秦巴山区娑罗子资源微量及重金属元素分析

微波消解系统处理秦巴山区各县区娑罗子样品,火焰原子吸收光谱法测定娑罗子中Ca、Mn、Cu、Zn、Fe、Mg6种微量元素的含量,石墨炉和氢化物法测定As、Pb和Cd3种重金属元素的含量。采用此方法回收率在97.06%—102.52%之间,相对标准偏差(RSD)小于1.76%。在秦巴山区10个采样点的娑罗子中均含有丰富的人体必需微量元素,比较各种元素含量,不同来源的样品存在差异。     

Development of a sequential injection anodic stripping voltammetry (SI-ASV) method for determination of Cd(II), Pb(II) and Cu(II) in wastewater samples from coatings industry

This paper describes the development and validation of a sequential injection (SI) anodic stripping voltammetry (ASV) method using the hanging mercury drop electrode for accumulation of the heavy metal cations Cu(II), Pb(II) and Cd(II). The method was applied to wastewater samples after proper acid digestion in open vessels to eliminate matrix effects. For a deposition time of 90 s at the flow rate of 10 μl s⁻¹, the detection limits of the method were 0.06, 0.09 and 0.16 μmol L⁻¹ for Cd, Pb and Cu, respectively. Under these conditions the linear dynamic range was between 0.20 and 9.0 μmol L⁻¹ and the sampling frequency was 30 analyses per hour. The relative standard deviation of the method was 3%(n=7) at the concentration level of 2.0 μmol L⁻¹. The accuracy of the method was evaluated by spiking the samples with known amounts of the metal cations, and by comparison with an independent analytical technique, the inductively coupled plasma atomic emission spectroscopy (ICP-AES). Average recoveries were around of 84%, and the results showed no evidence of systematic errors in comparison to the ICP-AES.     

In-medium hadronization in the deconfined matter at RHIC and LHC

We study the mechanism and probability of in-medium hadronization in the deconfined medium produced in heavy-ion collisions at RHIC and LHC. We show the likelihood of color-neutral objects to be formed inside the partonic fireball and the probability of these states to escape the medium with reduced interaction strength and energy loss. We will suggest specific measurements that are sensitive to the early degrees of freedom and show predictions for these measurements at RHIC and the LHC.     

The effect of TTL on the information traffic

In real communication protocols, the information packets have a finite Time-to-Live (TTL) to avoid the waste of network resources, such as infinite loop induced by routing error or too long transferring time. In this paper, we introduce TTL into the information traffic model on Barabási-Albert scale-free networks under local routing strategy and focus on its effect on the network capacity measured by the critical point (R_c) of phase transition from free flow to congestion. Simulations show that the network capacity and the communication velocity are improved. However, some packets are dropped before they arrived at destinations. It is found that the share of successfully arrived packets monotonously increases with the increment of TTL and it is considerably acceptable if TTL is not very small. We also examine the effect of TTL on the positive-feedback preference (PFP) internet model and the results are alike. Our work may be helpful in quantifying the effect of packet lifetime in real communication networks and in routing strategy designing.     

Development of new composite biosorbents from olive pomace wastes

In this study olive pomace was used as a source of binding substances for the development of composite biosorbents to be used in heavy metal removal from aqueous solutions. The aim was to obtain biosorbent material with an increased concentration of binding sites. The effects of two different extraction procedures (one using only methanol and the other one hexane followed by methanol) on the binding properties of olive pomace were tested by potentiometric titrations and batch biosorption tests for copper and cadmium removal. Titration modelling evidenced that both kinds of extractions generated a solid with a reduced amount of protonatable sites. Biosorption tests were organized according to full factorial designs. Analysis of variance denoted that both kinds of extractions determined a statistically significant negative effect on metal biosorption. In the case of cadmium extractions also determined a significant decrease of selectivity with respect to olive pomace.When the acid-base and binding properties of the substances extracted were determined, they were adsorbed onto a synthetic resin (octadecylsilane) and calcium alginate beads. In this way two kinds of composite biosorbents have been obtained both having an increased concentration of binding substances with respect to native olive pomace, also working more efficiently in metal removal.     

大数据背景下基于5S的城市交通拥堵评价模型研究

近几年来,城市交通拥堵问题日益突出,极大制约了城市发展。在大数据背景下,为了准确掌握交通实时拥堵状况,改善城市交通,便利市民出行,本文深入挖掘城市交通拥堵的影响因素,构建了基于交通5S要素的城市拥堵理论模型,运用径向基函数神经网络方法工具,以上海静安寺、上海站、陆家嘴周围三大拥堵路段的交通数据集为例,验证了该模型的有效性。实验结果表明,由该模型获得的城市交通拥堵预测值与上海实际交通路况具有较好的拟合效果,表明交通5S模型与方法能够准确有效地评价城市交通拥堵。     

快速路交通微分系统的脉冲迭代学习策略研究

针对快速路交通微分系统,结合该交通系统具有明显的重复性和周期性等特点,设计了一种脉冲迭代学习策略,并建立了迭代学习误差的收敛性条件.其次,利用λ范数和脉冲Gronwall不等式等方法证明了算法的收敛性.结合脉冲控制与学习控制的特点,该方法的优点在于容易实现和经济环保,且能有效地达到控制目的.最后,通过数值仿真实证进一步说明所设计控制方法的有效性.     

高负荷下带重尾服务强占优先排队的扩散逼近

考虑的排队系统是单服务台,顾客的初始到来是依泊松过程来到服务台,顾客的服务时间是重尾分布,服务的原则是强占优先服务.在高负荷条件下对此模型进行研究,获得了系统中的负荷过程,离去过程和队长过程的扩散逼近.     

基于局域相关向量机回归模型的小尺度网络流量的非线性预测

基于非线性时间序列局域预测法与相关向量机回归模型, 本文提出了局域相关向量机预测方法, 并应用于预测实际的小尺度网路流量序列. 应用基于信息准则的局域预测法邻近点的选取方法来选取局域相关向量机回归模型的邻近点个数. 对比分析了局域相关向量机预测法、前馈神经网络模型与局域线性预测法对网络流量序列的预测性能, 其中前馈神经网络模型的参数采用粒子群优化算法来优化. 实验结果表明: 邻近点优化后的局域相关向量机回归模型能够有效地预测小尺度网络流量序列, 归一化均方误差很小; 局域相关向量机回归模型生成的时间序列具有与原网络流量时间序列相一致的概率分布; 局域相关向量机回归模型的预测精度好于前馈神经网络模型的与局域线性预测法的. 关键词： 小尺度网络流量 非线性时间序列预测方法 局域预测法 相关向量机回归模型     

Radiation-induced transmission loss in optical materials at infrared wavelengths

Information concerning the effect of irradiation on the optical properties of materials in the infrared, sub-mm-and mm-wavelength regions is of increasing importance in fusion plasma diagnostics. The radiation induced transmission loss of a number of materials has therefore been investigated at wavelengths in the ranges 200 nm to 40 μm and 0.23 to 2.0 mm. The samples were irradiated with doses of up to 10¹⁰ rad in a nuclear reactor. While germanium shows considerable transmission loss at doses as low as 10⁶ rad, and the transmission of TPX decreases at 10⁹ rad, other materials, e.g. fused quartz and possibly ZnSe, exhibit sufficient radiation hardness for use in fusion plasma diagnostics.