全文获取类型
收费全文 | 13162篇 |
免费 | 2513篇 |
国内免费 | 2523篇 |
专业分类
化学 | 11318篇 |
晶体学 | 50篇 |
力学 | 205篇 |
综合类 | 82篇 |
数学 | 2967篇 |
物理学 | 3576篇 |
出版年
2024年 | 52篇 |
2023年 | 217篇 |
2022年 | 454篇 |
2021年 | 485篇 |
2020年 | 619篇 |
2019年 | 625篇 |
2018年 | 486篇 |
2017年 | 529篇 |
2016年 | 862篇 |
2015年 | 840篇 |
2014年 | 948篇 |
2013年 | 1352篇 |
2012年 | 1031篇 |
2011年 | 1088篇 |
2010年 | 905篇 |
2009年 | 1058篇 |
2008年 | 1025篇 |
2007年 | 1065篇 |
2006年 | 919篇 |
2005年 | 711篇 |
2004年 | 566篇 |
2003年 | 534篇 |
2002年 | 314篇 |
2001年 | 265篇 |
2000年 | 251篇 |
1999年 | 180篇 |
1998年 | 147篇 |
1997年 | 143篇 |
1996年 | 84篇 |
1995年 | 66篇 |
1994年 | 70篇 |
1993年 | 38篇 |
1992年 | 32篇 |
1991年 | 26篇 |
1990年 | 22篇 |
1989年 | 23篇 |
1988年 | 17篇 |
1987年 | 17篇 |
1986年 | 13篇 |
1985年 | 19篇 |
1984年 | 14篇 |
1983年 | 8篇 |
1982年 | 16篇 |
1981年 | 11篇 |
1980年 | 11篇 |
1979年 | 6篇 |
1978年 | 13篇 |
1977年 | 6篇 |
1976年 | 6篇 |
1973年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
42.
For approximate wave functions, we prove the theorem that there is a one‐to‐one correspondence between the constraints of normalization and of the Fermi–Coulomb and Coulomb hole charge sum rules at each electron position. This correspondence is surprising in light of the fact that normalization depends on the probability of finding an electron at some position. In contrast, the Fermi–Coulomb hole sum rule depends on the probability of two electrons staying apart because of correlations due to the Pauli exclusion principle and Coulomb repulsion, while the Coulomb hole sum rule depends on Coulomb repulsion. We demonstrate the theorem for the ground state of the He atom by the use of two different approximate wave functions that are functionals rather than functions. The first of these wave function functionals is constructed to satisfy the constraint of normalization, and the second that of the Coulomb hole sum rule for each electron position. Each is then shown to satisfy the other corresponding sum rule. The significance of the theorem for the construction of approximate “exchange‐correlation” and “correlation” energy functionals of density functional theory is also discussed. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
43.
《Journal of Chemical Sciences》2005,117(5):525-531
The silicon atom may increase its coordination number to values greater than four, to form pentacoordinated compounds. It
has been observed experimentally that, in general, pentacoordinated compounds show greater reactivity than tetracoordinated
compounds. In this work, density functional theory is used to calculate the global softness and the condensed softness of
the silicon atom for SiH
n
F4−n
and SiH
n
F
5−n
1−
. The values obtained show that the global and condensed softness are greater in the pentacoordinated compounds than in the
tetracoordinated compounds, a result that explains the enhanced reactivity. If the results are analysed through a local version
of the hard and soft acids and bases principle, it is possible to suggest that in nucleophilic substitution reactions, soft
nucleophiles preferably react with SiH
n
F
5−n
1−
, and hard nucleophiles with SiH
n
F4−n
. 相似文献
44.
Rodrigo París José Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3538-3549
Different diblock copolymers constituted by one segment of a monomer supporting a reactive functional group, like allyl methacrylate (AMA), were synthesized by atom transfer radical polymerization (ATRP). Bromo‐terminated polymers, like polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(butyl acrylate) (PBA) were employed as macroinitiators to form the other blocks. Copolymerizations were carried out using copper chloride with N,N,N′,N″,N″‐pentamethyldiethylenetriamine (PMDETA) as the catalyst system in benzonitrile solution at 70 °C. At the early stage, the ATRP copolymerizations yielded well‐defined linear block copolymers. However, with the polymerization progress a change in the macromolecular architecture takes place due to the secondary reactions caused by the allylic groups, passing to a branched and/or star‐shaped structure until finally yielding gel at monomer conversion around 40% or higher. The block copolymers were characterized by means of size exclusion chromatography (SEC), 1H NMR spectroscopy, and differential scanning calorimetry (DSC). In addition, one of these copolymers, specifically P(BA‐b‐AMA), was satisfactorily modified through osmylation reaction to obtain the subsequent amphiphilic diblock copolymer of P(BA‐b‐DHPMA), where DHPMA is 2,3‐dihydroxypropyl methacrylate; demonstrating the feasibility of side‐chain modification of the functional obtained copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3538–3549, 2007 相似文献
45.
Marco Lehmann-Waffenschmidt 《Central European Journal of Operations Research》2006,14(3):289-298
It is routine to demonstrate in the exchange economy framework that small changes of individual preferences and endowments always result in small changes of the derived excess demand functions as one should expect. Though being as desirable for reasons of the consistency of the whole approach, however, a precise proof of the converse direction so far is still open to question. The present paper shows that it is actually true. We use a decomposition method for aggregate excess demand functions developed by Mas-Colell which is derived from the well-known decomposition method developed by Sonnenschein and perfected by Debreu and Mantel. Our result fills in a notorious gap in the line of economic justification usually given for this decomposition, or disaggregation, method in that comparative static analysis would be restricted if the decomposition of excess demand functions would not be continuous. 相似文献
46.
Anatoliy Malyarenko 《Journal of Theoretical Probability》2006,19(2):263-288
We prove a general functional limit theorem for multiparameter fractional Brownian motion. The functional law of the iterated
logarithm, functional Lévy’s modulus of continuity and many other results are its particular cases. Applications to approximation
theory are discussed.
相似文献
47.
In this paper we prove existence results for semilinear neutral functional differential inclusions with finite or infinite
delay in Banach spaces. Our theory makes use of analytic semigroups and fractional powers of closed operators, integrated
semigroups and cosine families.
相似文献
48.
Magnetic properties of Co chain-coated carbon nanotube (CNT) were investigated using a first-principles calculation. Binding energy between Co chain and CNT increased with the coverage ratio, and the adsorption of Co chains on CNT enhanced the conductance channel. Total magnetic moment of Co chains coated on CNT increased with the coverage ratio, while the magnetic moment per Co atom decreased due to spin flip of majority spin states in Co atoms. Spin polarization at the Fermi level of the Co chains was calculated to converge to that of bulk fcc Co. 相似文献
49.
Covering numbers of precompact symmetric convex subsets of Hilbert spaces are investigated. Lower bounds are derived for sets containing orthogonal subsets with norms of their elements converging to zero sufficiently slowly. When these sets are convex hulls of sets with power-type covering numbers, the bounds are tight. The arguments exploit properties of generalized Hadamard matrices. The results are illustrated by examples from machine learning, neurocomputing, and nonlinear approximation. 相似文献
50.
We prove equivalence of the definitions by the author and by Korevaar and Schoen of the Sobolev classes of mappings of a domain of an arithmetic n-dimensional space to a metric space. 相似文献