Synthesis and NMR assignment of pentacycloundecane precursors of potential pharmaceutical agents

The synthesis and complete NMR elucidation of eight novel pentacycloundecane (PCU) derivatives are reported. These compounds are precursors in the synthesis of PCU‐based anti‐tuberculosis (TB) agents and potential human immunodeficiency virus (HIV) protease inhibitors. Two‐dimensional (2D) NMR techniques were used to assign the NMR spectra for these compounds. Substitution of the cage molecule at (C‐8/11) further complicates the assignment, since some of the substituted alkyl chain groups overlap with the cage proton signals. The side chain heteroatoms also introduce a rare through‐space deshielding effect to some of the carbon atoms of the cage skeleton. Ring strain in the rigid cage skeleton appears to induce drastic electronic changes in some parts of the cage framework. This observation is more dramatic for the C‐4 methylene group of the cage diols and the cage ethers. Copyright © 2010 John Wiley & Sons, Ltd.     

A note on static spaces and related problems

In this paper we study static spaces introduced in Hawking and Ellis (1975)  [1], Fischer and Marsden (1975) [3] and Riemannian manifolds possessing solutions to the critical point equation introduced in Besse (1987)  [11], Hwang (2000)  [12]. In both cases, on the manifolds there is a function satisfying a particular Ricci–Hessian type equation (1.6). With an idea similar to that used in Cao et al. (2012)  [15], [16], we have made progress in solving the problem raised in Fischer and Marsden (1975)  [3] of classifying vacuum static spaces and in proving the conjecture proposed in Besse (1987)  [11] concerning manifolds admitting solutions to the critical point equation in general dimensions. We obtain even stronger results in dimension 3.     

Structural analysis of certain linear operators representing chemical network systems via the existence and uniqueness theorems of spectral resolution. VI*

The present Part VI of this series of articles provides a mathematical and methodical link between (i) fundamental methodology in the repeat space theory (RST), which is referred to as the approach via the aspect of form and general topology and which has universal unifying power to handle additivity problems of molecules that have many identical moieties, and (ii) frontier electron theory of reactivity indices. Using theoretical tools required to link (i) and (ii), we establish a theorem from which the Generalized Alpha Existence Theorem (a theorem essential in the RST and proved in the previous Part V) directly follows. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem 84: 389–400, 2001     

加权Lebesgue空间的对偶和嵌入

本文建立了加权Lebesgue空间的对偶空间，并且给出了在这些空间之间嵌入的必要条件。     

Metric Inequality, Subdifferential Calculus and Applications

In this paper we establish characterizations of Asplund spaces in terms of conditions ensuring the metric inequality and intersection formulae. Then we establish chain rules for the limiting Fréchet subdifferentials. Necessary conditions for constrained optimization problems with non-Lipschitz data are derived.     

On approximation of dual spaces and dual operators

We study the connection between equations which approximate an initial abstract linear equation and the adjoint one. We prove that the operator which is adjoint to the approximating one approximates the adjoint operator. As examples we consider adjoint linear integral equations and mutually dual linear programming problems.     

基于平稳小波和相空间重构的激光混沌预测

提出了一种激光混沌时间序列预测算法.该算法通过平稳小波分解，将原始数据序列分解为与原序列等长的尺度系数和小波系数，利用坐标延迟理论，重建各级尺度系数和各级小波系数的相空间,再根据混沌吸引子的稳定性和分形性,在相空间中对尺度系数和小波系数进行预测,进而通过平稳小波重构算法,实现了时间序列的非线性预测.该算法对数据可以进行更平滑的处理，比无小波算法预测的时间范围更长.通过仿真试验说明，原始时间数据序列被成功的重建，说明算法能够有效的对非线性动态系统的时间序列进行建模和预测.     

空间光束实时捕获、跟踪实验与分析

提出一种空间光束捕获、跟踪设计方案,在实验室条件下实现其主要功能,并对其定位精度和实时性进行了分析,结果表明：信标光定位处理的时间为25 ms,角度测量的相对误差为1.3％,显示出良好性能.同时,为由理论分析到实际星载PAT系统提供试验依据.     

关于算子连续映射

在算子开集理论中给出了算子拓扑空间的概念，并在该空间中讨论了算子连续映射，得到了算子连续映射的等价刻划。