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211.
Dennis F. Thekkudan Sarah C. Rutan Peter W. Carr 《Journal of chromatography. A》2010,1217(26):4313-4327
Simulated chromatographic data were used to determine the precision and accuracy in the estimation of peak volumes (i.e., peak sizes) in comprehensive two-dimensional liquid chromatography in time (LC × LC). Peak volumes were determined both by summing the areas in the second dimension chromatograms and by fitting the second dimension areas to a Gaussian peak. The Gaussian method is better at predicting the peak volume than the moments method provided there are at least three second dimension injections above the limit of detection (LOD). However, when only two of the second dimension signals are substantially above baseline, the accuracy and precision of the Gaussian fit method become quite poor because the results from the fitting algorithm become indeterminate. Based on simulations in which the modulation ratio (MR = 41σ/ts) and sampling phase (?) were varied, we conclude for well-resolved peaks that the optimum precision in peak volumes in 2D separations will be obtained when the MR is between two and five, such that there are typically four to ten second dimension peaks recorded over the eight σ width of the first dimension peak. This sampling rate is similar to that suggested by the Murphy–Schure–Foley criterion. This provides an RSD of approximately 2% for the signal-to-noise ratio used in the present simulations. The precision of the peak volume of experimental data was also assessed, and RSD values were in the range of 4–5%. We conclude that the poorer precision found in the LC × LC experimental data as compared to LC may be due to experimental imprecision in sampling the effluent from the first dimension column. 相似文献
212.
Xiaoxu Lian 《Optics Communications》2011,284(22):5253-5258
Young's interference experiment is regarded as a two-slit diffraction phenomenon, the polarization singularities in Young's two-slit configuration illuminated with two linearly, orthogonally polarized Gaussian vortex beams are studied. It is shown that generally, there exist L-lines (linearly polarization) and polarization singularities including C-points (circular polarization), S23 and S31 singularities even though the parameters of two beams are the same. The pair creation-annihilation and motion of polarization singularities take place upon propagation, or by varying a control parameter, such as the amplitude ratio of two beams or obscure ratio of slits etc. For a special case of the illumination with two linearly, orthogonally polarized Gaussian vortex-free beams, polarization singularities, in particular, C-points may occur if a parameter of two beams is not equal. 相似文献
213.
By using the semi-analytic approach introduced earlier, we formulate and subsequently evaluate the irradiance fluctuations of partially coherent super Lorentz Gaussian beams for orders of 10 and 11. Within the range of examined source and propagation conditions, our calculations show that there will be less fluctuations at short propagation distances as the Lorentzian property is increased. But the reverse will be applicable, if the longer propagation distances are considered. The use of focusing will cause reductions, particularly for beams with increased Lorentzian property. 相似文献
214.
A detailed study of the morphology of nano-craters drilled in borosilicate glass by single shot femtosecond laser ablation near the ablation threshold has been performed by scanning electron microscopy, atomic force microscopy and scanning electron microscopy imaging after focused ion beam sectioning. The influence of the numerical aperture (NA = 0.4 and 0.8), the pulse energy (16 nJ < Ep < 600 nJ) and the position of the specimen surface into the focal region were systematically investigated, leading to nanometric or micrometric scales in every spatial dimension. The nanocrater’s size is not restricted by the diffraction limit but determined by the laser pulse stability and the material properties. If the beam is focused inside the glass, two craters are drilled, shaping very distinct morphologies. Their dimensions have been studied in details and different relationships have been proposed for the evolutions of the depths and of the various diameters of these craters as functions of the pulse energy, the numerical aperture and the position of specimen surface in the beam-material interaction region. It is suggested that the long, thin conical profile with very high aspect ratio of the secondary craters is due to a spontaneous reshaping of the beam which transforms the incoming Gaussian pulse into a Gaussian-Bessel pulse. As proposed in the developed model the geometry of the second craters seems to be connected with the one of the main craters. 相似文献
215.
E. Koushki 《Optics Communications》2011,284(23):5488-5494
In this investigation, the Gaussian decomposition and the Fresnel-Kirchhoff diffraction methods are compared from different view points. The virtues and faults of each method and also the reliable region of each one are discussed. This work is based on a numerical method for both the circular and elliptic Gaussian beams and results are compared with experimental data. This study is useful for materials exhibit optical Kerr effect such as two photon absorption and thermo-optical nonlinearities. 相似文献
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S. Abdalla 《Physica B: Condensed Matter》2011,406(3):584-587
The complicated structure of human blood has been characterized based on relaxation time, τ, and the Cole-Cole parameter, α, obtained from dielectric measurements. As previously reported by different authors, the experimental data show net deviation from the classical Debye model with certain distribution of relaxation times (Dτ). Plots of α versus width of the relaxation rate distribution of micro-particles inside the blood show that Dτ drastically affects the dielectric properties of the fluid. The mathematical function of Dτ is found to be Gaussian and we find that the α values of normal blood have net lower magnitude than that of diabetic blood. These results suggest that glucose in blood increases the broadness of the parameter α, which have significant importance in diabetic-biosensor manufacture. 相似文献
220.