Vertically aligned N-doped carbon nanotubes by spray pyrolysis of turpentine oil and pyridine derivative with dissolved ferrocene

Vertically aligned nitrogen-doped carbon nanotubes were synthesized from the pyrolysis of a mixture of turpentine oil, 4-tert-butylpyridine (C₉H₁₃N) and ferrocene on silicon and quartz substrate in nitrogen atmosphere at 700 °C by simple spray pyrolysis technique. SEM, TEM, TGA/DTA, Raman spectroscopy, XPS and electron probe micro analysis (EPMA) techniques were used to characterize the structural analysis and composition of the as-grown N-doped carbon nanotubes. Morphology of the films was greatly affected by the nature of the substrate. From the XPS and EPMA data, it was found that nitrogen content of the nanotubes were 1.6 at.% and 2 at.% on silicon and quartz substrate, respectively. Our studies show that two different types of N atoms can be present in these materials. These are ‘pyridinic’ and ‘graphitic’ nitrogen with binding energies of 398.2 eV and 400.4 eV, respectively. Raman spectroscopy reveals that graphitization of carbon nanotubes grown on silicon is better than nanotubes grown on quartz substrate. Thermogravimetric analysis showed that the thermal stability of as-prepared nanotubes grown on silicon substrate is higher than the nanotubes deposited on quartz substrate.     

The Independence Number for De Bruijn networks and Kautz networks

Let D be a directed graph; the (l,ω)-Independence Number of graph D, denoted by α_l,ω(D), is an important performance parameter for interconnection networks. De Bruijn networks and Kautz networks, denoted by B(d,n) and K(d,n) respectively, are versatile and efficient topological structures of interconnection networks. For l=1,2,…,n, this paper shows that α_l,d−1(B(d,n))=dⁿ,α_l,d−1(K(d,n))=α_l,d(K(d,n))=dⁿ+dⁿ⁻¹ if d≥3 and n≤d−2. In particular, the paper shows the exact value of the Independence Number for B(d,1) and B(d,2) for any d. For the generalized situation, the paper obtains a lower bound α_l,d−1(B(d,n))≥d² if n≥3 and d≥5.     

All-atom de novo protein folding with a scalable evolutionary algorithm

The search for efficient and predictive methods to describe the protein folding process at the all-atom level remains an important grand-computational challenge. The development of multi-teraflop architectures, such as the IBM BlueGene used in this study, has been motivated in part by the large computational requirements of such studies. Here we report the predictive all-atom folding of the forty-amino acid HIV accessory protein using an evolutionary stochastic optimization technique. We implemented the optimization method as a master-client model on an IBM BlueGene, where the algorithm scales near perfectly from 64 to 4096 processors in virtual processor mode. Starting from a completely extended conformation, we optimize a population of 64 conformations of the protein in our all-atom free-energy model PFF01. Using 2048 processors the algorithm predictively folds the protein to a near-native conformation with an RMS deviation of 3.43 A in < 24 h.     

Positron spectra from internal pair conversion observed in 238U + 181Ta collisions

We present new results from measurements and simulations of positron spectra, originating from ²³⁸U + ¹⁸¹Ta collisions at beam energies close to the Coulomb barrier. The measurements were performed using an improved experimental setup at the double-Orange spectrometer of GSI. Particular emphasis is put on the signature of positrons from Internal-Pair-Conversion (IPC) processes in the measured e⁺-energy spectra, following the de-excitation of electromagnetic transitions in the moving Ta-like nucleus. It is shown by Monte Carlo simulations that, for the chosen current sweeping procedure used in the present experiments, positron emission from discrete IPC transitions can lead to rather narrow line structures in the measured energy spectra. The measured positron spectra do not show evidence for line structures within the statistical accuracy achieved, although expected from the intensities of the observed γ-transitions ( E _γ∼ 1250-1600 keV) and theoretical conversion coefficients. This is due to the reduced detection efficiency for IPC positrons, caused by the limited spatial and momentum acceptance of the spectrometer. A comparison with previous results, in which lines have been observed, is presented and the implications are discussed. Received: 27 April 2000 / Accepted: 14 September 2000     

Coulomb excitation of 74Ge beam

⁷⁴Ge beam was Coulomb-excited on a ^natPb target. Ten E2 matrix elements including diagonal matrix elements for 5 low-lying states have been determined using the least-squares search code GOSIA. The expectation values of the rotational invariants 〈Q ²〉 and 〈cos3δ〉 show the small and triaxial deformation of the two lowest members of the ground-state band , while the 0₂ ⁺ and 2₂ ⁺ states are found to be almost spherical. Received: 31 August 2000 / Accepted: 4 December 2000     

Elastic scattering of intermediate-energy weakly bound particles on 12C nuclei

The differential cross-section for elastic scattering of deuterons at 700 MeV, ⁶Li and ⁶He at 2.07 GeV nuclei on ¹²C nucleus is calculated under the assumption of two-cluster (for deuterons and ⁶Li) and three-cluster (for ⁶He) structure of incident particle. For ⁶Li-¹²C and ⁶He-¹²C elastic scattering it is shown that there are quantitative distinctions in the behaviour of the observables calculated in the above approaches. Received: 13 October 1999 / Accepted: 3 January 2001     

Evanescent modes are not necessarily Einstein causal

Previously, experiments with microwave signals have shown that evanescent modes can travel faster than light. Several theoretical investigations have proven that in the case of signals with unlimitedly high frequency components, such superluminal velocities do not violate Einstein causality, thus group, signal, and energy velocities are c where c is the vacuum velocity of light. In this letter I shall show that frequency band limitation is a fundamental property of signals and that such signals containing only evanescent modes can violate Einstein causality. Received: 12 December 1998 / Accepted: 14 December 1998