A statistical model for global optimization by means of select and clone

A statistical model tor giobai optimization is constructed generalizing some properties ofthe Wiener process to the multidimensional case. A new approach, which is similar to the Branch and Bound approach, is proposed to the construction of algorithms based on statistical models. A two dimensional version of the algorithm is implemented, and test results are presented     

Composite of SiO2 and Hydrogel Having Microphase Separated Structure: Physical Properties Dependence on pH

Abstract

Organic-inorganic composite gel was prepared by using PEG-modified urethane acrylate (PMUA) gel and tetraethoxysilane (TEOS). PMUA gel was prepared by the phase-inversion emulsion polymerization of PMUA emulsion. The gelation of PMUA emulsion using this method enables PMUA gel to swell with H₂O, TEOS, and ethanol. Hydrolysis and condensation reaction rates of the sol-gel process are strongly influenced by the pH controlled by catalysts such as HCl and NH₄OH. Additionally, the morphology on the cross section of composite and the amount of silica ingredient incorporated into the composite gel were dependent on solvent, the molar ratio of H₂O to TEOS, as well as the pH value.

As the silica content increased, due to hydrogen bonds interacting between PMUA gel and SiO₂, particles, the tensile strength of composites considerably increased, whereas the elongation at break decreased. The incorporation of silica ingredient in PMUA gel/silica composites was verified with FTIR/ATR and SEM. The amount of the silica component in the composite was indirectly investigated by using TGA thermal analysis.     

氢键准则在DMSO水溶液中应用的评价

利用分子动力学模拟方法, 分别采用几何准则和能量准则分析了不同浓度下的二甲基亚砜(DMSO)水溶液的氢键统计和动力学等特性. 结果显示, 两种氢键准则可以很好地反映出溶液的氢键性质随浓度的变化趋势. 通过分析比较发现, 由于几何准则不能有效地排除具有弱对势能的分子对, 因此其统计的氢键数量要大于能量准则的结果.此外, 能量准则对于分子间相对取向的区分存在不足, 进而引起氢键寿命的计算结果偏大.因此,为使氢键分析更加准确, 本文建议使用几何-能量混合型氢键准则.     

基于CA和LS-SVM的TE过程多模型建模

针对TE化工过程高度非线性、复杂性的特点,本文提出了一种基于相关分析和最小二乘支持向量机对TE过程进行多模型建模方法,以提高模型性能。首先对TE过程采用相关分析法划分为3个子系统,对每个子系统分别采用基于C-均值聚类的最小二乘支持向量机建模和基于k均值聚类的最小二乘支持向量机多模型建模。实验表明,基于K-均值聚类的多模型建模能简化计算、提高模型精度、并且能更好的预测模型输出。     

基于非对称漂移双gamma跳-扩散过程的创新幂型期权定价模型

针对假设股价的对数收益率布朗运动在期权定价时产生的无法解释股价对数收益率的尖峰厚尾和序列相关性的缺陷,采用了Zhang提出的非对称漂移双gamma跳-扩散过程来描述资产(股价)的对数收益率运动形态(该过程是kou提出的双指数跳-扩散过程的推广),并利用Esscher风险中性变换,研究了幂型期权的定价公式.还设计了两种创新的幂型期权,在非对称漂移双gamma跳-扩散过程下给出了相应的定价公式.     

基于层次分析法的企业网络舆情危机应对评价研究

网络舆情危机应对评价是企业在新的舆论背景下研究危机应对的重点.采用定量和定性分析有机结合的层次分析法确定指标体系及权重,给出了企业网络舆情危机应对评价的步骤,并进行了评价验证.该评价体系为相关单位网络舆情危机应对评价提供一定的参考和指导.     

Method development for mono- and disaccharides monitoring in cell culture medium by capillary and microchip electrophoresis

The rapidly growing, competitive biopharmaceutical market requires tight bioprocess monitoring. An integrated, automated platform for the routine online/at-line monitoring of key factors in the cell culture medium could greatly improve process monitoring. Mono- and disaccharides, as the main energy and carbon source, are one of these key factors. A CE-LIF method was developed for the analysis of several mono- and disaccharides, considering requirements and restrictions for analysis in an integrated, automated monitoring platform, such as the possibility for miniaturization to microchip electrophoresis. Analysis was performed after fluorescent derivatization with 8-aminopyrene-1,3,6-trisulfonic acid. The derivatisation reaction and the separation BGE were optimized using design of experiments. The developed method is applicable to the complex matrix of cell culture medium and proved transferable to microchip electrophoresis.     

Real-time in situ monitoring of manufacturing process and CFRP quality by relative resistance change measurement

In situ monitoring of resin flow, impregnation of carbon fiber fabrics, and curing during composite manufacturing are very important for determining the quality of composite parts. In conventional methods, sensors, such as optical fibers and strain gages, are bonded to or embedded in the composites for measuring the changes in mechanical and chemical properties. Although they can detect resin curing behavior and impregnation of carbon fibers, they may adversely affect the manufacturing process or structural integrity of the composites. In this study, carbon fiber itself was used as a sensor that minimizes the degradation of mechanical properties and increases the efficiency of monitoring the manufacturing process. The change in the electrical resistance of carbon fiber fabrics was monitored during the various manufacturing processes when the resin flowed through the carbon fiber fabric and curing progressed. The effectiveness of this monitoring method was confirmed, and it is expected to be applicable in monitoring the quality of the finished composite parts.     

选矿产品矿物自动分析的光片制备

基于扫描电子显微镜的矿物自动分析仪(Quantitative Evaluation of Minerals by Scanning Electronic Microscopy)、MLA(Mineral Liberation Analyser)和AMICS(Advanced Mineral Identification and Characterization System)可用于测定选矿产品中目的矿物的粒度和单体解离度,为确定合理的磨矿细度以及优化选矿工艺流程提供依据。环氧树脂光片的制备是矿物自动识别和测量的最关键的一环,其代表性直接关系到后续数据测量的准确性和真实性。对于金属矿产品来说,由于选矿产品中矿物颗粒粗细不均、密度差异较大,在环氧树脂胶结固化过程中矿物颗粒会产生明显的分异作用并互相黏连,造成分析结果失真。实验证明,把样品与晶质石墨混均,然后加入环氧树脂以及固化剂搅拌混合倒入圆柱状模具进行冷镶嵌,待样品固化后再沿圆柱体的纵向进行切割,并对其切割面进行粗磨、细磨、精磨以及抛光,就可以制备出样品分散性好、分布均匀、表面光滑平整的具有代表性的环氧树脂光片。