偏硼酸锂-四硼酸锂熔融-电感耦合等离子体原子发射光谱(ICP-AES)法测定石膏中多组分含量

石膏在我国储量丰富,应用广泛,快速准确分析其成分含量对石膏资源的综合利用具有重要意义。针对酸溶法无法测定SiO2,碱熔法无法测定K2O、Na2O的问题,本文建立一种偏硼酸锂-四硼酸锂熔融-电感耦合等离子体发射光谱法同时测定石膏中CaO、SO3、Al2O3、Fe2O3、MgO、TiO2、K2O、Na2O、SiO2含量。实验优化了熔剂用量、熔融温度,结果表明采用试样与偏硼酸锂-四硼酸锂混合熔剂质量比例1：5,在铂金坩埚中1000 ℃熔融10 min,在超声条件下,于50 mL 10 %盐酸中浸取熔融物,能够有效分解试样而浸取待测组分。向标准溶液系列中加入偏硼酸锂-四硼酸锂-盐酸基体溶液以消除基体对测试结果的影响。各待测组分的校准曲线的相关性系数均大于0.9990,方法检出限在3~292 μg/g范围内;采用实验方法分别对国家一级标准物质GBW03109a、GBW03110和实际样品进行测定,标准物质的5次平行测试的相对标准偏差在0.14 %~8.86 %之间,测定结果的相对误差在0.03~8.75 %之间,测试结果与标准值无显著性差异;实际样品中各成分测定值的RSD（n=5）为0.24~8.80 %。该方法操作简单、准确度高、精密度好、检出限低,可以同时测定石膏中的多组分含量,能够为石膏资源综合利用调查评价提供一定的技术支撑 。     

闪烁体Y_2SiO_5:Ce的发光特性

Y_2SiO_5:Ce~(3+)(YSO:Ce)具有高密度、不吸潮以及良好的光输出和快速衰减的特性,是一种重要的闪烁材料。研究采用高温固相法制备Y_2SiO_5:Ce~(3+)+0.2%(YSO:Ce)。在低温及室温下,对闪烁体YSO:Ce的时间分辨发射光谱、激发光谱以及衰减曲线进行了测量和分析。YSO:Ce主要有两类发射,一是晶体的缺陷发射,发射中心在320 nm;二是掺杂的Ce~(3+)的5d→4f发射,发射中心在440 nm。只有当激发能量(E_x)大于材料带隙宽度(E_g)时才能够激发出晶体缺陷发射,对应慢速的激发发射过程,且低温时发射强度较大,当温度升高时有温度猝灭,在室温下时间分辨发射光谱中几乎观察不到晶体缺陷发射。对于发射中心位于440 nm Ce~(3+)的5d→4f能级发射,在60~300 nm范围内能够观察到多个激发峰,其中能量小于材料禁带宽度的激发是属于Ce~(3+)5d能级的直接激发带,对应快速的激发发射过程。在低温时能够观测到发光中心位于392和426 nm分立的发射峰,对应Ce~(3+)的5d→4f(~2F_(5/2),~2F_(7/2))的发射。当温度升高到室温时,光谱宽化,无法观测到分立的发射峰。在温度200和300 K时,当激发光的能量大于带隙宽度,衰减曲线有明显的上升沿,说明有能量传递给Ce~(3+)。     

A股上市公司内部人股票买卖行为及获利能力分析

系统地分析了2006年至2011年我国A股市场上市公司的内部人在二级市场的交易行为及其收益预测.结论表明:尽管在我国证券市场中存在针对内部人交易的法律法规,但总体上内部人在交易中仍然表现出良好的时机把握能力.不论是买入还是卖出,均能获得显著的超额收益.内部人交易超额收益的大小受到公司所有权性质、内部人类型等因素的影响.一方面,较于董事、监事等内部人,高管获利能力普遍较强,而其中董事长和总经理的获利能力最强;另一方面,由于我国特殊的公司所有权性质与晋升机制,使得国有上市公司的董事长和总经理利用内部人交易获利的动机小于非国有企业;规模越大的国有上市公司,其董事长和总经理通过内部人交易获取超额收益的程度也越小.     

Emission analysis of Li6LuY(BO3)3:Tb3+,Dy3+ phosphors

In this paper, we present the synthesis and luminescence properties of Tb³⁺ and Dy³⁺-doped lithium lutetium yttrium borate (Li₆LuY(BO₃)₃) phosphors. We have adopted the well-known solid state reaction method for the synthesis of these phosphors. The emission intensities of the synthesized phosphors were found to reach their maximum, when doped by 1 mol% of Tb³⁺ and 3 mol% of Dy³⁺, beyond which emission intensities decrease due to concentration quenching. The homogeneous phase, crystalline structure and uniform morphology of the synthesized phosphors were confirmed by X-ray diffraction analysis (XRD) and Scanning electron microscopy (SEM). The X-ray and UV–VIS-induced luminescence, decay time and CIE chromaticity were investigated for the synthesized phosphors.The X-ray induced integrated light yield was measured to be 82% for Li₆LuY(BO₃)₃:Tb³⁺ (LLYBO) and 59% for Li₆LuY(BO₃)₃:Dy³⁺ of that of commercially available X-ray imaging material; Gd₂O₂S:Tb³⁺ (Gadox).LLYBO:Tb³⁺ phosphor displayed five major emission bands that correspond to ⁵D_j → ⁷F_j transitions. The 1931 Commission Internationale de l'Eclairage (CIE) chromaticity coordinates were also measured.     

