鲜牛奶变质过程的激光诱导荧光光谱研究

本文用激光诱导荧光（LIF）方法对鲜牛奶和酸牛奶变质过程进行了荧光光谱研究,介绍了所用测试系统的组成及测试方法,给出了变质过程荧光谱,并对测试结果进行了分析,研究表明,变质过程与荧光光谱之间存在密切联系。     

Multiple scattering of gamma rays in water,concrete and sand

The transmitted photon spectra of¹³³Ba,²²Na,¹³⁷Cs,⁵⁴Mn and⁶⁰Co point sources are measured through different thicknesses of water, concrete and sand. The multiple-scatter peaks observed in these materials at 60, 90 and 100 keV energies respectively are found to be independent of incident photon energy and thickness of the medium.     

Cd3Al2Ge3O12:Mn2+锗酸盐石榴石光谱性质

本文报道室温下Cd₃Al₂Ge₃O₁₂:Mn²⁺(简称CAGG:Mn²⁺)锗酸盐石榴石的漫反射光谱、激发和发射光谱.在UV光激发下,在CAGG中Mn²⁺离子发射强黄光,这是基质到Mn²⁺离子无辐射能量传递的结果.Mn²⁺的黄发射带是由一个弱的红带和一个强的绿带所组成.讨论了这两个Mn²⁺发射带的起因.     

比较与研究金属离子与三种蛋白的配位机理

本文通过测定牛血红蛋白、人血清蛋白、伴刀豆球蛋白Ａ与过渡态金属离子Ｃｒ（Ⅲ）、Ｆｅ（Ⅲ）在不同条件下的荧光强度变化来揭示蛋白质与金属离子形成络合物的配位点，从而确定所形成配合物的结构，并讨论了溶液ＰＨ值对蛋白质荧光强度的影响。另外，对金属离子与蛋白质体系进行了荧光偏振的研究。     

Planar graphs without triangles adjacent to cycles of length from 4 to 7 are 3-colorable

It is known that planar graphs without cycles of length from 4 to 7 are 3-colorable (Borodin et al., 2005) [13] and that planar graphs in which no triangles have common edges with cycles of length from 4 to 9 are 3-colorable (Borodin et al., 2006) [11]. We give a common extension of these results by proving that every planar graph in which no triangles have common edges with k-cycles, where k∈{4,5,7} (or, which is equivalent, with cycles of length 3, 5 and 7), is 3-colorable.     

An improved approximation algorithm for requirement cut

This note presents improved approximation guarantees for the requirement cut problem: given an n-vertex edge-weighted graph G=(V,E), and g groups of vertices X₁,…,X_g⊆V with each group X_i having a requirement r_i between 0 and |X_i|, the goal is to find a minimum cost set of edges whose removal separates each group X_i into at least r_i disconnected components. We give a tight Θ(logg) approximation ratio for this problem when the underlying graph is a tree, and show how this implies an O(logk⋅logg) approximation ratio for general graphs, where .     

LAP及DLAP单晶的晶格振动光谱

本文对新型有机光学非线性晶体LAP的晶格振动进行了群论分析.并记录了各种几何配置下LAP单晶及其氘化物DLAP单晶在50～3700cm~(-1)范围的偏振喇曼光谱及偏振红外反射光谱.对谱图进行了识别.对LAP和DLAP单晶中NH_3~+,PO_4~(3-),COO~-基团的内振动进行了比较.实验结果表明DLAP单晶和LAP单晶具有相同的对称性.氘化使晶体的通光范围向红外方向扩展.     

玻璃基质中ZnS纳米晶Mn2+的EPR谱

用融熔法制备分散有ZnS:Mn²⁺纳米晶的纳硼硅(Na₂O-B₂O₃-SiO₂)玻璃在不同温度、时间对样品进行退火处理,得到不同尺寸的纳米晶.研究了玻璃基质中ZnS:Mn²⁺纳米晶的EPR谱、微波功率饱和EPR谱及发射光谱,发现Mn²⁺有二种组态,即替位组态和间隙位组态.分析结果表明替位组态Mn²⁺及周围立方晶场的畸变程度直接影响光学发光特性.     

几种稠环芳烃有机EL材料性能的量子化学理论研究

采用量子化学半经验方法（ＲＨＦ／ＰＭ３）对几种稠环芳烃化合物电致发光（ＥＬ）材料的性质进行了理论研究。利用能量梯度法优化构型,对各优化的构型作振动分析,均未出现虚频率。在此基础上,采用ＲＨＦ／ＣＩＳ方法计算其电子光谱。并给出了化合物ＥＬ１,ＥＬ２电子光谱的最大波长λ与ＣＩＳ组态之间的关系。所有计算结果与实验值基本吻合。     

Electronic structure of F,-center in MgO

The embedded-cluster numerical variational method has been developed to calculate the electronic structure of perfect MgO, F and F⁺-centers in MgO. The energy band, bulk density of states has been calculated by cluster Mg₁₄O₁₃, Mg₁₄O₁₂F⁺ and Mg₁₄O₁₂F. The calculated absorption energy for F⁺ and F centers is in good agreement with experimental data. In our calculated defect energy levels, that the first excited state of F⁺-center is at CB-3.46 eV, indicates the necessity of a large photoelectron yielding energy. We also calculate the radius of color center electron, and plot the map of charge-density distribution of valence electrons in which the structure of the color center is shown directly. Received 22 May 1998