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991.
Bruce J. West Raoul Kopelman Katja Lindenberg 《Journal of statistical physics》1989,54(5-6):1429-1439
The conditions for macroscopic segregation ofA andB in a steady-stateA+B 0 reaction are studied in infinite systems. Segregation occurs in one and two dimensions and is marginal ford=3. We note the dependence of these results on the precise experimental conditions assumed in the theory. We also note the difference between these results and our earlier ones for finite systems where the critical dimension isd=2. 相似文献
992.
P. Calderoni A. Pellegrinotti E. Presutti M. E. Vares 《Journal of statistical physics》1989,55(3-4):523-577
We consider a system of spins which have values ±1 and evolve according to a jump Markov process whose generator is the sum of two generators, one describing a spin-flipGlauber process, the other aKawasaki (stirring) evolution. It was proven elsewhere that if the Kawasaki dynamics is speeded up by a factor –2, then, in the limit 0 (continuum limit), propagation of chaos holds and the local magnetization solves a reaction-diffusion equation. We choose the parameters of the Glauber interaction so that the potential of the reaction term in the reaction-diffusion equation is a double-well potential with quartic maximum at the origin. We assume further that for each the system is in a finite interval ofZ with –1 sites and periodic boundary conditions. We specify the initial measure as the product measure with 0 spin average, thus obtaining, in the continuum limit, a constant magnetic profile equal to 0, which is a stationary unstable solution to the reaction-diffusion equation. We prove that at times of the order –1/2 propagation of chaos does not hold any more and, in the limit as 0, the state becomes a nontrivial superposition of Bernoulli measures with parameters corresponding to the minima of the reaction potential. The coefficients of such a superposition depend on time (on the scale –1/2) and at large times (on this scale) the coefficient of the term corresponding to the initial magnetization vanishes (transient bimodality). This differs from what was observed by De Masi, Presutti, and Vares, who considered a reaction potential with quadratic maximum and no bimodal effect was seen, as predicted by Broggi, Lugiato, and Colombo. 相似文献
993.
We prove that Gibbs states for the Hamiltonian
, with thes
x varying on theN-dimensional unit sphere, obtained with nonrandom boundary conditions (in a suitable sense), are almost surely rotationally invariant if
withJ
xy i.i.d. bounded random variables with zero average, 1 in one dimension, and 2 in two dimensions. 相似文献
994.
Thomas Unnerstall 《Journal of statistical physics》1989,54(1-2):379-403
The irreversible macroscopic dynamics of the Josephson junction coupled to external wires acting as a current source is derived rigorously from the underlying microscopic Hamiltonian quantum mechanics. The external systems are treated in the singular coupling limit. The use of this limit is explicitly justified via an interpretation of the singular coupling limit in terms of the relative magnitudes of system, reservoir, and coupling energies. The qualitative behavior of the macroscopic dynamical equations is shown to depend sensitively and crucially on the interaction between the wires and the superconductors and on the size of the wires: the dc Josephson effect only happens when one lets Cooper pairs be driven into the junction by collective (i.e., small) reservoirs. 相似文献
995.
Fabio Martinelli Enzo Olivieri Elisabetta Scoppola 《Journal of statistical physics》1989,55(3-4):477-504
We apply previous results on the pathwise exponential loss of memory of the initial condition for stochastic differential equations with small diffusion to the problem of the asymptotic distribution of the first exit times from an attracted domain. We show under general hypotheses that the suitably rescaled exit time converges in the zero-noise limit to an exponential random variable. Then we extend the results to an infinite-dimensional case obtained by adding a small random perturbation to a nonlinear heat equation. 相似文献
996.
负载型双金属簇催化剂的多相一氧化碳加氢反应性能索全伶,李晔(内蒙古工业大学化学工程系,呼和浩特010062)殷元骐,金道森(中国科学院兰州化学物理研究所,兰州730000)关键词一氧化碳加氢,多相催化,双金属簇催化剂,钾效应。1.引言异核金属羰基簇作... 相似文献
997.
纳秒级激光闪光光解装置可用于有机光化学、光物理过程,瞬态发光和吸收的动力学过程的研究,在不改变原装置整体布局和结构的基础上,建立了有机非线性光学材料的二阶非线性系数测定方法,并为国家863专家委员会承担过仲裁测定。 相似文献
998.
应用全倒易空间X 射线散射理论分析(FRS XRSA)与SAXS研究了HEPP在应变(ε)与回复(R)过程中结晶、取向与超结构的变化.结果指出,ε可以诱发结晶,但当ε≥30%后,结晶度(XWC)趋于不变:ε可以导致晶粒破碎;ε与R对取向分布与平均取向基本上无影响,这符合片晶平行分离模型,而非叶簧弯曲模型;发现,在ε≤30%时,层状片晶的分离为主要过程,而当ε>30%后,则分离的片晶会发生断层滑移;ε可以诱发微孔,类似地当ε>20%,微孔尺寸亦趋不变.从凝聚态结构阐明了HEPP在ε R过程中不同阶段的结构变化 相似文献
999.
T. S. Martins J. R. Matos G. Vicentini P. C. Isolani 《Journal of Thermal Analysis and Calorimetry》2005,82(1):77-82
Summary Rare earth picrate (RE) complexes with L-lysine (Lys) were synthesized and characterized. Elemental analysis (CHN), EDTA titrations and thermogravimetry data suggest
a general formula RE(pic)3·2Lys·2H2O, where RE=La-Lu (without Pm) and Y, pic=picrate). IR spectra suggest that Lys is coordinated to the central ion through the nitrogen of the α-amino group. Parameters
obtained from the absorption spectrum of the Nd compound indicated that the metal-ligand bonds are essentially electrostatic.
Emission spectrum and biexponential behavior of the luminescence decay of the Eu compound suggest the existence of polymeric
species. Thermogravimetric/derivative thermogravimetric (TG/DTG) and differential scanning calorimetry (DSC) curves of all
complexes are very similar, with five events. The final products are the corresponding rare earth oxides and their X-ray diffraction
patterns are identical to the calcinated oxides.</o:p> 相似文献
1000.
Simultaneous separation and identification of hashish constituents by coupled liquid chromatography-mass spectrometry (HPLC-MS) 总被引:1,自引:0,他引:1
C. Rustichelli V. Ferioli F. Vezzalini M. C. Rossi G. Gamberini 《Chromatographia》1996,43(3-4):129-134
Summary This paper reports the use of liquid chromatography for the separation and determination of the major cannabinoids extracted from hashish samples. The direct coupling to the mass spectrometer enables the selective identification both of neutral and acidic cannabinoids. The developed method does not require any preliminary derivatization and should, therefore, be of interest in forensic analysis for simple and unequivocal determination of hashish constituents.Part of this work was presented at the 2nd Italian-Spanish Joint Meeting of Medicinal Chemistry, 30 August–3 September 1995, Ferrara, Italy. 相似文献