Synthesis and Characterization of Biodegradable Alternating Polyesteramides from Mixed Diamidediols and Sebacic Acid

A series of polyesteramide prepolymers[PrePEA（0/4,8）s] having mixed alternating bisesterdiamide units was synthesized via melt polycondensation from N,N＇-bis（2-hydroxyethyl）oxamide（0） and N,N＇-bis（2-hydroxyethyl）-adipamide（4） with sebacic acid（8） at different molar ratios.Chain extension of them was conducted with 2,2＇-（1,4-phenylene）-bis（2-oxazoline） and adipoyl biscaprolactamate as combined chain extenders.The chain extended polyesteramides[ExtPEA（0/4,8）s] were characterized by proton nuclear magnetic resonance（1H NMR）,gel permeation chromatography（GPC）,differential scanning calorimetry（DSC）,thermogravimetry analysis（TGA）,wide angle X-ray scattering,tensile test and enzymatic degradation.The results show that ExtPEA（0/4,8）s were crystalline polyesteramides.They had Tm up to 136.5 ℃ and initial decomposition temperature above 297.5 ℃.They crystallized in similar crystallites into Nylon-66 and degraded under the catalysis of protease or lipase.They are thermoplastic materials with tensile strength up to 21.5 MPa and elongation at break above 64.0％.     

不同分子量软链段的聚己内酯型聚氨酯扩链反应动力学研究

合成了一系列不同分子量的聚己内酯,进而制备异氰酸根封端的聚己内酯预聚体,用傅里叶变换红外光谱研究了不同分子量的聚己内酯预聚体与二元醇的扩链反应.扩链反应动力学研究结果表明:聚己内酯预聚体与二元醇的扩链反应均为二级反应;随着软链段反应物料分子量的增加,反应速率常数显著降低,但当分子量超过某一范围后,其对反应速率的影响逐渐减小,趋于不变.对于不同硬链段反应物料含量的扩链反应体系,硬链段反应物料含量越高,软链段反应物料分子量对反应速率的影响越明显,而且,当软链段反应物料分子量超过某一范围后,不同体系的反应速率常数间的差值趋于不变.Arrhenius方程中的指前因子(B)随软链段反应物料分子量的变化关系与速率常数对分子量的依赖关系相同;从反应速率常数对温度的依赖关系可见:表观活化能的直线斜率基本相同,扩链反应的活化能主要与官能团的反应活性相关.     

固定接触界面法向静弹性刚度

基于Hertz接触理论推导了两个微凸体之间互相作用的法向接触静弹性刚度.根据修正后的一个微接触点的平截面积尺寸分布,给出了界面的总法向接触静弹性条件刚度、总条件载荷的解析解.将法向静弹性刚度的解析解嵌入到有限元软件中,获得整机的理论模态.通过实验对解析解进行了定量验证.以机床结合部为研究对象,在理论振型与实验振型一致的...     

Multipliers,covers, and stem extensions for Lie superalgebras

Suppose that the underlying field is of characteristic different from 2 and 3. We first prove that the so-called stem deformations of a free presentation of a finite-dimensional Lie superalgebra L exhaust all the maximal stem extensions of L; up to equivalence of extensions. Then we prove that multipliers and covers always exist for a Lie superalgebra and they are unique up to superalgebra isomorphisms. Finally, we describe the multipliers, covers, and maximal stem extensions of Heisenberg superalgebras and model filiform Lie superalgebras.     

半格分次弱Hopf代数的$G$-Cleft扩张

本文首先将Clifford幺半群代数分解为交叉积的半格直和,然后将这个结果通过$H$-$G$-cleft扩张推广到所谓的$G$-交叉积上.     

ALGEBRAIC EXTENSION OF ＊-A OPERATOR

In this paper, we study various properties of algebraic extension of *-A operator.Specifically, we show that every algebraic extension of *-A operator has SVEP and is isoloid.And if T is an algebraic extension of *-A operator, then Weyl's theorem holds for f(T), where f is an analytic functions on some neighborhood of σ(T) and not constant on each of the components of its domain.     

具有卷积的中心自反环

本文研究了具有卷积的中心自反环的性质,定义并引入了中心-自反环,显然,中心-自反环是自反环、中心自反环和-自反环的推广.给出了这类环的一些特征,研究了相关的环扩张,包括平凡扩张,Dorroh扩张和多项式扩张.     

Actions of Ore extensions and growth of polynomial H-identities

We show that if A is a finite-dimensional associative H-module algebra for an arbitrary Hopf algebra H, then the proof of the analog of Amitsur’s conjecture for H-codimensions of A can be reduced to the case when A is H-simple. (Here we do not require that the Jacobson radical of A is an H-submodule.) As an application, we prove that if A is a finite-dimensional associative H-module algebra where H is a Hopf algebra H over a field of characteristic 0 such that H is constructed by an iterated Ore extension of a finite-dimensional semisimple Hopf algebra by skew-primitive elements (e.g., H is a Taft algebra), then there exists integer PIexp^H(A). In order to prove this, we study the structure of algebras simple with respect to an action of an Ore extension.     

Chain Extension of Polyamide 6 Using Bisoxazoline Coupling Agents

The chain extension behaviors of 2,2′-(1,3-phenylene)bis(2-oxazoline) (MPBO) and 2,2′-bis(2-oxazoline) (BOZ) were studied to evaluate the coupling effect on polyamide 6 (PA6) in a Haake Rheocord mixer and an extruder. The coupling results showed that there existed an optimal dosage of chain extender, lack of which caused deficiency of chain extension and excess of which led to more blocking reaction. The effect of chain extension with MPBO was shown to be inferior to BOZ. When the optimum amount of chain extenders was added in PA6, the intrinsic viscosity of the polyamide 6 increased from 1.632dl/g to 1.787dl/g(MPBO) and 2.031dl/g(BOZ), respectively. The reaction time decreased very fast with an increase in the temperature. The chain-extended products dissociated at high temperature; the degradation is suggested to proceed from the onset of the chain extension reaction, as do the coupling and blocking reactions. Furthermore, the effects of MPBO and BOZ on the thermal and mechanical properties of chain-extended PA6 were also investigated.     

Extremal maximal sectorial extensions of sectorial relations

The extremal maximal sectorial extensions of a not necessarily densely defined sectorial relation (multivalued linear operator) in a Hilbert space are characterized in terms of a construction which goes back to Sebestyén and Stochel. In particular the two extreme maximal sectorial extensions, namely the Friedrichs extension and the Kreĭn extension, are characterized. For this purpose a survey is given of the connection between closed sectorial forms and maximal sectorial relations.