The interplay between geometry,electronic structure,and reactivity of Cu-Ni bimetallic (111) surfaces

The mutual influence of surface geometry (e.g. lattice parameters, morphology) and electronic structure is discussed for Cu-Ni bimetallic (111) surfaces. It is found that on flat surfaces the electronic d-states of the adlayer experience very little influence from the substrate electronic structure which is due to their large separation in binding energies and the close match of Cu and Ni lattice constants. Using carbon monoxide and benzene as probe molecules, it is found that in most cases the reactivity of Cu or Ni adlayers is very similar to the corresponding (111) single crystal surfaces. Exceptions are the adsorption of CO on submonolayers of Cu on Ni(111) and the dissociation of benzene on Ni/Cu(111) which is very different from Ni(111). These differences are related to geometric factors influencing the adsorption on these surfaces. Received: 26 August 2002 / Accepted: 4 September 2002 / Published online: 5 February 2003 RID="*" ID="*"Corresponding author. Fax: +44-1223/76-2829, E-mail: gh10009@cam.ac.uk [+1pt] Present address: University of Cambridge, Lensfield Road, Department of Chemistry, Cambridge CB2 1EW, UK     

Electro-responsive asymmetric nanopores in polyimide with stable ion-current signal

For the preparation of a single asymmetrically shaped nanopore in a polyimide membrane, Kapton foils were irradiated with single heavy ions and subsequently etched from one side in sodium hypochlorite (NaOCl). The other side of the membrane was protected from etching by a stopping medium containing a reducing agent for hypochlorite ions (OCl^-). The resulting conical nanopore rectified ion current and exhibited a stable ion-current flow. Received: 23 May 2002 / Accepted: 2 September 2002 / Published online: 15 January 2003 RID="*" ID="*"Corresponding author. Fax: +49-6159/712-179, E-mail: Z.Siwy@gsi.de     

Multiple Coulomb excitation of a 70Ge beam and the interpretation of the 02 + state as a deformed intruder

Electromagnetic properties of the low-lying states in a ⁷⁰Ge nucleus were studied through the multiple Coulomb excitation of a ⁷⁰Ge beam with a ^natPb target. Relative γ-ray intensities were measured as a function of emission angle relative to the scattered projectile. Sixteen E2 matrix elements, including diagonal ones, for 6 low-lying states have been determined using the least-squares search code GOSIA. The expectation values 〈Q ²〉 of 0₁ ⁺ and 0₂ ⁺ states in ⁷⁰Ge are compared with those in ^{72, 74, 76}Ge. Simple mixing calculations indicate that the 0₂ ⁺ states in ⁷⁰Ge and ⁷²Se can be treated as deformed intruder states. It is shown that the deformed intruder becomes the ground state in ⁷⁴Kr. These interpretations of the 0₂ ⁺ states in this region are compared with the potential-energy surface calculations by the Nilsson-Strutinsky model, which allow to interpret the experimental results in a qualitative way from the theoretical point of view. Received: 2 September 2002 / Accepted: 5 November 2002 / Published online: 25 February 2003 RID="a" ID="a"e-mail: sugawara@pf.it-chiba.ac.jp Communicated by D. Schwalm     

Legendre Transformation for Regularizable Lagrangians in Field Theory

Hamilton equations based not only upon the Poincaré–Cartan equivalent of a first-order Lagrangian, but also upon its Lepagean equivalent are investigated. Lagrangians which are singular within the Hamilton–De Donder theory, but regularizable in this generalized sense are studied. Legendre transformation for regularizable Lagrangians is proposed and Hamilton equations, equivalent with the Euler–Lagrange equations, are found. It is shown that all Lagrangians affine or quadratic in the first derivatives of the field variables are regularizable. The Dirac field and the electromagnetic field are discussed in detail.     

Second-Order Subexponential Sequences and the Asymptotic Behavior of Their De Pril Transform

Suppose that { f(n), n N ₀ } is a sequence of positive real numbers and suppose that the sequence { a(n), n N ₀ } is given by a(0) = 0, and, for n 1, by the convolution equation nf(n) = a* f(n). The resulting sequence is denoted by a(n) = _f (n) and is called the De Pril transform of { f(n), n N ₀ } . In this paper, we consider first- and second-order asymptotic behavior of { _{f (n), n N 0} } for a large class of subexponential sequences { f(n), n N ₀ } . We also discuss some applications.     

