全文获取类型
收费全文 | 76181篇 |
免费 | 5524篇 |
国内免费 | 4731篇 |
专业分类
化学 | 31506篇 |
晶体学 | 476篇 |
力学 | 5890篇 |
综合类 | 708篇 |
数学 | 20423篇 |
物理学 | 27433篇 |
出版年
2024年 | 127篇 |
2023年 | 726篇 |
2022年 | 1718篇 |
2021年 | 1823篇 |
2020年 | 1869篇 |
2019年 | 1863篇 |
2018年 | 1565篇 |
2017年 | 1797篇 |
2016年 | 2242篇 |
2015年 | 1804篇 |
2014年 | 2803篇 |
2013年 | 5167篇 |
2012年 | 3109篇 |
2011年 | 3402篇 |
2010年 | 2860篇 |
2009年 | 4207篇 |
2008年 | 4589篇 |
2007年 | 5070篇 |
2006年 | 4226篇 |
2005年 | 3453篇 |
2004年 | 2943篇 |
2003年 | 3151篇 |
2002年 | 3470篇 |
2001年 | 2647篇 |
2000年 | 2532篇 |
1999年 | 2186篇 |
1998年 | 2100篇 |
1997年 | 1373篇 |
1996年 | 1218篇 |
1995年 | 1067篇 |
1994年 | 1088篇 |
1993年 | 863篇 |
1992年 | 951篇 |
1991年 | 639篇 |
1990年 | 576篇 |
1989年 | 471篇 |
1988年 | 457篇 |
1987年 | 418篇 |
1986年 | 371篇 |
1985年 | 384篇 |
1984年 | 374篇 |
1983年 | 201篇 |
1982年 | 315篇 |
1981年 | 381篇 |
1980年 | 333篇 |
1979年 | 345篇 |
1978年 | 310篇 |
1977年 | 248篇 |
1976年 | 209篇 |
1973年 | 141篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
121.
《Journal of Chemical Sciences》2005,117(5):525-531
The silicon atom may increase its coordination number to values greater than four, to form pentacoordinated compounds. It
has been observed experimentally that, in general, pentacoordinated compounds show greater reactivity than tetracoordinated
compounds. In this work, density functional theory is used to calculate the global softness and the condensed softness of
the silicon atom for SiH
n
F4−n
and SiH
n
F
5−n
1−
. The values obtained show that the global and condensed softness are greater in the pentacoordinated compounds than in the
tetracoordinated compounds, a result that explains the enhanced reactivity. If the results are analysed through a local version
of the hard and soft acids and bases principle, it is possible to suggest that in nucleophilic substitution reactions, soft
nucleophiles preferably react with SiH
n
F
5−n
1−
, and hard nucleophiles with SiH
n
F4−n
. 相似文献
122.
Pavla Fialová Inmaculada Robina Petr Sedmera Lucie Petrásková-Hušáková 《Tetrahedron letters》2005,46(50):8715-8718
Glycosyl azides are new efficient donors for glycosidases. Their high water solubility facilitates transglycosylations with comparable or better yields than common O-glycosides. The azido group totally changes the β-GalNAc-ase/β-GlcNAc-ase ratio in β-N-acetylhexosaminidases (from the usual 0.3-1.0 to <0.01), contrary to all known aglycons. 相似文献
123.
In this paper, we consider questions related to the structure of inverse matrices of linear bounded operators acting in infinite-dimensional complex Banach spaces. We obtain specific estimates of elements of inverse matrices for bounded operators whose matrices have a special structure. Matrices are introduced as special operator-valued functions on an index set. The matrix structure is described by the behavior of the given function on elements of a special partition of the index set. The method used for deriving the estimates is based on an analysis of Fourier series of strongly continuous periodic functions. 相似文献
124.
Marianna Pensky 《Annals of the Institute of Statistical Mathematics》2002,54(1):83-99
The traditional empirical Bayes (EB) model is considered with the parameter being a location parameter, in the situation when the Bayes estimator has a finite degree of smoothness and, possibly, jump discontinuities at several points. A nonlinear wavelet EB estimator based on wavelets with bounded supports is constructed, and it is shown that a finite number of jump discontinuities in the Bayes estimator do not affect the rate of convergence of the prior risk of the EB estimator to zero. It is also demonstrated that the estimator adjusts to the degree of smoothness of the Bayes estimator, locally, so that outside the neighborhoods of the points of discontinuities, the posterior risk has a high rate of convergence to zero. Hence, the technique suggested in the paper provides estimators which are significantly superior in several respects to those constructed earlier. 相似文献
125.
长江中下游的主要防洪工程是长江干堤 ,长江堤防线路长、工程浩大、堤基工程地质水文地质条件复杂 ,涉及大量的已有地质数据和资料。今后在整治加固堤防的工程地质勘察工作中 ,还需随时进行数据的收集、存储、检索、分析、统计和维护 ,随时调用这些数据进行综合处理、编制报告和图件 ;在防汛期间可以针对堤防险工险段的险情 ,随时查询和调用有关的资料、数据或者图件 ,提供采取抢险措施决策的地质依据。这既提高了地质数据的利用价值和利用率 ,又保证了信息的准确性、完整性和共享性。因此 ,建立合理的长江堤防工程地质信息处理模型及其成熟的技术方法具有重要的意义。 相似文献
126.
抓好数学建模竞赛 推动数学教学改革 总被引:5,自引:0,他引:5
本文通过近几年组织数学建模教学和指导学生参加竞赛的实践 ,探索抓好数学建模竞赛 ,促进数学教学改革 ,推动数学素质教育 ,提高人才培养质量的途径、措施和方法 相似文献
127.
The current state of using expert system (ES) techniques for statistics is expounded through the difficulties of defining the notion of statistical expert system (SES) and through several well-known examples. The main characteristics of statistical expertise, and particularly the important concept of strategy are emphasized. The current state of SESs is seen in the context of the global trend of the evolution of ES, i.e. within the growth of second generation expert system (SGESs). The knowledge base of these ESs represent an attempt to represent not only experts' knowledge but also the way experts acquire their expertise, thanks to the existence of an underlying model. We show through many examples how far SESs are and/or will be able to be SGESs. 相似文献
128.
Pál Sohár Gábor Bernáth Géza Stájer Angela E. Szabo 《Magnetic resonance in chemistry : MRC》1989,27(9):872-876
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments. 相似文献
129.
在非线性项满足全局Lipschitz条件下,本文研究了一类It型非线性时滞关联随机大系统的分散鲁棒控制问题.系统的时滞是关于状态和控制输入的.基于Lyapunov泛函及线性矩阵不等式(LMI)的分析方法,得到了无记忆状态反馈控制器使整个时滞关联随机大系统可镇定的充分条件. 相似文献
130.
Characterizations of the containment of a convex set either in an arbitrary convex set or in the complement of a finite union
of convex sets (i.e., the set, described by reverse-convex inequalities) are given. These characterizations provide ways of
verifying the containments either by comparing their corresponding dual cones or by checking the consistency of suitable associated
systems. The convex sets considered in this paper are the solution sets of an arbitrary number of convex inequalities, which
can be either weak or strict inequalities. Particular cases of dual characterizations of set containments have played key
roles in solving large scale knowledge-based data classification problems where they are used to describe the containments
as inequality constraints in optimization problems. The idea of evenly convex set (intersection of open half spaces), which
was introduced by W. Fenchel in 1952, is used to derive the dual conditions, characterizing the set containments. 相似文献