亚甲蓝与硫酸化茯苓多糖相互作用机理的研究

为从分子水平认识硫酸化多糖分子与小分子之间相互作用的机理,文章采用氯磺酸-吡啶法(Wolfrom法)对茯苓多糖进行结构修饰,制得硫酸化茯苓多糖(SP)。通过理论模型测得亚甲蓝(MB)与SP最大结合数N=54,结合常数K=1.563×106,考察了反应体系中MB/SP摩尔比、NaCl、乙醇、羟丙基-β-环糊精以及Triton X-100对相互作用的影响。探讨了MB与SP相互作用产生变色反应的机理,认为其是在MB 与SP大分子间发生静电相互作用的基础上,结合态MB分子之间的疏水相互作用所引起的。     

Magnetocaloric effect and multifunctional properties of Ni–Mn-based Heusler alloys

The studies of magnetocaloric properties, phase transitions, and phenomena related to magnetic heterogeneity in the vicinity of the martensitic transition (MT) in Ni–Mn–In and Ni–Mn–Ga off-stoichiometric Heusler alloys are summarized. The crystal structure, magnetocaloric effect (MCE), and magnetotransport properties were studied for the following alloys: Ni₅₀Mn_50−xIn_x, Ni_50−xCo_xMn₃₅In₁₅, Ni₅₀Mn_35−xCo_xIn₁₅, Ni₅₀Mn₃₅In₁₄Z (Z=Al, Ge), Ni₅₀Mn₃₅In_15−xSi_x, Ni_50−xCo_xMn_25+yGa_25−y, and Ni_50–xCo_xMn_32−yFeyGa₁₈. It was found that the magnetic entropy change, ΔS, associated with the inverse MCE in the vicinity of the temperature of the magneto-structural transition, TM, persists in a range of (125-5) J/(kg K) for a magnetic field change ΔH=5 T. The corresponding temperature varies with composition from 143 to 400 K. The MT in Ni₅₀Mn_50−xIn_x (x=13.5) results in a transition between two paramagnetic states. Associated with the paramagnetic austenite-paramagnetic martensite transition ΔS=24 J/(kg K) was detected for ΔH=5 T at T=350 K. The variation in composition of Ni₂MnGa can drastically change the magnetic state of the martensitic phase below and in the vicinity of TM. The presence of the martensitic phase with magnetic moment much smaller than that in the austenitic phase above TM leads to the large inverse MCE in the Ni₄₂Co₈Mn_32−yFeyGa₁₈ system. The adiabatic change of temperature (ΔT_ad) in the vicinity of TC and TM of Ni₅₀Mn₃₅In₁₅ and Ni₅₀Mn₃₅In₁₄Z (Z=Al, Ge) was found to be ΔT_ad=−2 K and 2 K for ΔH=1.8 T, respectively. It was observed that |ΔT_ad|≈1 K for ΔH=1 T for both types of transitions. The results on resistivity, magnetoresistance, Hall resistivity in some In-based alloys are discussed.     

转换反射中光自旋霍尔效应的自旋堆积方向

从理论上和实验上研究了转换反射中光自旋霍尔效应的自旋堆积方向的方法,建立了描述光束在空气-棱镜界面反射的自旋堆积模型,揭示了横移与光束入射偏振角的定性关系。研究发现,当入射角小于布儒斯特角时,随着入射偏振角的逐渐增大,自旋堆积的方向发生反转。而当入射角大于布儒斯特角时,自旋堆积的方向不再随入射偏振角的变化而反转。结果表明,在光束入射角为确定值且小于布儒斯特角的情况下,可以通过调控光束的入射偏振角转换自旋堆积的方向。转换自旋堆积方向的研究为有效调控光自旋霍尔效应提供了新的途径。     

高能重离子碰撞中末态粒子分布的非对称性

对Bevalac1.2A GeV Au+Au碰撞实验,根据以流方向为z轴的质心坐标系中末态粒子方位角分布的非对称性为极小的条件,确定了事件中五种质量范围(A=1,2,3,4,5-8)末态粒子的集合侧向流流角.在以流方向为z轴的质心坐标系中研究了不同质量末态粒子极角分布,结果表明质量越大的粒子在流方向分布得越集中,侧向流的“流”值越大.     

GW──I磁传感器实验仪研制

本文介绍了自制磁传感器实验仪的原理。     

温度和雷诺数对表面活性剂溶液传热的影响

对不同温度和雷诺数下阳性离子表面活性剂十六烷基三甲基氯化铵(CTAC)溶液在循环回路中的传热特性进行了实验研究。在水中加入表面活性剂后溶液的传热特性明显降低,在不同的温度工况下均存在一个临界雷诺数,随着溶液温度的改变而发生变化。在不同的实验浓度条件下均存在一个临界温度,在临界温度以下时,临界雷诺数随温度升高而增加;在临界温度以上时,临界雷诺数随温度升高而急剧下降。分析该表面活性剂溶液阻力减小和传热性能降低之间的关系,提出了通过对溶液温度的控制来改变减阻流体传热特性的方法。     

对四类泻流问题的深入研究

对热学中的4类泻流问题进行了详细的计算,并对结果进行了分析讨论.恒温的泻流问题有解析的解,而绝热泻流问题往往受限于数学知识只能得到数值的结果;同时本文也对泻流的近平衡态条件进行了大致的分析.这些将有助于广大师生对于泻流问题的全面认识.     

Tunneling of Spinor Bose-Einstein Condensates in Optical Lattice

In this letter, we have studied the tunneling effects and fluctuations of spinor Bose-Einstein condensates in optical lattice. It is found that there exist tunneling effects and fluctuations between lattices l and l ＋ 1, l and l - 1, respectively. In particular, when the optical lattice is infinitely long and the spin excitations are in the long-wavelength limit, tunneling effects disappear between lattices I and l＋ 1, and I and l - 1. In this case the fluctuations are a constant, and the magnetic soliton appears.     

范德堡方法在ZnO薄膜测试中的应用

近年来,随着对宽禁带半导体材料,氧化锌薄膜研究的快速发展,对其电学性质的研究也显得尤为重要。主要介绍范德堡方法在ZnO薄膜电学性质测量中的应用,并对初步测量结果作简要的讨论。     

Total absolute curvature and tightness of noncompact manifolds

In the first part we prove an extension of the Chern-Lashof inequality for noncompact immersed manifolds with finitely many ends. For this we give a lower bound of the total absolute curvature in terms of topological invariants of the manifold. In the second part we discuss tightness properties for such immersions. Finally, we give an upper bound for the substantial codimension.