Convenient,mild and rapid synthesis and characterization of some Schiff-base ligands and their complexes with uranyl(II) ion

Some Schiff-base complexes of UO₂(II) ion derived from 2-hydroxyacetophenone and aliphatic diamines under reflux conditions have been synthesized. The resulting ligands and their complexes have been characterized by elemental analyses (C, H, N), infrared, ¹H NMR, ¹³C NMR and mass spectra. In these efficient reactions, Schiff-base complexes with important applications in analytical and organic chemistry are prepared.     

On the usage of NURBS as interface representation in free‐surface flows

When simulating free‐surface flows using the finite element method, there are many cases where the governing equations require information which must be derived from the available discretized geometry. Examples are curvature or normal vectors. The accurate computation of this information directly from the finite element mesh often requires a high degree of refinement—which is not necessarily required to obtain an accurate flow solution. As a remedy and an option to be able to use coarser meshes, the representation of the free surface using non‐uniform rational B‐splines (NURBS) curves or surfaces is investigated in this work. The advantages of a NURBS parameterization in comparison with the standard approach are discussed. In addition, it is explored how the pressure jump resulting from surface tension effects can be handled using doubled interface nodes. Numerical examples include the computation of surface tension in a two‐phase flow as well as the computation of normal vectors as a basis for mesh deformation methods. For these examples, the improvement of the numerical solution compared with the standard approaches on identical meshes is shown. Copyright © 2011 John Wiley & Sons, Ltd.     

近自由面细长体的振荡问题

本文引进细长体的假定,把三维的流体运动问题化成了二维的非定常问题。前面剖面对后面剖面的干扰作用用积分表示,对物体作了适当近似以后,改善了切片理论。根据物面条件把整个问题的求解分解为兴波问题和振荡问题,而振荡问题可由兴波问题的适当组合表示出来。这样,大大简化了问题的求解。作为例子,本文数值计算了细长体的水动力导数,给出了结果。     

硅和锗纳米线的原子排布和电荷分布的密度泛函紧束缚方法研究

低维硅锗材料是制备纳米电子器件的重要候选材料,是研发高效率、低能耗和超高速新一代纳米电子器件的基础材料之一,有着潜在的应用价值。采用密度泛函紧束缚方法分别对厚度相同、宽度在0.272 nm~0.554 nm之间的硅纳米线和宽度在0.283 nm~0.567 nm之间的锗纳米线的原子排布和电荷分布进行了计算研究。硅、锗纳米线宽度的改变使原子排布,纳米线的原子间键长和键角发生明显改变。纳米线表层结构的改变对各层内的电荷分布产生重要影响。纳米线中各原子的电荷转移量与该原子在表层内的位置相关。纳米线的尺寸和表层内原子排列结构对体系的稳定性产生重要影响。     

Compact Kähler Surfaces with Trivial Canonical Bundle

The classical conjectures of Weil on K3 surfaces – that the set of suchsurfaces is connected; that a version of the Torelli theorem holds; thateach such surface is Kähler; and that the period map issurjective – are reconsidered in the light of a generalisation of theNakai–Moishezon criterion, and short proofs of all the conjectures aregiven. Most of the proofs apply equally or with minor variation tocomplex 2-tori, the only other compact Kähler surfaces with trivialcanonical bundle.     

Equisingular Deformations of Sandwiched Singularities

We relate the equisingular deformation theory of plane curve singularities and sandwiched surface singularities. We show the existence of a smooth map between the two corresponding deformation functors and study the kernel of this map. In particular we show that the map is an isomorphism when a certain invariant is large enough.     

New Examples of Willmore Surfaces in S n

A surface x: M S ⁿ is called a Willmore surface if it is a criticalsurface of the Willmore functional _M (S – 2H ²)dv, where H isthe mean curvature and S is the square of the length of the secondfundamental form. It is well known that any minimal surface is aWillmore surface. The first nonminimal example of a flat Willmoresurface in higher codimension was obtained by Ejiri. This example whichcan be viewed as a tensor product immersion of S ¹(1) and a particularsmall circle in S ²(1), and therefore is contained in S ⁵(1) gives anegative answer to a question by Weiner. In this paper we generalize theabove mentioned example by investigating Willmore surfaces in S ⁿ (1)which can be obtained as a tensor product immersion of two curves. We inparticular show that in this case too, one of the curves has to beS ¹(1), whereas the other one is contained either in S ²(1) or in S ³(1). In the first case, we explicitly determine the immersion interms of elliptic functions, thus constructing infinetely many newnonminimal flat Willmore surfaces in S ⁵. Also in the latter casewe explicitly include examples.     

Marked Schottky Groups and Representations of Surface Groups

We give a complete condition for any n elements of PSL(2, R)to generate a Fuchsian group which is a Schottky group on thatset of generators, and apply it to a question of Bowditch onrepresentations of surface groups into PSL(2, R). 2000 MathematicalSubject Classification: 20H10, 32G15.