全文获取类型
收费全文 | 1088篇 |
免费 | 110篇 |
国内免费 | 130篇 |
专业分类
化学 | 206篇 |
晶体学 | 6篇 |
力学 | 73篇 |
综合类 | 32篇 |
数学 | 656篇 |
物理学 | 355篇 |
出版年
2024年 | 3篇 |
2023年 | 15篇 |
2022年 | 36篇 |
2021年 | 16篇 |
2020年 | 26篇 |
2019年 | 40篇 |
2018年 | 29篇 |
2017年 | 40篇 |
2016年 | 33篇 |
2015年 | 16篇 |
2014年 | 61篇 |
2013年 | 106篇 |
2012年 | 59篇 |
2011年 | 62篇 |
2010年 | 69篇 |
2009年 | 76篇 |
2008年 | 78篇 |
2007年 | 78篇 |
2006年 | 64篇 |
2005年 | 55篇 |
2004年 | 54篇 |
2003年 | 42篇 |
2002年 | 46篇 |
2001年 | 34篇 |
2000年 | 24篇 |
1999年 | 25篇 |
1998年 | 24篇 |
1997年 | 18篇 |
1996年 | 19篇 |
1995年 | 12篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1973年 | 2篇 |
1957年 | 1篇 |
排序方式: 共有1328条查询结果,搜索用时 46 毫秒
21.
22.
J. P. Wesley 《Foundations of Physics Letters》1990,3(6):581-605
Weber electrodynamics predicts the Kaufmann-Bucherer experiments and the fine structure energy level splitting of the H-atom (neglecting spin) without mass change with velocity (i.e., mass
). The Weber potential for the gravitational case yields Newtonian mechanics, confirming Mach's principle. It provides a cosmological condition yielding an estimated radius of the universe of 8 × 109 light years. Despite these successes, the independent evidence for Kaufmann mechanics, where mass changes with velocity (i.e., mass
) is convincing. Perhaps a slight alteration may make the Weber theory compatible with Kaufmann mechanics. 相似文献
23.
Silver halide (AgX) microcrystal was used as template to synthesize hollow polyelectrolyte capsules. These hollow capsules were characterized by laser light scattering (LLS) used to measure the size of the capsules in solution. The ratio of hydrodynamic radius (Rh) from dynamic LLS to the radius of gyration (Rg) from static LLS is almost unity, revealing that the entities are hollow in solution. The results suggest that the LLS method can be regarded as a good complement to the confocal laser scanning microscopy (CLSM) method for the characterization of small hollow capsules, and it possesses the advantage of not needing fluorescence labeling. 相似文献
24.
用V/r~3-F表确定滴体积测定管的末端半径方奕文,王镜和(汕头大学化学系,汕头,515063)关键词滴体积法,表面张力,滴体积测定管,末端半径表面张力是液体或溶液所具有的非常重要的性质。借测定表面活性剂溶液的表面张力可确定表面活性剂的表面活性,计算?.. 相似文献
25.
令X=(n1,n2,…,nt),Y=(m1,m2,…,mt)是两个t维递减序列.如果对所有的j,1≤j≤t,都有∑i=1~j、ni≥∑i=1~j mi以及∑i=1~t ni=∑i=1~t mi,则称X可盖Y,记作X■Y.如果X≠Y,则记作X■Y.本文考虑联图G(n1,n2,…,nt;a)=(Kn1∪n2∪…∪Knt)∨Ka的谱半径,这里n1+n2+…+nt+a=n,(n1,n 相似文献
26.
27.
高效毛细管电泳是近年来分离科学中发展最为迅速的方法之一.它具有分离效率高、所需样品量极少、适合于生物大分子的分离测定和自动化程度高等特点.在毛细管电泳中,区带电泳作为主要的分离模式发挥了重要的作用[1].本文中以麦芽寡糖类物质为对象,研究了离子流体动力学半径在分离中的作用和规律,提出了麦芽寡糖的迁移时间、淌度与其所含糖基数目的线性关系,并在不同的体系与操作电压下得到了验证.同时,也为利用毛细管电泳技术估算麦芽寡糖所含糖基数提供了简易的途径.1实验部分自行组装毛细管电泳电化学检测系统,高压电源0~30k… 相似文献
28.
Anjali Acharya A. Goswami P. K. Pujari S. Sabharwal S. B. Manohar 《Journal of polymer science. Part A, Polymer chemistry》2002,40(8):1028-1036
Positron annihilation lifetime spectroscopy was used to characterize the reentrant volume‐phase‐transition behavior of poly(N‐isopropyl acrylamide) hydrogel in an ethanol/water mixed solvent. The polymer gel was synthesized with γ irradiation. The ortho‐positronium lifetime (τ3) in the gel slowly increased with an increase in the ethanol content in the mixed solvent. τ3 was not influenced by the volume phase transition. The ortho‐positronium intensity decreased with the collapse of the gel in an approximately 10% ethanol/water mixture. When swelled in pure ethanol, τ3 initially increased with the solvent amount in the gel, showing the destruction of intramolecular hydrogen bonding and the relaxation of polymer chains. The lower critical solution temperature of the gel in the 10% ethanol/water mixture was lower than that in pure water, and τ3 for various solvent contents showed behavior similar to that seen in pure solvent. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 1028–1036, 2002 相似文献
29.
30.
Light-stable micelles with azo dyes were prepared by micelle formation of a nonamphiphilic diblock copolymer containing azobenzene and UV absorbent at ca. 1 mol% as the unit ratios. The nonamphiphilic block copolymer consists of two different kinds of random copolymer blocks: poly[4-(phenylazophenoxymethyl)styrene-co-vinylphenol] (P(AS-co-VPh)) and poly[4-(2-hydroxybenzophenoxymethyl)styrene-co-styrene] (P(HBS-co-St)). This random block copolymer, P(AS-co-VPh)-b-P(HBS-co-St) formed the micelles in the presence of 1,4-butanediamine (BDA) through hydrogen bond cross-linking between the VPh units via BDA. The micelles had the azobenzene moieties at the cores and the UV absorbents at the coronas. The micelles showed a small color difference in color fading experiments, in comparison with the unimers and with micelles having no UV absorbent at the coronas. It is significant that the diblock copolymer forms the micelles and has the UV absorbents at the coronas to suppress the color fading. Furthermore, the chain length of ,-diamines had no effect on the hydrodynamic radius of the micelles, but affected the aggregation number and the cmc. 相似文献