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31.
近年来随着NdFeB永磁的应用发展,对金属Nd质量的要求越来越高,而电解过程碳颗粒运动及溶解对金属质量的影响至关重要。通过理论与数值模拟相结合的方式对流场中不溶于电解液的碳固体颗粒的主要受力类型进行梳理,对其运动轨迹进行数值模拟研究,针对稀土电解槽进行了颗粒-流场的计算及模拟,研究发现曳力及重力是颗粒在电解槽中起主要作用的力。曳力是改变颗粒运动轨迹的影响因素,且曳力随粒径的增大而增大。0.07 mm颗粒粒径是区分主要作用力是重力还是曳力的临界值,颗粒粒径越大,越不利于电解槽得到纯净的Nd单质。对进一步改进电解槽槽型,从而得到质量更好、杂质更少的稀土金属,并对后续各物理场对颗粒的影响提供参考意义。 相似文献
32.
Akihiro Kitashoji Kosei Kitagawa Dr. Akimasa Fujihara Prof. Dr. Tomoyuki Yatsuhashi 《Chemphyschem》2020,21(9):847-852
A multiply charged molecule expands the range of a mass window and is utilized as a precursor to provide rich sequence coverage; however, reflectron time-of-flight mass spectrometer has not been well applied to the product ion analysis of multiply charged precursor ions. Here, we demonstrate that the range of the mass-to-charge ratio of measurable product ions is limited in the cases of multiply charged precursor ions. We choose C6F6 as a model molecule to investigate the reactions of multiply charged molecular cations formed in intense femtosecond laser fields. Measurements of the time-of-flight spectrum of C6F6 by changing the potential applied to the reflectron, combined with simulation of the ion trajectory, can identify the species detected behind the reflectron as the neutral species and/or ions formed by the collisional charge transfer. Moreover, the metastable ion dissociations of doubly and triply charged C6F6 are identified. The detection of product ions in this manner can diminish interference by the precursor ion. Moreover, it does not need precursor ion separation before product ion analysis. These advantages would expand the capability of mass spectrometry to obtain information about metastable ion dissociation of multiply charged species. 相似文献
33.
Hydrodynamic pressure exerted on a plunge pool slab by jet impingement is of high interest in high dam projects. The present study experimentally investigated the characteristics of pressure induced by a jet through a constant width flip bucket (CFB) and a slit flip bucket (SFB). A pressurized plane pipe was employed in the flume experiments to control the inlet velocities in the flip buckets. A concise method is proposed to predict the mean dynamic pressure field. Its implementation is summarized as follows: First, the position of the pressure field is determined by the trajectories of free jets, and to calculate its trajectories, an equation based on parabolic trajectory theory is used; second, the maximum mean dynamic pressure is obtained through dimensional analysis, and then the pressure field is established by applying the law of Gaussian distribution. Those steps are integrated into a concise computing procedure by using some easy-to-obtain parameters. Some key parameters, such as takeoff velocity coefficient, takeoff angle coefficient, and the parameter , are also investigated in this paper. The formulas of these coefficients are obtained by fitting the experimental data. Using the proposed method, the easy-to-obtain geometric parameters and initial hydraulic conditions can be used to calculate the maximum mean dynamic pressure on the slab. A comparison between experimental data and calculated results confirmed the practicability of this model. These research results provide a reference for hydraulic applications. 相似文献
34.
《Wave Motion》2020
We consider a point-like observer that moves in a medium illuminated by noise sources with Lorentz-invariant spectrum. We show that the autocorrelation function of the signal recorded by the observer allows it to perceive its environment. More precisely, we consider an observer with constant acceleration (along a Rindler trajectory) and we exploit the recent work on the emergence of the Green’s function from the cross correlation of signals transmitted by noise sources. First we recover the result that the signal recorded by the observer has a constant Wigner transform, i.e. a constant local spectrum, when the medium is homogeneous (this is the classical analogue of the Unruh effect). We complete that result by showing that the Rindler trajectory is the only straight-line trajectory that satisfies this property. We also show that, in the presence of an obstacle in the form of an infinite perfect mirror, the Wigner transform is perturbed when the observer comes into the neighborhood of the obstacle. The perturbation makes it possible for the observer to determine its position relative to the obstacle once the entire trajectory has been traversed. 相似文献
35.
颗粒流体两相流模型研究进展 总被引:28,自引:0,他引:28
本文介绍了颗粒流体两相流动的特征及其模拟方法, 重点论述了拟流体模型的研究现状及发展, 并对两相流动模拟中的各种方法进行了展望。 相似文献
36.
密闭系统中微波辅助萃取机制探讨 总被引:9,自引:2,他引:9
通过与普通加热萃取虎杖中白藜芦醇的产率进行对比 ,对密闭系统中微波辅助萃取的机理进行了探讨。结果表明 ,微波辅助萃取与普通加热萃取二者的活化能相差不大 ,分别为30.06和30.32kJ·mol-1。但微波辅助萃取的表观速率常数约是普通加热萃取的20倍。并且还利用电子扫描显微镜对样品微结构进行了观察 ,研究表明 ,细胞内极性成分如水吸收了微波能后压力迅速增加导致细胞结构的破坏是MAE快速高效的关键 ,由于细胞的破坏 ,萃取剂和萃取目标化合物更容易通过细胞壁 ,加速了扩散速度 ,进而加速了萃取速度。 相似文献
37.
王柏懿 《应用数学和力学(英文版)》2003,24(8):928-935
By using Lagrangian method, the flow properties of a dusty-gas point source in a supersonic free stream were studied and the particle parameters in the near-symmetry-axis region were obtained . It is demonstrated that fairly inertial particles travel along oscillating and intersecting trajectories between the bow and termination shock waves . In this region, formation of " mufti- layer structure" in panicle distribution with alternating low- and high density layers is revealed. Moreover, sharp accumulation of particles occurs near the envelopes of particle trajectories . 相似文献
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本文应用准三体模型及扩展的LEPS势能面 (PES)、准经典轨线和CPOAM模型计算了Ba+RBr(R=CH3,C2H5,C3J7,C4H9,n-C5H11)→BaBr+R反应体系产物 BaBr的转动取向,结果表明产物BaBr的转动取向随碰撞能的增加越趋强烈,随烷基的增大而减弱. 相似文献