Luminescent Properties of a Polymer Photoluminescent Composite Containing the Binuclear (EU,TB) Complex as an Emitter

Uninuclear europium (Eu), as well as binuclear Eu and terbium (Tb), complexes were synthesized using acrylic acid (AA) as the first ligand and 1,10-phenanthroline (Phen) as the second ligand. The relative weight ratio of the europium (III) (Eu³⁺) to terbium (III) (Tb³⁺) ions of the binuclear complex was 1:1 as determined via energy dispersive X-ray analysis. The structures of the Eu(AA)₃Phen and Eu_0.5Tb_0.5(AA)₃Phen complexes were characterized by Fourier transform infrared spectroscopy. A series of tri-cellulose acetate (TCA)/ the Eu(AA)₃Phen and TCA/Eu_0.5Tb_0.5(AA)₃Phen composites were prepared by solution blending, and their luminescent properties were investigated by fluorescence spectrophotometry. The excitation spectra of all composites indicated that the TCA matrix probably affected the energy absorption and transfer of organic ligands. In TCA/Eu_0.5Tb_0.5(AA)₃Phen composites the introduced Tb³⁺ ions had some influence on energy absorption and transfer of organic ligands; the energy transfer process of the complex is suggested to be as follows: Phen→AA→Tb³⁺ion→Eu³⁺ion. The emission spectra indicated that the luminescent intensity of the TCA/Eu_0.5Tb_0.5(AA)₃Phen composites was noticeably stronger than that of the TCA/Eu(AA)₃Phen composites, suggesting that the comparatively stable and high-efficiency energy transfer process was only slightly influenced by the TCA matrix. In summary, the TCA/Eu_0.5Tb_0.5(AA)₃Phen (90/10) composite possesses fine luminescent properties for potential usage as red fluorescent materials.     

n × n 上三角算子矩阵的单值扩张性以及应用*

设X_i是无穷维复Banach空间, L(X_j,X_i)是X_j到X_i上的有界线性算子全体.考虑 n × n 上三角算子矩阵T=(T_ij)_1≤j≤n, 其中T_ij L(X_j,X_i),1≤j≤n; T_ij=0, i>j.本文研究了T的单值扩张性, 通过考察集合S(T)={λ∈C}: T在点λ没有SVEP},证明了S(T)在i=1 ? nS(T_i)中退化,进而给出等式S(T)=i=1 ? n S(T_i)成立的条件. 同时, 考察了T的单值扩张性扰动,得到了S(T)保持对角稳定时T_i所需的条件并予以证明, 同时举例说明这些条件的合理性.最后, 给出单值扩张性关于谱σ(T)和局部谱σT (x)的应用, 得到了谱扰动和局部谱扰动不变的新条件.     

Two-Phase Image Segmentation by Nonconvex Nonsmooth Models with Convergent Alternating Minimization Algorithms

Two-phase image segmentation is a fundamental task to partition an image into foreground and background. In this paper, two types of nonconvex and nonsmooth regularization models are proposed for basic two-phase segmentation. They extend the convex regularization on the characteristic function on the image domain to the nonconvex case, which are able to better obtain piecewise constant regions with neat boundaries. By analyzing the proposed non-Lipschitz model, we combine the proximal alternating minimization framework with support shrinkage and linearization strategies to design our algorithm. This leads to two alternating strongly convex subproblems which can be easily solved. Similarly, we present an algorithm without support shrinkage operation for the nonconvex Lipschitz case. Using the Kurdyka-Łojasiewicz property of the objective function, we prove that the limit point of the generated sequence is a critical point of the original nonconvex nonsmooth problem. Numerical experiments and comparisons illustrate the effectiveness of our method in two-phase image segmentation.     

Hα∞到Hβ∞复合算子的线性组合

设B是N维复空间C^N中的开单位球,φ_i为B上的解析自映射,H_α^∞表示定义在单位球上的加权解析函数空间.本文主要研究的是从空间H_α^∞到H_β^∞上的复合算子线性组合■的紧致性,其中λ_i(i=1,2,…,M)是非零常数.另外,根据紧致性等价条件,得出算子差分对(C_φ1-C_φ2)-(C_φ3-C_φ1)是紧致的当且仅当C_φ1-C_φ2与C_φ3-C_φ1都是紧致的算子.     

