异氰酸分子NH(a1Δ)+CO(X1Σ+)通道在193nm的离子成像光解动力学研究

The photodissociation dynamics of isocyanic acid (HNCO) has been studied by the timesliced velocity map ion imaging technique at 193 nm. The NH(a¹Δ) products were measured via (2+1) resonance enhanced multiphoton ionization. Images have been accumulated for the NH(a¹Δ) rotational states in the ground and vibrational excited state (v=0 and 1). The center-of-mass translational energy distribution derived from the NH(a¹Δ) images implies that the CO vibrational distributions are inverted for most of the measured ¹NH(v|j) internal states. The anisotropic product angular distribution observed indicates a rapid dissociation process for the N-C bond cleavage. A bimodal rotational state distribution of CO(v) has been observed, this result implies that isocyanic acid dissociates in the S₁ state in two different pathways.     

交叉分子束方法研究H+CH4和H+CD4反应:CH3/CD3的振动激发态产物通道

We study the H+CH₄/CD₄→H₂/HD+CH₃/CD₃ reactions using the time sliced velocity map ion imaging technique. Ion images of the CH₃/CD₃ products were measured by the (2+1) resonance enhanced multi-photon ionization (REMPI) detection method. Besides the CH₃/CD₃ products in the ground state, ion images of the vibrationally excited CH₃/CD₃ products were also observed at two collision energies of 0.72 and 1.06 eV. It is shown that the angular distribution of the products CH₃/CD₃ in vibrationally excited states gradually vary from backward scattering to sideways scattering as the collision energy increases. Compared to the CH₃/CD₃ products in the ground state, the CH₃/CD₃ products in vibrationally excited states tend to be more sideways scattered, indicating that larger impact parameters play a more important role in the vibrationally excited product channels.     

Random walks generated by affine mappings

This article is concerned with Markov chains on ^m constructed by randomly choosing an affine map at each stage, and then making the transition from the current point to its image under this map. The distribution of the random affine map can depend on the current point (i.e., state of the chain). Sufficient conditions are given under which this chain is ergodic.     

Convergence of the Klein-Gordon equation to the wave map equation with magnetic field

This paper is devoted to the proof of the convergence from the modulated cubic nonlinear defocusing Klein-Gordon equation with magnetic field to the wave map equation. More precisely, we discuss the nonrelativistic-semiclassical limit of the modulated cubic nonlinear Klein-Gordon equation with magnetic field where the Planck's constant ?=ε and the speed of light c are related by c=ε−α for some α?1. When α=1 the limit wave function satisfies the wave map with one extra term coming from the magnetic field. However, α>1, the effect of the magnetic filed disappears and the limit is the typical wave map equation only.     

Computation of symbolic dynamics for one-dimensional maps

In this paper we design and implement rigorous algorithms for computing symbolic dynamics for piecewise-monotone-continuous maps of the interval. The algorithms are based on computing forwards and backwards approximations of the boundary, discontinuity and critical points. We explain how to handle the discontinuities in the symbolic dynamics which occur when the computed partition element boundaries are not disjoint. The method is applied to compute the symbolic dynamics and entropy bounds for the return map of the singular limit of a switching system with hysteresis and the forced Van der Pol equation.     

H~2×R中给定平均曲率曲面的Weierstrass表示

定义了H~2×R中曲面的法高斯映照,给出了给定平均曲率曲面的Weierstrass表示,证明了法高斯映照满足一个二阶偏微分方程,并且该方程是所得到的Weierstrass表示的完全可积条件.     

The α-limit sets of a unimodal map without homtervals

Let f:I→I be a unimodal map on I without homtervals. We characterize the α-limit set of each point in I by considering the consecutive renormalization process of f.     

Logistic映射三周期轨道分支值确定

运用分支函数的方法研究了Logistic映射出现稳定三周期点的参数窗口,借助软件Singular 2.0.3运用多元多项式的Grobner基并结合严格局部分析的方法给出Logistic映射出现稳定三周期点时的参数值范围,最后数值模拟方法对所得的结果进行了验证,并指出伪轨现象.     

叶片扩压器进口安装角对离心压缩机性能影响的数值与实验研究

对不同扩压器进口安装角下离心压缩机的性能进行了实验研究,并详细计算分析了相应的流场分布。分析表明, 不同的进口安装角对压缩机的流动有较大的影响,压缩机的性能曲线也有不同程度的左右偏移;进口处较大的正冲角和负冲角均会在扩压器叶片表面出现大尺度的分离涡团;在给定的流量工况下,应存在一个最佳的进口安装角,使得扩压器效率最高;设计工况下,最高效率所对应的冲角并非为零。