一个新颖的二茂铁羧酸混配合物的制备、晶体结构及电化学性质研究

本文以3-二茂铁羰基丙酸(L1)、1，1′-二茂铁二羰基-3，3′-双丙酸(L2)、2，2′-联吡啶胺(dpa)以及Zn(Ac)₂·2H₂O为原料合成了一个结构新颖的混配合物[Zn₂(L1)₂(L2)(dpa)]。X-射线单晶衍射分析表明，该配合物是一个中心对称的双核配合物，并在N-H…O氢键和C-H…O氢键的作用下形成了二维的超分子化合物。采用差示脉冲对该配合物的电化学性质进行了初步的研究。     

铜-康铜热电偶的低温不均匀性实验研究

从冰点到液氮温度的宽低温区内,对随机选取的铜-康铜热电偶进行了重复性精度标定.测试结果表明,多次断偶重复焊接行为将产生约0.272 mV的标准差.这意味着在液氮条件下,温度测量过程的最大误差将达8.98 ℃.所以,对现场、尤其对深冷区的现场进行精确测温实验中出现的断偶故障,重新焊接后必须重新标定才能继续使用.     

掺杂铕和铽的卤硼酸盐荧光体的制备及光谱特征

采用高温固相法在空气中合成了一系列掺杂稀土离子的卤硼酸盐荧光体, 研究了其发光性质和基质组成对稀土离子共掺杂的荧光体发光性质的影响. 研究结果表明, 在Eu3+和Tb3+共掺杂的体系中存在电子转移, 因此出现了Eu3+, Eu2+和 Tb3+共存于同一基质共同发射的现象. Ce3+对Eu2+和Tb3+具有敏化作用, 可增强其发射强度. 基质的组成对稀土离子的发射峰位和发射强度有明显影响.     

叠加激发双模压缩真空态的量子统计特性(英文)

从激发双模压缩真空态a^+mb^+m|ξ>出发构造了叠加态|Ψ>,研究了|Ψ>的量子统计特性.结果表明:在一定的条件下,随着相位差的变化,叠加态|Ψ>的平均光子数出现类似于Rabi振荡的崩塌与复原现象,而且与单个激发双模压缩真空态a^+mb^+m|ξ>相比,在叠加态|Ψ>中光场的相位压缩和亚泊松光子统计特性都得到了加强.     

En">Characters and Composition Factor Multiplicities for the Lie Superalgebra $${\mathfrak{g}}{\mathfrak{l}}$$ ( m / n )

The multiplicities a of simple modules L in the composition series of Kac modules V lambda for the Lie superalgebra (m/n ) were described by Serganova, leading to her solution of the character problem for (m/n ). In Serganova's algorithm all with nonzero a are determined for a given this algorithm, turns out to be rather complicated. In this Letter, a simple rule is conjectured to find all nonzero a for any given weight . In particular, we claim that for an r-fold atypical weight there are 2r distinct weights such that a = 1, and a = 0 for all other weights . Some related properties on the multiplicities a are proved, and arguments in favour of our main conjecture are given. Finally, an extension of the conjecture describing the inverse of the matrix of Kazhdan–Lusztig polynomials is discussed.     

根据表面反射特性进行目标探测的波段选择

计算和分析了表面反射特性对选择波段进行目标探测的影响.通过引入正交子空间投影方法,将背景信号从接收到的混合光谱中消除,从而达到压缩背景信号的目的.并在此基础上运用匹配跟踪算法自动地进行优化波段的选择,达到选择最佳波段的目的,从而进行目标探测.在大气外实际目标的探测中,得到了进行大气外目标探测的波段选择与目标表面反射特性的关系.     