Magnetohydrodynamic properties of incompressible Meissner fluids

We consider a superconducting material that exists in the liquid state, more precisely, in which the Meissner-Ochsenfeld effect persists in the liquid state. First, we investigate how the shape of such a hypothetical Meissner liquid will adapt to accomodate for an applied external field. In particular, we analyse the case of a droplet of Meissner fluid, and compute the elongation of the droplet and its quadrupole frequency as a function of the applied field. Next, the influence of an applied field on the flow of the liquid is studied for the case of a surface wave. We derive the dispersion relation for surface waves on an incompressible Meissner fluid. We discuss some candidate realizations of the Meissner fluids and for the case of a superconducting colloid discuss which regime of wave lengths would be most affected by the Meissner effect.     

Precision measurement of vector and tensor analyzing powers in elastic deuteron-proton scattering

High-precision vector and tensor analyzing powers of elastic deuteron-proton ( d + p) scattering have been measured at intermediate energies to investigate effects of three-nucleon forces. Angular distributions in the range of 70^°-120^° in the center-of mass frame for incident-deuteron energies E _d ^lab = 130 and 180 MeV were obtained using the RIKEN facility. The beam polarization was unambiguously determined by measuring the ^12C (d, α)^10B(2⁺) reaction at 0^°. Results of the measurements are compared with state-of-the-art three-nucleon calculations. The present modeling of nucleon-nucleon forces and its extension to the three-nucleon system is not sufficient to describe the high-precision data consistently and requires, therefore, further investigation.     

Electromagnetic cavity to explore disordered systems

In the course of characterizing an electromagnetic cavity we have come to understand details of transmission and reflection traces, some of which may be useful as tools to investigate local modes in random media. We have demonstrated quantitative agreement of frequency shift observations with theory, have demonstrated that the spatial distribution of electric and magnetic fields can be measured using insulating and conducting spheres, and have used perturbation due to wires and disks to demonstrate the local direction of electric and magnetic fields. We have observed that not only frequency shifts but also spatial shifts of modes can be used to observe the intensity of interaction of modes with extended objects in the cavity.     

Thickness determination of molecularly thin lubricant films by angle-dependent X-ray photoelectron spectroscopy

An angle-dependent X-ray photoelectron spectroscopy (XPS) method used to measure the thickness of molecularly thin lubricants was developed. The method was built based on an island model of patched overlayer on a flat substrate by using the photoemission signal solely from the lubricant film. Typical molecularly thin Zdol films on the CHx overcoat of unused commercial magnetic disks were measured to verify the metrology. The lubricant thickness determined by the metrology was equal to the recent result by thermostatic high vacuum atomic force microscopy. The measured deduction in the thickness of the molecularly thin lubricant films, successively irradiated by the monochromatic source operated at 14 kV/250 W, was as low as 1 ? during the first irradiation hour. XPS spectra showed that no hydrocarbons, water or oxygen were adsorbed over the Zdol outer surfaces in the tested XPS conditions. The inelastic mean free path (IMFP) of C 1s in Zdol or in CHx was found to be independent of take off angle (TOA) when TOA < 40°. The IMFP of C 1s in Zdol was ∼63.5 ? and the lubricant island thickness was ∼35 ?.     

Coherent Structures in Transition of a Flat-Plate Boundary Layer at Ma = 0.7

Direct numerical simulation （DNS） of a spatially evolving fiat-plate boundary layer transition process at free stream Mach number 0. 7 is performed. Tollmien-Schlichting （T-S） waves are added on the inlet boundary as the disturbances before transition. Typical coherent structures in the transition process are investigated based on the second invariant of velocity gradient tensor. The instantaneous shear stress and the mean velocity profile in the transition region are studied. In our view, the fact that the peak value of shear stress in the stress concentration area increases and exceeds a threshold value during the later stage of the trallsition process plays an important role in the laminar breakdown process.