 M. Its potential response remains unaffected of pH in the range 3.0–7.6, and the cell assembly could be used successfully in partially nonaqueous medium (up to 10 % v/v) without any significant change in the slope value or the working concentration range. The sensor worked satisfactorily for about ten weeks and exhibited excellent selectivity over a number of mono‐, bi‐, and tri‐valent cations including alkali, alkaline earth metal, and transition metal ions. It could be used as an indicator electrode for the end point determination in the potentiometric titration of nickel ions against ethylenediaminetetraacetic acid (EDTA) as well as for the determination of nickel ion concentration in real samples.     

Biham–Middleton–Levine model in consideration of cooperative willingness

In this paper, the Biham-Middleton-Levine （BML） model with consideration of cooperative willingness has been proposed to study the traffic flow in urban networks. An evolutionary game with a cooperative willingness profile is intro-duced to deal with conflicts between disturbing neighbors. Simulation results suggest that imitating cooperative willingness can ease the effect of premature seizure on traffic flow due to the introduction of evolutionary games. Phase diagrams with a strategy profile and cooperative willingness profile have been investigated in detail. Our findings also prove that by imitating the more successful, cooperative willingness instead of simply the more successful strategies, the evolution of cooperation is significantly promoted, hence improving the order of cooperation and relieving the pressure of traffic networks.     

Data and queueing analysis of a Japanese air-traffic flow

Congestion is a major cause of inefficiency in air transportation. A question is whether delays during the arrival phase of a flight can be absorbed more fuel-efficiently in the future. In this context, we analyze Japan’s flow strategy empirically and use queueing techniques in order to gain insight into the generation of the observed delays. Based on this, we derive a rule to balance congestion delays more efficiently between ground and en-route. Whether fuel efficiency can be further improved or not will depend on the willingness to review the concept of runway pressure.     

改善交通视角下的城市人口经济分布研究

城市各区的人口-经济分布直接决定了各区之间的车流量,从而决定了城市的交通拥堵程度.充分考虑各区入口经纬度、道路基本路况和人口-经济分布等构建交通指数模型,探究各区入口的拥堵情况.之后从市民出行的角度构建评价模型,评价城市各区布局是否合理.最后,构建非线性规划模型,为城市各区人口经济合理分布提供政策建议.以深圳市为实例进行了实证研究,结果表明深圳市接下来应该着重发展罗湖、南山和盐田区的经济,住房规划首先考虑南山区.     

基于权的最小平方法的山区道路交通安全度模糊综合评价

针对山区道路交通特点,综合考虑影响山区道路交通安全度的人、车、路、环境等主要因素,运用层析分析法构建道路交通安全度评价指标体系,基于权的最小平方法建立模糊综合评价模型,并利用加权平均原则对其进行综合评价.以云南省罗富路"者桑"段为例,结果表明该模型可以有效的反映道路的安全状况,且权的最小平方法可以实现道路交通安全度主要影响因素权重系数的精确分配,合理反映各评价指标的重要性,为提高道路的交通安全性奠定基础.     

无预警紧急疏散中公交车辆路径的确定方法

针对无预警式紧急疏散中公交救援车辆的最佳路径确定问题,提出了一个非线性混合整数规划模型.模型不仅考虑了有接收能力限制的多避难所系统,还对如何处理具有不同载客上限的公交救援车进行了分析.利用添加了虚拟路段和节点的时空网络,在以加权的综合疏散时间最小为目标的同时实现了疏散伤亡最小化.通过分析实际疏散的实施过程,得到了一种产生模型可行解的有效方法.通过将时间滚动式的流量加载模式与经典遗传算法相结合,给出了新模型的实用解法.最后,通过算例验证了模型和算法的有效性.     

钙调素与重金属Pb2+结合反应的方波极谱与循环伏安法研究

采用方波极谱法研究了重金属Pb2+与钙调素(CaM)的结合反应, 直接检测到Pb2+-CaM配合物的存在, 并进一步利用循环伏安法研究了Pb2+-CaM的电极反应. 在pH=6.5时, 用方波极谱法在Pb2+-CaM体系中检测出2个还原峰, 峰电位分别为-0.44~-0.47 V和-0.73~-0.77 V, 说明在Pb2+-CaM体系中铅有2种存在形式, -0.44~-0.47 V的还原峰对应于游离态Pb2+, 电位更负的还原峰对应于配合物[Pb2+-CaM]. 2个还原峰的峰电流均随着cPb2+/cCaM比值增大而增大; 至cPb2+/cCaM≥10后, 配合物[Pb2+-CaM]的峰电流基本不再变化, 而游离态Pb2+的峰电流则继续增大. 利用极谱滴定曲线的拐点可判断出Pb2+在CaM中有10个结合位点. 进一步的测量结果表明, 循环伏安曲线出现游离态Pb2+的氧化峰和还原峰, 而络合态的[Pb2+-CaM]只有其还原峰, 反向电压扫描时不出现阳极波, 即没有相对应的氧化峰出现.