基于简单碰撞理论煤粉燃烧动力学模型的研究-PART Ⅲ:氧气可达比表面积

根据不同温度下氧分子平均自由程的大小,比较了小孔、中孔和大孔中三种扩散速率与煤焦表面燃烧速度的大小.研究表明2000 K以内,颗粒表面分子扩散速率比氧化反应速率大1个数量级以上,过度扩散速率不小于氧化速率.温度小于1200K时,燃烧速率比Knudsen扩散速率小1～5个数量级,扩散孔径小于15～28 nm,反应主要在内外表面进行;1200～1600K时,燃烧速率与Knudsen扩散速率相当,扩散临界孔径28～38 nm,反应在外表面及浅层内表面进行;温度1600K以上时,Knudsen扩散速率比燃烧速率小1个数量级,孔径38～50 nm以下内表面上碳的氧化速度受扩散控制.煤焦的氧化主要发生在Knudsen扩散临界孔径10～50 nm以上的氧气可达表面上.     

Moment equations for a spatially extended system of two competing species

The dynamics of a spatially extended system of two competing species in the presence of two noise sources is studied. A correlated dichotomous noise acts on the interaction parameter and a multiplicative white noise affects directly the dynamics of the two species. To describe the spatial distribution of the species we use a model based on Lotka-Volterra (LV) equations. By writing them in a mean field form, the corresponding moment equations for the species concentrations are obtained in Gaussian approximation. In this formalism the system dynamics is analyzed for different values of the multiplicative noise intensity. Finally by comparing these results with those obtained by direct simulations of the time discrete version of LV equations, that is coupled map lattice (CML) model, we conclude that the anticorrelated oscillations of the species densities are strictly related to non-overlapping spatial patterns.     

Diffusion in flashing periodic potentials

The one-dimensional overdamped Brownian motion in a symmetric periodic potential modulated by external time-reversible noise is analyzed. The calculation of the effective diffusion coefficient is reduced to the mean first passage time problem. We derive general equations to calculate the effective diffusion coefficient of Brownian particles moving in arbitrary supersymmetric potential modulated by: (i) an external white Gaussian noise and (ii) a Markovian dichotomous noise. For both cases the exact expressions for the effective diffusion coefficient are derived. We obtain acceleration of diffusion in comparison with the free diffusion case for fast fluctuating potentials with arbitrary profile and for sawtooth potential in case (ii). In this case the parameter region where this effect can be observed is given. We obtain also a finite net diffusion in the absence of thermal noise. For rectangular potential the diffusion slows down, for all parameters of noise and of potential, in comparison with the case when particles diffuse freely.     

Nonlinear mean field Fokker-Planck equations. Application to the chemotaxis of biological populations

We study a general class of nonlinear mean field Fokker-Planck equations in relation with an effective generalized thermodynamical (E.G.T.) formalism. We show that these equations describe several physical systems such as: chemotaxis of bacterial populations, Bose-Einstein condensation in the canonical ensemble, porous media, generalized Cahn-Hilliard equations, Kuramoto model, BMF model, Burgers equation, Smoluchowski-Poisson system for self-gravitating Brownian particles, Debye-Hückel theory of electrolytes, two-dimensional turbulence... In particular, we show that nonlinear mean field Fokker-Planck equations can provide generalized Keller-Segel models for the chemotaxis of biological populations. As an example, we introduce a new model of chemotaxis incorporating both effects of anomalous diffusion and exclusion principle (volume filling). Therefore, the notion of generalized thermodynamics can have applications for concrete physical systems. We also consider nonlinear mean field Fokker-Planck equations in phase space and show the passage from the generalized Kramers equation to the generalized Smoluchowski equation in a strong friction limit. Our formalism is simple and illustrated by several explicit examples corresponding to Boltzmann, Tsallis, Fermi-Dirac and Bose-Einstein entropies among others.     