半导体量子点及其应用(Ⅰ)

量子点，又称“人造原子”，它是纳米科学与技术研究的重要组成部分，由于载流子在半导体量子点中受到三维限制而具有的优异性能，构成了量子器件和电路的基础，在未来的纳米电子学、光电子学，光子、量子计算和生命科学等方面有着重要的应用前景，受到人们广泛重视，文章分为Ⅰ、Ⅱ两个部分：第Ⅰ部分介绍了半导体量子点结构的制备和性质；第Ⅱ部分介绍了量子点器件的可能应用。     

近红外光谱技术测定紫花苜蓿青贮鲜样的发酵品质

及时了解青贮饲草的发酵品质,如青贮饲草中氨态氮(NH₃-N),乳酸(LA), 乙酸(AA),丁酸(BA)含量,对畜牧业生产具有重要意义。应用偏最小二乘回归法(PLS)、傅里叶变换近红外光谱技术和液氮冷冻制样技术,建立了适合不同品种,不同生育期,不同茬次和不同青贮方法即时测定青贮苜蓿鲜样中氨态氮,乳酸,乙酸,丁酸的近红外校正模型,以期对NIRS在测定紫花苜蓿青贮样品中这些物质的可行性进行分析。所建模型的交叉检验决定系数(R2_CV)为0.602 4～0.949 7,交叉检验标准误(RMSECV)为0.559～3.78 g·kg-1鲜重。用检验集样品对模型进行外部检验,预测相关系数(r)为0.882 6～0.985 3,预测标准误为0.571～3.15 g·kg-1鲜重。结果表明,采用适当的样品处理方法和光谱分析技术可以实现近红外光谱技术对苜蓿青贮样品发酵品质的评定。     

Optical reflection properties for the interface associated with Chern insulator and chiral metamaterial

Based on the topological nature of Chern insulator and magnetoelectric coupling of chiral metamaterial, we investigate the electrodynamics for the interface associated with the two media. The Fresnel coefficients of the interface between Chern insulator and chiral metamaterial, as well as the corresponding polarization rotation angles, are derived. The reflection characteristics of the linearly polarized incident wave at the interface, such as complete polarization conversion and change of polarization state, are discussed. Under the combined influence of Chern insulator and chiral metamaterial, the partial polarization conversion may be enhanced to the complete polarization conversion, and the chiral metamaterial may compensate for the suppression effect of longitudinal conductivity of Chern insulator on the polarization conversion.     

Assessing the nucleophilic character of 2-amino-4-arylthiazoles through coupling with 4,6-dinitrobenzofuroxan: Experimental and theoretical approaches based on structure-reactivity relationships

A kinetic study of the reactions of potentially bioactive 2-amino-4-arylthiazoles with highly reactive 4,6-dinitrobenzofuroxan (DNBF) is reported herein in acetonitrile solution. The complexation reaction was followed by recording the UV–vis spectra with time at λ_max = 482 nm. Electronic effects of substituents influencing the rate of reaction have been studied using structure-reactivity relationships. It is shown that the Hammett plot relative to the reaction of DNBF with 2-amino-4-(4-chlorophenyl)thiazole exhibit positive deviation from the log k₁ versus σ correlation, while it showed excellent linear correlation in terms of Yukawa–Tsuno equation. It has be noticed that the nonlinear Hammett plot observed for 2-amino-4-(4-chlorophenyl) thiazole is not attributed to a change in rate-determining step but is due to nature of electronic effect of substituent caused by the resonance of stabilization of substrates. The second-order rate constant (k₁) relating to the bond C–C and C-N forming step of the complexation processes of DNBF with 4-substituted-aminothiazoles and 2-amino-5-methyl-4-phenylthiazole, respectively, is fit into the linear relationship log k = s_N (N + E), thereby permitting the assessment of the nucleophilicity parameter (N) of the 2-amino-4-arylthiazoles of the range (4.90 < N < 6.85). 2-amino-4-arylthiazoles is subsequently ranked by positioning its reactivity on the general nucleophilicity scale developed recently by Mayr and coworkers (2003) leading an interesting and a direct comparison over a large domain of π-, σ -, and n-nucleophiles. The global electrophilicity/nucleophilicity reactivity indexes of the 2-amino-4-arylthiazoles have been investigated by means of a density functional theory (DFT) method. .