基于VMM的SATA控制器功能验证

针对专用集成电路(ASIC)设计中功能验证的效率和完备性问题,以验证方法学手册(VMM)为基础搭建了串行高级技术附件(SATA)控制器分层式验证平台.验证组件的实现大量重用验证知识产权核(VIP),在采用随机激励的基础上以覆盖率统计驱动验证的过程,根据SATA控制器的功能设计记分牌进行结果的自动化比对.实验结果表明,这些方法提高了功能验证的效率,保证了验证的完备性,最终功能覆盖率达到98.25%.     

Quantaloids Describing Causation and Propagation of Physical Properties

A general principle of causal duality for physical systems, lying at the base of representation theorems for both compound and evolving systems, is proved; formally it is encoded in a quantaloidal setting. Other particular examples of quantaloids and quantaloidal morphisms appear naturally within this setting; as in the case of causal duality, they originate from primitive physical reasonings on the lattices of properties of physical systems. Furthermore, an essentially dynamical operational foundation for studying physical systems is outlined; complementary as it is to the existing static operational foundation, it leads to the natural axiomatization of causal duality in operational quantum logic.     

烷基苯的热力学性质与分子拓扑指数的关系研究

此文分析了烷基苯的结构特点，以分子的拓扑指数为结构参数，研究了苯、烷基系列的燃烧热，生成自由能等八种热力学性质与结构参数的关系，提出计算热力学性质的一个通用关系式Ｙ＝ａ·Ｎ＋ｂ·Ｒ＋ｃ·ＮＲ＋ｄ，用计算机处理，得到一系列经验公式，计算结果表明：烷基苯系列的热力学性质与拓扑指数相关性能很好。     

Growth,optical, mechanical and electrical studies of nonlinear optical crystal: l-Valinium oxalate

l-Valinium oxalate (LVO) single crystal has been grown by solution growth technique at room temperature. The crystal structure and lattice parameters were determined for the grown crystal by single crystal X-ray diffraction studies. Optical constants like band gap, refractive index, reflectance, extinction coefficient and electric susceptibility were determined from UV–vis–NIR spectrum. The microhardness studies reveal the mechanical strength of the grown crystal. The dielectric constant, dielectric loss and AC conductivity of the compound were calculated at different temperatures and frequencies to analyze the electrical properties. Nonlinear optical property was discussed to confirm the SHG efficiency of the grown crystal.     

Preparation and Thermal Properties of Boron-Containing o-Cresol-Formaldehyde Resin/Octa(aminophenyl)-POSS Nanocomposites

The boron-containing o-cresol-formaldehyde resin (BoCFR) and octa(aminophenyl) polyhedral oligomeric silsesquioxane (OAP-POSS) were synthesized, and the BoCFR/OAP-POSS nanocomposite prepared via an in-situ method. The curing process of the resin was characterized by Fourier transform infrared (FTIR). The thermal properties and dynamic mechanical properties of the nanocomposites were investigated. The results show that the maximal mechanical loss temperature (T_p) increased with increasing OAP-POSS content. When the content of OAP-POSS was 10 wt% the T_p was over 200°C, 27°C higher than the pure BoCFR. The BoCFR/OAP-POSS nanocomposite had better thermal stablitity than the pure BoCFR. The residual weight of the o-cresol-formaldehyde resin was only 6.13 wt% at 600°C. But the residual weight of the pure BoCFR was 55.73 wt% at 600°C, and the residual weights of the BoCFR nanocomposites were all higher than pure BoCFR. The residual weight of the BoCFR nanocomposite was 63.2 wt% at 600°C and 21.83 wt% at 900°C when the OAP-POSS content was 10 wt%. The weight loss of BoCFR/OAP-POSS nanocomposite can be divided primarily into two temperature stages, from 430°C to 550°C and from 550°C to 900°C. The main thermal degradation reaction follows first order kinetics.     

A study of texture in PVC gels by infrared dichroism and X-ray diffraction

The main body of the present work is a summary of the extensive account in Ref. 1 to which we have to refer the reader for most of the details. Additional material is being included where explicitly stated.