Emission efficiency of diamine derivatives of tris[4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono]europium

Diamine derivatives of tris[4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono]europium were synthesized and characterized by NMR, IR and UV-vis spectroscopy. The emission efficiency and decay times of the produced Eu(III) coordination complexes in acetone solutions were measured upon ligand excitation. The effect of the amine ligands was studied and the relation between the emission and the structure of the synthesized compounds was discussed.     

Analytical artifacts produced by a polycarbonate chamber compared to a Teflon chamber for measuring surface mercury fluxes

We found significant differences in mercury fluxes measured with a dynamic surface mercury flux chamber made of Teflon versus one made of polycarbonate. While both materials responded reasonably well when virgin materials were used, the polycarbonate chamber was found to exhibit significant chamber blanks under light after it was exposed to surface mercury fluxes of >100 ng/m²/h. Most significantly, the polycarbonate chamber blocked all wavelengths of light below ∼320 nm. Given that ultraviolet radiation plays an important role in soil mercury flux, the polycarbonate chamber was found to significantly underestimate observed fluxes from background soil in both high light conditions (by 1–4-fold) and under diffuse, low light conditions (by ∼10-fold). These results suggest that Teflon produces fewer analytical artifacts in the surface emission of mercury measured with a flux chamber than polycarbonate.     

Theoretical study of low-lying electronic states and emission spectra of the excimer ions NaHe and NaNe

Ab initio CASSCF calculations using the Gaussian basis set aug_cc_pVTZ developed by Dunning et al. specifically for calculations at the post-HF level was carried out for excimer NaHe⁺ and NaNe⁺ ions in order to determine spectroscopic characteristics and radiation lifetimes of their low-lying excited electronic states. The computed emission spectra of these were shown to be in good agreement with the experimental ones observed recently by Hammer et al. (Hyperfine Interactions 88 (1994) 151). Contrary to the earlier popular opinion, all excited electronic states of these ions, correlating with the limit Rg⁺+Na, and not just the radiating singlet states turn out to be bound. It was shown that under the conditions of an experiment similar to the one performed by Hammer et al., the excited triplet NaHe⁺(1³Σ⁺) states can decay as a result of their interactions with a high-energy Ar⁺ beam. This decay has to be accompanied with the formation of the ions He⁺, which in turn can interact with sodium atoms to yield the radiating NaHe⁺(2¹Σ⁺) states again and, thus to maintain the emission observed in the experiment.     

Atomic emission of anhydrous hydrogen bromide: Spectra from 200 to 900 nm by sealed inductively coupled plasma-atomic emission spectroscopy

Anhydrous hydrogen bromide, at concentrations of up to 25%, has been introduced into a sealed inductively coupled plasma system for spectrochemical analysis. The emission spectra of 15% anhydrous hydrogen bromide is reported over the spectral range of 200 to 900 nm from an enclosed inductively coupled plasma discharge operated at atmospheric pressure and 1.1 kW. More than 140 atomic Br I lines are identified and reported along with their relative intensities. Where possible, molecular band assignments of Br₂ are made. Impurities identified qualitatively include Fe, Sn, C, and Ni. The presence of these impurities were verified by gas phase hydrolysis and subsequent inductively coupled plasma-mass spectrometry analysis.     

碳纤维阴极发射均匀性的实验研究

 分别用自制浸渍碘化铯（CsI）针式环状碳纤维阴极和环状不锈钢阴极所产生的电子束轰击尼龙目击靶,研究碳纤维阴极发射均匀性。在碳纤维阴极电子束轰击的目击靶上得到了均匀的烧蚀痕迹,而不锈钢阴极电子束轰击的目击靶上烧蚀痕迹不均匀,表明碳纤维阴极发射电子束的均匀性优于不锈钢阴极。分析认为两阴极不同的发射机制及其所特有的材料性质和结构导致其发射电子束均匀性的差异。用光学显微镜和电子显微镜对不锈钢阴极尖端和碳纤维阴极尖端和侧面进行扫描,发现不锈钢阴极仅尖端处被烧蚀,而碳纤维阴极尖端和侧面都有烧蚀痕迹,验证了碳纤维阴极由场发射和表面闪络共同作用的发射机制的假设分析。     

Relating geologic units and mobility system kinematics contributing to Curiosity wheel damage at Gale Crater,Mars

Curiosity landed on plains to the north of Mount Sharp in August 2012. By June 2016 the rover had traversed 12.9 km to the southwest, encountering extensive strata that were deposited in a fluvial-deltaic-lacustrine system. Initial drives across sharp sandstone outcrops initiated an unacceptably high rate of punctures and cracks in the thin aluminum wheel skin structures. Initial damage was found to be related to the drive control mode of the six wheel drive actuators and the kinematics of the rocker-bogie suspension. Wheels leading a suspension pivot were forced onto sharp, immobile surfaces by the other wheels as they maintained their commanded angular velocities. Wheel damage mechanisms such as geometry-induced stress concentration cracking and low-cycle fatigue were then exacerbated. A geomorphic map was generated to assist in planning traverses that would minimize further wheel damage. A steady increase in punctures and cracks between landing and June 2016 was due in part because of drives across the sharp sandstone outcrops that could not be avoided. Wheel lifetime estimates show that with careful path planning the wheels will be operational for an additional ten kilometers or more, allowing the rover to reach key strata exposed on the slopes of Mount Sharp.