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41.
Mixed-metal sulfido cluster [(PdCl2)(Cp*Ir)2(μ3-S)2] (Cp*=η5-C5Me5) dissolved in CH2Cl2 reacted with two equivalent of L (L=nicotinamide, isonicotinamide, or N-methylnicotinamide) in the presence of AgBF4 to give the cationic clusters [(PdL2)(Cp*Ir)2(μ3-S)2][BF4]2. The single-crystal X-ray diffraction studies of these products have disclosed that in the solid state the PdIr2S2 cores are self-assembled to form one-dimensional chains through the intermolecular hydrogen-bonding between the amide groups for L=nicotinamide or two-dimensional sheets via the hydrogen-bonding between the amide groups and the BF4 anions for L=isonicotinamide, whereas no organization of the cluster cores is observed for L=N-methylnicotinamide. 相似文献
42.
After the next revision of the ISO-standards for hardness testing (ISO 6506–6508) an estimation of the uncertainty (ISO/IEC 17025, ISO 5725) is mandatory. The two proposed approaches of part one (ISO 6506–6508) of the ISO Standards for hardness are exemplified. The calculation approach implemented in an Excel-based file, which is available via , is announced.Presented at the Metro Trade Workshop on Traceability and Measurement Uncertainty in Testing, 30–31 January 2003, Berlin, Germany 相似文献
43.
Nonequilibrium Brownian dynamics simulations of shear thinning in concentrated colloidal suspensions
Gerald Wilemski 《Journal of statistical physics》1991,62(5-6):1239-1253
The effect of interparticle forces on shear thinning in concentrated aqueous and nonaqueous colloidal suspensions was studied using nonequilibrium Brownian dynamics. Hydrodynamic interactions among particles were neglected. Systems of 108 particles were studied at volume fractions of 0.2 and 0.4. For the nonaqueous systems, shear thinning could be correlated with the gradual breakup of small flocs present because of the weak, attractive secondary minimum in the interparticle potential. At the highest shear rate for=0.4, the particles were organized into a hexagonally packed array of strings. For the strongly repulsive aqueous systems, the viscosity appeared to be a discontinuous function of the shear rate. For=0.4, this discontinuity coincided with a transition from a disordered state to a lamellar structure for the suspension. 相似文献
44.
In spite of Sinai's result that the decay of the velocity autocorrelation function for a random walk on
d
(d=2) can drastically change if local impurities are present, it is shown that local impurities can not abolish weak convergence to the Brownian motion if d2. 相似文献
45.
利用破产理论和随机控制理论研究保险基金最优投资策略,建立生存概率最大化的目标函数,得到最优投资策略满足的随机微分方程;在初始金逼近0时得到保险基金的最优投资策略的显示解;采用递推算法,得到初始准备金为任意值时的最优投资策略. 相似文献
46.
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48.
In this paper we investigated the stability of fractional order fuzzy cellular neural networks with leakage delay and time varying delays. Based on Lyapunov theory and applying bounded techniques of fractional calculation, sufficient criterion are established to guarantee the stability. Hybrid feedback control is applied to derive the proposed results. Finally, numerical examples with simulation results are given to illustrate the effectiveness of the proposed method. 相似文献
49.
利用理论分析和数值计算的方法,研究了偏置磁极周期会切磁铁产生的、可用于带状电子束宽边聚焦的边聚焦场。结果表明:增加偏置长度,减小电子束通道宽度,增大磁极轴向长度可以在基本不改变边聚焦场在x方向上分布特性的前提下提高幅值;增大电子束通道的高度,增大磁极厚度均可以减小边聚焦场在x方向上分布曲线的曲率,但同时其幅值也会降低,该降低可利用前述方法予以补偿。在对带状电子束宽边聚焦进行束匹配时,可以先进行曲率匹配,再进行幅值匹配。在进行参数选择时,应合理选择束通道高度和磁极厚度的取值,以避免束通道内的边聚焦场在x方向上的分布出现曲率反向。 相似文献
50.
Summary Recently much attention has been directed to the validation of analytical methods. The level of validation will depend on the method application. If a method is developed for general use, for instance by different analysts, instruments or laboratories, then the effect of these changes need evaluation. This is normally referred to as ruggedness testing, where the limitations of the method to changes in the specified conditions are examined.This paper examines the use of Plackett-Burman fractional factorial experiment designs for ruggedness testing in high performance liquid chromatography (HPLC). The ability of these designs to identify confounding effects is applied to the stability indicating analysis of Salbutamol and its major degradation product, AH4045. The results show that confounding effects, proving extremely pertinent to HPLC, can be identified.The assay proved rugged to most tested changes although not to the use of column packing material from different manufacturers. 相似文献