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51.
GMA熔融接枝EPDM的研究 总被引:10,自引:0,他引:10
以甲基丙烯酸缩水甘油酯(GMA)为接枝单体,过氧化二异丙苯(DCP)为引发剂,对三元乙丙胶(EPDM)进行了熔融接枝,在烃链上引入极性基团,以改善EPDM与极性聚合物的相容性。用差示扫描量热计(DSC)研究了GMA的聚合温度,用富里叶红外(FT-IR)、凝胶渗透色谱(GPC)对接枝产物进行了表征。实验结果表明,产物的接枝率和凝胶量可以通过反应条件(温度、时间、反应物组成及加料方式)来控制。 相似文献
52.
Tatjana Topalovic Vincent A. Nierstrasz Lorenzo Bautista Dragan Jocic Antonio Navarro Marijn M. C. G. Warmoeskerken 《Cellulose (London, England)》2007,14(4):385-400
Hydrogen peroxide can be catalyzed to bleach cotton fibers at temperatures as low as 30°C by incorporating dinuclear tri-μ-oxo
bridged manganese(IV) complex of the ligand 1,4,7-trimethyl-1,4,7-triazacyclononane (MnTACN) as the catalyst in the bleaching
solution. The catalytic system was found to be more selective under the conditions applied than the non-catalytic H2O2 system, showing better bleaching performance while causing slightly lower decrease in degree of polymerization (DP) of cellulose.
In order to gain fundamental knowledge of the bleach effect on cotton fibers and cellulose as its main component, especially
after catalytic bleaching, X-ray Photoelectron Spectroscopy (XPS) was used to study surface chemical effects. The Washburn
method was applied to investigate wetting properties, and liquid porosity was used to obtain pore volume distribution (PVD)
plots. Parallel analyzes performed on model cotton fabric, i.e. “clean” cotton fabric stained with morin - a pigment regularly
found in native cotton fiber, helped to differentiate between pigment oxidation and other bleaching effects produced on the
(regular) industrially scoured cotton fabric. Bleaching was not limited to the chemical action but also affected cotton fiber
capillary parameters most likely due to the removal of non-cellulosic materials as well as chain-shortened cellulose. 相似文献
53.
Eric S. Key 《Journal of Theoretical Probability》1992,5(2):375-389
Suppose thatX
1,X
2,... is a sequence of iid random variables taking values inZ
+. Consider the random sequenceA(X)(X
1,X
2,...). LetY
n
be the number of integers which appear exactly once in the firstn terms ofA(X). We investigate the limit behavior ofn
–(1–)
Y
n
for [0, 1]. 相似文献
54.
磺化丁基橡胶离聚体在混合溶剂中的聚集行为 总被引:1,自引:0,他引:1
用顺磁共振(ESR)谱和粘度法考察了磺化丁基橡胶离聚体在二甲苯/正己醇混合溶剂中的聚集行为.ESR谱表明离聚体的离子基团发生聚集,其聚集程度受极性共溶剂(正己醇)的影响.粘度考察表明,在不同的浓度时离子基团有不同的聚集形式,低浓度时以分子内聚集为主,高浓度时以分子间聚集为主.离聚体的聚集度(DA)与浓度(c)的关系可用经验式DA=Aexp(kc2)表示,其中A、k为常数.k值反映聚集度受浓度影响的程度,醇含量增大时k值减小,这是因为醇对离子的溶剂化作用导致离子聚集的倾向减小. 相似文献
55.
关于两两NQD列的若干极限性质 总被引:32,自引:0,他引:32
本文讨论了两两NQD列的Marcinkiewicz型弱大数律及Jamison型加权和的强稳定性,指出了两两NQD列与独立列的一个本质性区别,从而提出了解决两两NQD旬几乎处处收敛和完全收敛的一种方式。 相似文献
56.
Given a connected undirected graph G, the Degree Preserving Spanning Tree Problem (DPSTP) consists in finding a spanning tree T of G that maximizes the number of vertices that have the same degree in T and in G. In this paper, we introduce Integer Programming formulations, valid inequalities and a Branch-and-cut algorithm for the DPSTP. Reinforced with new valid inequalities, the upper bounds provided by the formulation behind our Branch-and-cut method dominate previous DPSTP bounds in the literature. 相似文献
57.
58.
The partial order on monomials that corresponds to domination when evaluated at positive Newton sequences is fully understood. Here we take up the corresponding partial order on linear combinations of monomials. In part using analysis based upon the cone structure of the exponents in p-Newton sequences, an array of conditions is given for this new partial order. It appears that a characterization in general will be difficult. Within the case in which all coefficients are 1, the situation in which, for general sequence length, there are two monomials, each of length two and nonnegative integer exponents, the partial order is fully characterized. The characterization is combinatorial, in terms of indices in the monomials, and, already here there is much more than term-wise domination. 相似文献
59.
We consider β-expansions of formal Laurent series over finite fields. If the base β is a Pisot or Salem series, we prove that the β-expansion of a Laurent series α is automatic if and only if α is algebraic. 相似文献
60.
K. H. Illers 《Journal of Macromolecular Science: Physics》2013,52(4):471-482
The physical properties of PVC depend on two fundamental parameters, which are influenced by thermal history: free volume and crystallinity. This is demonstrated by DSC, sorption, low strain and ultimate mechanical properties. 相似文献