全文获取类型
收费全文 | 17893篇 |
免费 | 1884篇 |
国内免费 | 1520篇 |
专业分类
化学 | 10028篇 |
晶体学 | 100篇 |
力学 | 725篇 |
综合类 | 159篇 |
数学 | 8206篇 |
物理学 | 2079篇 |
出版年
2024年 | 38篇 |
2023年 | 350篇 |
2022年 | 284篇 |
2021年 | 295篇 |
2020年 | 560篇 |
2019年 | 575篇 |
2018年 | 591篇 |
2017年 | 453篇 |
2016年 | 669篇 |
2015年 | 747篇 |
2014年 | 1048篇 |
2013年 | 1583篇 |
2012年 | 970篇 |
2011年 | 1169篇 |
2010年 | 977篇 |
2009年 | 1121篇 |
2008年 | 1215篇 |
2007年 | 1160篇 |
2006年 | 966篇 |
2005年 | 758篇 |
2004年 | 702篇 |
2003年 | 687篇 |
2002年 | 595篇 |
2001年 | 424篇 |
2000年 | 413篇 |
1999年 | 398篇 |
1998年 | 352篇 |
1997年 | 242篇 |
1996年 | 249篇 |
1995年 | 260篇 |
1994年 | 232篇 |
1993年 | 155篇 |
1992年 | 167篇 |
1991年 | 92篇 |
1990年 | 84篇 |
1989年 | 74篇 |
1988年 | 66篇 |
1987年 | 44篇 |
1986年 | 42篇 |
1985年 | 65篇 |
1984年 | 62篇 |
1983年 | 20篇 |
1982年 | 65篇 |
1981年 | 46篇 |
1980年 | 35篇 |
1979年 | 39篇 |
1978年 | 40篇 |
1977年 | 28篇 |
1976年 | 30篇 |
1973年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
Wei‐Ling Wang Jian‐Wei Xu Yee‐Hing Lai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4154-4164
Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and 1H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu2+, Co2+, Ni2+, Zn2+, Mn2+, and Ag+ ions. In contrast, only Cu2+, Co2+, and Ni2+ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu2+, Co2+, and Ni2+ ions toward P7 are of the order of 106 M?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006 相似文献
102.
The present paper deals with the long-time behavior of a class of nonautonomous retarded semilinear parabolic differential equations. When the time delays are small enough and the spectral gap conditions hold, the inertial manifolds of the nonautonomous retard parabolic equations are constructed by using the Lyapunov-Perron method. 相似文献
103.
本文对二种新合成的2,3-二羟基萘二钼和四钼多酸有机衍生物[n-Bu)4N]2[Mo2O5(OC10H6O)2](Ⅰ)和[n-Bu)4N]2[Mo4O10(OC10H6O)2(OCH3)2](Ⅱ)进行了红外光谱与核磁共振波谱研究,发现[Mo2O5]^2 中钼氧多桥键的红外振动频率较[Mo4O10(OCH3)2]^2 中钼氧多桥键的红外振动频率红移,而在配合物Ⅱ中2,3-二羟基中芳环的^1H化学位移较配合物Ⅰ中向低场移动。同时还发现含二钼配位中心[Mo2O5]^2 的[Mo2O5(OC10H6O)2]^2-与含四钼配位中心[Mo4O10(OCH3)2]^2 的[Mo4O10(OC10H6O)2(OCH3)2]^2-生成条件的差异仅仅只在反应体系的pH值的微小变化,说明钼多酸有机衍生物阴离子是对体系酸碱度极为敏感的物质。 相似文献
104.
Common fixed-point results are established for a new class of noncommuting selfmaps. We apply them to obtain several invariant approximation results which unify, extend, and complement well-known results. 相似文献
105.
Raiko P. Zaikov 《Letters in Mathematical Physics》1994,32(4):283-297
Higher spin extensions of the non-Abelian gauge symmetries for the classical WZNW model are considered. Both linear and nonlinear realizations of the extended affine Kac-Moody algebra are obtained. It is a characteristic property of the WZNW model that it admits a higher spin linear realization of the extended affine Kac-Moody algebra which is equivalent to the corresponding higher spin nonlinear realization of the same algebra. However, in both cases, the higher spin Noether currents do not span an invariant space with respect to their generating transformations. Here, the current space is extended to an invariant space which allows us to gauge the symmetry.Supported by Bulgarian Foundation on Fundamental Research under contract Ph-318/93-95. 相似文献
106.
Ryuhei Wakita Masanori Miyakoshi Yohji Nakatsuji Mitsuo Okahara 《Journal of inclusion phenomena and macrocyclic chemistry》1991,10(1):127-139
A series of noncyclic neutral ionophores has been synthesized by the reaction of oligoethylene glycol dihalides with 8-quinolinol. Complexation properties for alkali metal picrates were evaluated from solvent extraction and bulk liquid membrane transport experiments. Complexation profiles of the newly synthesized ionophores with a hexyl chain were similar to those of their homologues without the hexyl chain in the extraction experiments. Among them, the pentaethylene glycol derivatives showed the highest extraction efficiency and selectivity towards potassium ion. From the1H NMR spectra (400 MHz), the change in chemical shifts of the aromatic protons upon the addition of alkali metal thiocyanates suggested the existence of a stabilization effect which is caused by intramolecular stacking conformations between the quinoline rings during complexation. Aryl stacking interactions depend on the size of the cations and on the chain length of the oligoethylene glycol. The relationship between transport ability towards alkali metal cations and lipophilicity of these ionophores is also discussed. 相似文献
107.
Hiroshi Sugita 《Probability Theory and Related Fields》1994,100(1):117-130
Summary We show that each holomorphic Wiener function has a skeleton which is intrinsic from several viewpoints. In particular, we study the topological aspects of the skeletons by using the local Taylor expansion for holomorphic Wiener functions.Supported in part by the Grant-in-Aid for Science Research 03740120 Min. Education 相似文献
108.
Alexander O. Smirnov 《Letters in Mathematical Physics》2006,76(2-3):297-316
We find a new class of Fuchsian equations, with algebro-geometric solutions associated to a hyperelliptic curve. A method for calculating its arithmetic genus and branching points is suggested. Numerous examples are given. 相似文献
109.
In this paper we study random orderings of the integers with a certain invariance property. We describe all such orders in a simple way. We define and represent random shuffles of a countable set of labels and then give an interpretation of these orders in terms of a class of generalized riffle shuffles. 相似文献
110.