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101.
Electrochemical oxidation of uric acid in phosphate-containing supporting electrolytes between pH 3–9 at a reticulated vitreous carbon electrode in a thin-layer spectroelectrochemical cell leads to formation of U.V.-absorbing intermediate species. Electrochemical reduction of the intermediate-containing solution leads to the partial regeneration of uric acid. This behavior provides compelling evidence that an imine-alcohol is one of the U.V.-absorbing intermediate species since only this compound may be expected to be reduced to a species which can regenerate uric acid. 相似文献
102.
Frank Caridi 《Journal of multivariate analysis》1983,13(1):52-66
For the problem of estimating the natural parameter of a p-dimensional exponential family, a characterization of regular limits of Bayes procedures is obtained which generalizes results of Sacks [14], Brown [3], and Berger and Srinivasan [1]. The form is deduced under regularity conditions for the loss function which are more general than squared error. As a corollary it is then stated that the class of procedures with this form is a complete class. The parameter space may be open, and when it is closed, the limits of Bayes procedures are generalized Bayes. 相似文献
103.
By a charge transfer mechanism for electrophilic aromatic substitution the logarithmic plot of overall rate constants for substitution against ionization potentials is correctly predicted. Also, orientation of substitution is found to be correlated with the hyperfine coupling constants of the aromatic radical cation. The presence of radical cations under the conditions of electrophilic substitution is discussed. 相似文献
104.
Christian L. Pedersen Ole Buchardt Sine Larsen Kenneth J. Watson 《Tetrahedron letters》1973,14(24):2195-2198
105.
106.
The adsorption of 12CO on Ir films evaporated under ultrahigh vacuum (UHV) conditions was studied using infrared reflection-absorption spectroscopy (IRAS). Only a single absorption band was observed at 300 K, shifting continuously from the “singleton” value ~2010 cm?1 at very low coverages to 2093 cm?1 at saturation coverage. This band is attributed to CO adsorbed on top of the surface atoms. Synchronously with this shift the bandwidth at half maximum intensity decreases from ~30 to 8 cm?1. The integrated peak area increases linearly with coverage up to a relative coverage (θr) of approximately 0.4, then the increase levels off and a maximum is observed. Upon continuing adsorption the intensity decreases slightly. In addition results are presented on adsorption at 300 K of 12CO?13CO isotopic mixtures. The coverage induced frequency shift is discussed in terms of a dipole-dipole coupling mechanism and it is concluded that intermolecular coupling can explain the shift (~83 cm?1) observed. The decrease in intensity at coverages > 0.4 is attributed to the formation of a compressed overlayer with part of the CO molecules adsorbed in a multicentre position with different spectral properties. No infrared bands of nitrogen adsorbed at 78 K could be detected at pressures up to 6.7 kPa (1 Pa = 0.0075 Torr, 1 Torr = 133.32 Pa). 相似文献
107.
Safe bounds in linear and mixed-integer linear programming 总被引:1,自引:0,他引:1
Current mixed-integer linear programming solvers are based on linear programming routines that use floating-point arithmetic. Occasionally, this leads to wrong solutions, even for problems where all coefficients and all solution components are small integers. An example is given where many state-of-the-art MILP solvers fail. It is then shown how, using directed rounding and interval arithmetic, cheap pre- and postprocessing of the linear programs arising in a branch-and-cut framework can guarantee that no solution is lost, at least for mixed-integer programs in which all variables can be bounded rigorously by bounds of reasonable size.
Mathematics Subject Classification (2000):primary 90C11, secondary 65G20 相似文献
108.
We provide an asymptotic formula for the number of labelled essential DAGs an and show that limnan/an=c, where an is the number of labelled DAGs and c13.65, which is interesting in the field of Bayesian networks. Furthermore, we present an asymptotic formula for the number of labelled chain graphs.Acknowledgment. I would like to thank Prof. Peter Grabner for his support and very helpful discussions, which where constitutive for this article. I am also thankful to the referees for their comments.This Research was supported by the Austrian Science Fund (FWF), START-Project Y96-MATFinal version received: January 28, 2004 相似文献
109.
DU Beiliang WANG Jian Department of Mathematics Suzhou University Suzhou China Nantong Vocational College Nantong China 《中国科学A辑(英文版)》2004,47(3)
Let K_(m,n) be a complete bipartite graph with two partite sets having m and nvertices, respectively. A K_(p,q)-factorization of K_(m,n) is a set of edge-disjoint K_(p,q)-factorsof K_(m,n) which partition the set of edges of K_(m,n). When p=i and q is a prime number,Wang, in his paper "On K_(1,k)-factorizations of a complete bipartite graph" (Discrete Math,1994, 126; 359-364), investigated the K_(1,q)-factorization of K_(m,n) and gave a sufficientcondition for such a factorization to exist. In the paper "K_(1,k)-factorizations of completebipartite graphs" (Discrete Math, 2002, 259: 301-306), Du and Wang extended Wang'sresult to the case that q is any positive integer In this paper, we give a sufficient conditionfor K_(m,n) to have a K_(p,q)-factorization. As a special case, it is shown that the Martin's BACconjecture is true when p: q=k: (k+1) for any positive integer k. 相似文献
110.
Connections between uniform exponential expansiveness and complete admissibility of the pair
are studied. A discrete version for a theorem due to Van Minh, Räbiger and Schnaubelt is presented. Equivalent characterizations of Perron type for uniform exponential expansiveness of evolution families in terms of complete admissibility are given. 相似文献