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141.
Peculiarities of quadrupolar relaxation in electrolyte solutions were established via comparison of the data obtained from
proton and deuteron resonances. It has been shown that quadrupole coupling constants (QCC) of deuterons depend not only on
internal electron structure of molecule or ion, but on solution structure as well. To interpret the experimental results quantum-chemical
calculations of QCC of deuterons in different molecular complexes simulating different solution substructures were carried
out. Density functional theory (DFT) method with hybrid B3LYP functional was used for all calculations. 相似文献
142.
V. K. Aswal J. V. Joshi P. S. Goyal Rajesh Patel R. V. Upadhyay R. V. Mehta 《Pramana》2004,63(2):285-290
Small-angle neutron scattering studies have been carried out to check the structural integrity of citryltrimethylammonium
bromide (CTABr) micelles in a magnetic fluid for different magnetic fluid concentrations at two different temperatures 303
and 333 K. It is found that the CTABr micelles grow with increasing magnetic fluid concentration and there is a decrease in
the micellar size with increase in temperature. 相似文献
143.
Sergey Chervon 《General Relativity and Gravitation》2004,36(7):1547-1553
A new strategy of exact solutions construction in inflationary cosmology within the self-interacting scalar field theory is proposed. It is shown that inflationary models have no restrictions dictated by the slow-roll approximation on the self-interacting potential. The suggested approach makes it possible to compute precisely the e-folds numbers in inflationary scenarios. The scalar field with a logarithmic evolution in time is analyzed in details. Other possible types of scalar field evolution are discussed. 相似文献
144.
In this article, a special type of fractional differential equations(FDEs) named the density-dependent conformable fractional diffusion-reaction(DDCFDR) equation is studied. Aforementioned equation has a significant role in the modelling of some phenomena arising in the applied science. The well-organized methods, including the exp(-φ(ε))-expansion and modified Kudryashov methods are exerted to generate the exact solutions of this equation such that some of the solutions are new and have been reported for the first time. Results illustrate that both methods have a great performance in handling the DDCFDR equation. 相似文献
145.
Koga T 《The European physical journal. E, Soft matter》2005,17(3):381-388
The formation of intramolecular micelles in copolymers with periodic sequence, where hydrophobic units (stickers) are periodically placed along the chain, is studied by using multicanonical Monte Carlo computer simulations for an off-lattice bead-rod model in three dimensions. With decreasing the temperature, a transition from random-coil conformations to micelles occurs and flower-type micelles are formed via the transition. The number of stickers forming a micelle core is limited by the excluded-volume effect of loop chains around micelle cores. By this effect, two intramolecular micelles are formed for long polymer chains with 60 bonds via the coil-to-micelle transition. By further decreasing the temperature, we find that another transition, i.e., a micelle-to-micelle transition, takes place. At this transition point, the two intramolecular micelles merge into one micelle. Furthermore, we extend the multicanonical MC method to study elastic properties of single polymer chains with strong attractive interactions under external force fields, and study how the intramolecular micellization affects the elastic property of single polymer chains. 相似文献
146.
A. A. Kamnev L. A. Kulikov Yu. D. Perfiliev L. P. Antonyuk E. Kuzmann A. Vértes 《Hyperfine Interactions》2005,165(1-4):303-308
Emission Mössbauer spectroscopy with the 57Co isotope was used to study very dilute rapidly frozen aqueous solutions of cobalt(II) complexes with low-molecular-weight biomolecules (aromatic amino acids – anthranilic acid and L-tryptophan) and within a sophisticated biopolymer, bacterial glutamine synthetase, a key enzyme of nitrogen metabolism. The appearance of after-effects of the 57Co→57Fe nuclear transformation as well as the coordination properties of the cation and the ligands in the complexes are discussed on the basis of their Mössbauer parameters. 相似文献
147.
B. M. Azizur Rahman A. K. M. Saiful Kabir Muttukrishnan Rajarajan Kenneth T. V. Grattan 《Optical and Quantum Electronics》2005,37(1-3):171-183
Modal solutions of planar photonic crystal waveguides with rectangular air-holes are presented by using a rigorous full-vectorial finite element-based approach. The effective indices, mode field profiles, spot-sizes, power confinements, modal hybridness, beat lengths and group velocity dispersions are shown for the fundamental and higher order modes of the quasi-TE and TM polarizations. 相似文献
148.
In this study, in order to explain solvent proton relaxation mechanism, the spin-lattice relaxation time (T1) of agar solutions was measured as a function of agar concentration. Relaxation measurements were carried out by a FT-NMR spectrometer operating at 60 MHz and inversion recovery pulse squence was used. Relaxation rate(1/T1a) was linearly proportional to concentration of agar solution (C), and the T1 mechanism of solvent water protons in agar solutions should be caused by the chemical exchange of water protons between free and bound water. 相似文献
149.
闻小永 《原子与分子物理学报》2007,24(6):1171-1175
通过函数变换和扩展Jacobi椭圆函数展开法,利用吴消元法,借助符号运算软件Maple,得到非线性Schringer方程丰富的包络形式精确解,特别是由两个Jacobi椭圆函数表示的精确解.当模数m→1或m→0时,一部分解退化为双曲函数或三角函数表示的解,F-展开法和扩展的F-展开法得到的精确解是本文结果的特例. 相似文献
150.
YANG Jian-Song 《理论物理通讯》2007,48(2):295-298
In this letter, the φ^6 + φ^5 model in (D + 1) dimensions can be solved by a truncated series method. A series of solitary solutions of the φ^6 + φ^5 model in (D + 1) dimensions have be obtained. 相似文献