姿态倾斜对时-空联合调制型干涉成像光谱仪成像质量的影响

时空联合调制型干涉成像光谱仪获取的像面干涉图是带有干涉条纹的二维空间图像,具有对姿态变化敏感的特点.根据该类仪器的成像过程,在竖直摄影时,相邻两帧像面干涉图之间的像移量为一列像元;偏离竖直摄影时,由于像面干涉图的几何变形或旋转,会引入非正常像移.利用共线方程导出了这一非正常像移量的表达式.利用仿真计算说明:这一非正常像移会在像面干涉图序列中不断积累,导致提取出的物体干涉信息失真.在竖直摄影而平台指向精度较低、倾斜摄影、探测器阵列的安装方向精度较低或者航空成像且存在偏流角时,必须对像面干涉图进行有效校正,才能保证最终反演出的物体光谱的真实性.     

基于频谱分析的匀速运动模糊图像模糊方向识别

点扩展函数的设置是图像复原中的关键问题,对于匀速直线运动模糊图像,运动方向和模糊长度决定了点扩展函数。根据运动模糊图像和原始图像在频谱上存在的对应关系,即运动模糊图像频谱存在着对应于传递函数零点的暗条纹,提出对运动模糊图像,通过二维傅里叶变换、二值化以及Radon变换检测运动模糊图像频谱图上暗条纹的方向和位置,来实现运动方向测量的方法。用该方法对模糊图像进行检测,模糊方向的识别精度小于1°。实验证明该方法可以实现平面内任意方向运动的测量。     

与二项式光场相互作用的运动原子熵压缩

运用量子信息熵理论,研究了二项式光场与运动二能级原子相互作用过程中运动原子的信息熵压缩。讨论了不同的原子初态和场的有关参数对原子信息熵压缩的影响。结果表明：选择原子初态、场模结构、场调节参数及原子运动速度可以调控原子信息熵的压缩方向、偶极矩分量值和压缩周期;适当的选择参数可得到持续性的原子信息熵压缩。     

Lattice Lotka-Volterra model with long range mixing

A spatio-temporal process in the Lattice Lotka Volterra (LLV) model, when realized on low dimensional support, is studied. It is shown that the introduction of a long-range mixing causes a drastic change in the system’s behavior, which transits from small random-like fluctuations to global oscillations when the mixing rate transcends above a critical point. The amplitude of the induced oscillations is well defined by the mixing rate and is insensitive to the initial conditions and the lattice size variations. The observed behavior essentially differs from that predicted by the Mean-Field model which is conservative. The oscillations are of limit-cycle type and appear as a stochastic analog of a Hopf bifurcation.     

Active Brownian motion models and applications to ratchets

We give an overview over recent studies on the model of Active Brownian Motion (ABM) coupled to reservoirs providing free energy which may be converted into kinetic energy of motion. First, we present an introduction to a general concept of active Brownian particles which are capable to take up energy from the source and transform part of it in order to perform various activities. In the second part of our presentation we consider applications of ABM to ratchet systems with different forms of differentiable potentials. Both analytical and numerical evaluations are discussed for three cases of sinusoidal, staircaselike and Mateos ratchet potentials, also with the additional loads modelled by tilted potential structure. In addition, stochastic character of the kinetics is investigated by considering perturbation by Gaussian white noise which is shown to be responsible for driving the directionality of the asymptotic flux in the ratchet. This stochastically driven directionality effect is visualized as a strong nonmonotonic dependence of the statistics of the right versus left trajectories of motion leading to a net current of particles. Possible applications of the ratchet systems to molecular motors are also briefly discussed.     

Accounting for the energies and entropies of kinesin’s catalytic cycle

When the processive motor protein kinesin walks along the biopolymer microtubule it can occasionally make a backward step. Recent single molecule experiments on moving kinesin have revealed that the forward-to-backward step ratio decreases exponentially with the load force. Carter and Cross (Nature 435, 308-312, 2005) found that this ratio tightly followed 802 × exp[−0.95F], where F is the load force in piconewtons. A straightforward analysis of a Brownian step leads to L/(2k _B T) as the factor in front of the load force, where L is the 8 nm stepsize, k _B is the Boltzmann constant, and T is the temperature. The factor L/(2k _B T) does indeed equal 0.95 pN⁻¹. The same analysis shows how the 802 prefactor derives from the power stroke energy G as exp[G/(2k _B T)]. There are indications that the power stroke derives from the entropically driven coiling of the 30 amino acid neck linker that connects the two kinesin heads. This idea is examined and consequences are deduced.