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991.
《Arabian Journal of Chemistry》2023,16(2):104412
Capacitive Deionization (CDI) is an emerging technology with great potential applications. Most researchers view it as a viable water treatment alternative to reverse osmosis. This research reports the preparation and application of a carbon aerogel polypyrrole (CA-PPy) composite for the desalination of NaCl solution by the hybrid CDI method. The carbon aerogel (CA) was prepared from a Resorcinol / Formaldehyde precursor by the sol–gel method. The aerogel obtained from the sol–gel was then pyrolysed in a tube furnace to form CA. Polypyrrole (PPy) was prepared by the Oxidative chemical polymerisation of pyrrole, ferric chloride hexahydrate (oxidant), and sodium dodecyl sulfate (dopant). A composite of CA and PPy was then prepared and used to modify carbon electrodes. The CA-PPy composite was characterised to verify its composition, morphology, thermal properties, and functional groups. The electrochemical properties of the material were determined by Cyclic voltammetry (CV) and Electrochemical impedance spectroscopy (EIS) tests. The electrochemical tests were done using a GAMRY potentiostat electrochemical workstation, a 1.0 M KCl was used as the electrolyte, and the applied potential window was (-0.2 to + 0.6) V for the CV test. The EIS test was done with the same concentration of KCl electrolyte at an applied potential of 0.22 V and at a frequency range of (0.1 – 100, 000) Hz. The optimal specific capacitance of the CA is 115F/g, and that of the composite is 360.1F/g, they were both obtained at a scan rate of 5 mV/s. The CDI desalination study of the CA-PPy composite showed a salt adsorption capacity (SAC) of 10.10 mg/g (300 mg/L NaCl solution) – 15.7 mg/g (800 mg/L NaCl solution) at 1.2 V applied voltage. The salt recovery efficiency of the electrode material in the 300 mg/L solution is 27 %, in the 500 mg/L solution, it is 20.12 %, and in the 800 mg/L solution, it is 15.41 %. The electrode material also showed good electrochemical stability after nine cycles of ion adsorption/desorption study. 相似文献
992.
P. Das;P. K. Karmakar 《Europhysics letters》2019,126(1)
We report the evolutionary dynamics of nonlinear nucleus-acoustic wave patterns excitable in a strongly coupled self-gravitating complex quantum degenerate plasma (QDP) systems. It is inertially composed of strongly correlated non-degenerate heavy nuclei and weakly coupled degenerate light nuclei treated classically. It is thermally constituted of non-relativistic and ultra-relativistic degenerate lighter electrons behaving quantum mechanically. Application of nonlinear perturbation analysis results in a conjugated pair of extended Korteweg-de Vries (e -KdV) equations of unique mathematical shape. The constructed numerical tapestry shows the collective excitations of a new conjugational pair of nonlinear eigenmode structures of gravito-electrosatic origin. The electrostatic potential fluctuations evolve as a distinct family of stable periodic symmetric waves resembling regular soliton-antisoliton pulse-trains; in contrast,the gravitational counterparts evolve as a unique extended class of asymmetric oscillatory solitons and non-monotonous compressive dispersive asymmetric pulse-trains. The microphysical influential dependencies of the eigenstructural patterns on various sensible plasma multi-parametric factors are illustratively analyzed in both the non-relativistic (NR) and ultra-relativistic (UR) limits of the non-local quantum electronic dynamics. The applicability of the explored results in wave kinetic phenomenological processes naturalistically relevant in diversified compact astro-objects and their ambient hydrodynamic atmospheres is summarily outlined.https://doi.org/10.1209/0295-5075/126/10001 相似文献
993.
994.
995.
Macro-scale deformation of granular solids comprising large number of grains (>106) are most efficiently described within the framework of continuum mechanics. It is notable, however that the micro-scale deformations in these materials are concentrated at the grain-boundaries or grain-contacts. Thus, the deformation energies in these systems must be modeled by considering the deformations concentrated in the neighborhood of the grain-boundaries or grain-contacts. To address this issue, grain-interactions has been widely described in the Hertzian sense by considering the relative movement of points on either side of a grain boundary or contact treated as an imperfect interface. This communication introduces the relevant kinematic variables given in the terms of the grain displacements, spins and size that can be used to estimate the relative movement of a grain boundary or contact. The macro-scale kinematic variables useful for continuum modeling are then identified with the grain-scale kinematic variables. The deformation energy density of the granular solid can thus be expressed both in terms of the grain-scale as well as the macro-scale kinematic variables providing the necessary pathway for micro-macro identification which can lead to non-classical micromorphic continuum models that incorporate grain-scale representation. 相似文献
996.
997.
In this paper, a physiological model of invasive blood-glucose (BG) measurement is employed to consider the diabetic treatment by the external auxiliary system, i.e., artificial pancreas (AP). For such system, there are two time delays, i.e., technological and liver's physiological delay, where the former comes from external auxiliary system with the active pancreas inputting. The technological delay and the infection degree of patients are considered as two controlled parameters to regulate the BG level of patients. This two parameters can also lead to the non-resonant double Hopf bifurcations. The classification and unfolding for the non-resonant double Hopf bifurcation are performed in terms of non-linear dynamics. The results show that such controlled parameters are very important. They can determine the efficiency for the diabetic treatment. It implies whether the diabetic patients recover or are still tormented by the simple or complex glucose fluctuation. The results have also been promising applications on analyzing, predicting and optimizing the medical outcome, evaluating the medical risk and feasibility. The physiological meaning in this paper is that one is able to achieve the better medical outcomes for the different patients by controlling the technological delay qualitatively. 相似文献
998.
A. Sjberg 《Nonlinear Analysis: Real World Applications》2009,10(6):3472-DECMA
We present the theory of double reductions of PDEs with two independent variables that admit a Lie point symmetry and a conserved vector invariant under the symmetry. The theory is applied to a third order nonlinear partial differential equation which describes the filtration of a visco-elastic liquid with relaxation through a porous medium. 相似文献
999.
Carlos A. D. Zarro 《General Relativity and Gravitation》2009,41(3):453-468
We investigate the conditions for which a d-dimensional perfect fluid solution is in hydrostatic equilibrium with a cosmological constant. We find a generalization of
Buchdahl inequality and obtain an upper bound for the degree of compactification. Using the Tolman–Oppenheimer–Volkoff equation
to get a lower bound for the degree of compactification we analyse the regions where the solution is in hydrostatic equilibrium.
We obtain the inner metric solution and the pressure for the constant fluid density model. 相似文献
1000.
In this work, we consider quasi-one-dimensional Bose-Einstein condensates (BECs), with spatially varying collisional interactions, trapped in double-well potentials. In particular, we study a setup in which such a “collisionally inhomogeneous” BEC has the same (attractive-attractive or repulsive-repulsive) or different (attractive-repulsive) types of interparticle interactions. Our analysis is based on the continuation of the symmetric ground state and anti-symmetric first excited state of the non-interacting (linear) limit into their nonlinear counterparts. The collisional inhomogeneity produces a saddle-node bifurcation scenario between two additional solution branches; as the inhomogeneity becomes stronger, the turning point of the saddle-node tends to infinity and eventually only the two original branches remain, which is completely different from the standard double-well phenomenology. Finally, one of these branches changes its monotonicity as a function of the chemical potential, a feature especially prominent, when the sign of the nonlinearity changes between the two wells. Our theoretical predictions, are in excellent agreement with the numerical results. 相似文献