黑碳颗粒物表面SO2的非均相臭氧氧化

采用漫反射红外傅里叶变换光谱(DRIFTS)结合离子色谱(IC)、 X射线光电子能谱(XPS)研究了常温常压下SO2与O3在黑碳颗粒物(以Printex U为代表, 简称UBC)表面的非均相反应. 研究发现, 在O3和水气存在的情况下, 体系的反应产物主要是SO42-, 反应在一定时间内持续进行. UBC可提供反应活性位点, 促进SO2在其表面的臭氧氧化. O3是关键的氧化剂, 能显著提高SO2非均相氧化生成SO42-的速率. 水气的存在有利于表面活性位点再生, 使反应持续发生. 当SO2和O3的浓度为1014~1015 molecule/cm3、 相对湿度为40%时, SO2在UBC(1: 400, 以NaCl为稀释剂稀释400倍)表面非均相反应生成SO42-的稳态摄取系数(γBET)为1~6×10-6, SO42-的生成速率为1014~1015 ion·s-1·g-1.     

Optical and electrical properties of black gold layers in the far infrared

Black gold layers, prepared by an evaporation process in an inert atmosphere, are an efficient absorber in the far infrared spectral region. Experimental results are presented for their reflectance in the wavelength range between λ=15 μm and 1000 μm, corresponding to a wave number k=1/λ between 10 cm⁻¹ and 650 cm⁻¹. The black gold layers may electrically be either metallic or semiconducting, the metallic ones exhibiting higher absorbance. The layers have a percolated structure whose dielectric properties are described by the Bergman formalism for an effective medium. On the basis of this model, the deviation of the optical properties of the layers from bulk gold are accounted for solely by the topology of the percolated structure. The values derived for the electron collision time in the gold particles and for the percolation factor agree with those derived from the electrical conductivity of the layers and its temperature dependence.     

中山市1387名青年学生头发微量元素检测与分析

为了探讨中山市青年学生头发中的微量元素含量,测定了该市来自三个学校的1387名青年学生头发中的锌、铁、铜、钙、阵、锰、铅含量。结果表明,女生与男生的头发锌含量有显著差异（P＜0．05）,女生与男生的头发中钙含量有高度显著差异（P＜0．001）;城区与乡镇的青年学生头发中钙、铜含量有高度显著性差异（P＜001）;父母文化程度高与父母文化低的青年学生头发中钙含量有高度显著性差异（P＜0．01）;在青年学生的年龄、性别、家庭、居住地区等不同的比较中,以发钙值含量差异显著性最高。提示青年学生应注意饮食营养均衡,补充必需的微量元素,加强体育锻炼,对提高体系有一定的意义。     

Separation ofCimicifuga racemosa triterpene glycosides by reversed phase high performance liquid chromatography and evaporative light scattering detection

Summary The main triterpene glycosides ofCimicifuga racemosa were separated by reversed phase HPLC, using a C-18 column, Evaporative Light Scattering (ELS) detection and a grient system consisting of water, acetonitrile and reagent alcohol. Within 35 min three main glycosides could be separated and quantified in the methanolic root extract with detection limits of 10.5, 15.6 and 31.6 μg·mL⁻¹ respectively. The method was successfully used, to analyzed differentCimicifuga racemosa market products, as well as to distinguish between otherCimicifuga samples from China.     

乌骨鸡活性肽对体外非酶糖基化的抑制作用

采用正交实验优化了体外非酶糖基化反应体系,体系中加入不同浓度的乌骨鸡活性肽I、Ⅱ37 ℃孵育,同时以肌肽为阳性对照,观察乌骨鸡活性肽对非酶糖基化反应的影响.通过测定预定时间体外非酶糖基化体系的吸光度和荧光值计算乌骨鸡活性肽对非酶糖基化反应的抑制率和对非酶糖基化终产物生成的抑制率.结果表明乌骨鸡活性肽Ⅱ对体外非酶糖基化反应和非酶糖基化终产物的生成均具有较强的抑制作用.     

甘肃省会宁县高一学生碘营养状况调查与分析

为调查并分析会宁县高一学生碘营养状况及其对生长发育的影响,采取随机整群抽样法选取研究对象,采集清晨空腹静脉血测量血生化（包括TSH（促甲状腺激素）、FT4（游离甲状腺素）、总蛋白、白蛋白、胆固醇、甘油三酯和磷）、血常规,及取指端末梢血测钙（Ca）含量,同步测昔体格发育状况（包括身高、体质量、上臂围、右臂肱三头肌皮褶厚度）和智力相关指标（联合瑞文IQ值、注意力、学习力、光反射和声反射能力）。结果表明,调查对象TSH平均含鼍为（1．91±1．84）mu／L,低于参考值下限的占61．40％,FT4平均含量为（8．36±7．27）pmol／L,低于参考值下限的占66．49％,TSH和FT4都低于参考值下限的占48．42％,所有渊杏对象TSH和FT4均在参考值上限之内;男女生间比较发现女生碘缺乏程度高于男生（P〈0．001）;从对象膳食碘的摄入量发现,98％以上未达到推荐摄入量,并在生源、性别、年龄间存在差异性;血清碘含量分层分析发现随着碘营养状况的改善,各项智力测试值依次增加,全血Ca和血清P含量存在差别（P〈0．05）;三类指标相关分析显示FT4值与白蛋白、胆固醇、血小板及白细胞数目（P〈0．05）呈止相关关系,TSH与胆固醇、白细胞数目以及甘油三脂（P〈0．05）呈正相关关系;身高和体质量随TSH和FT4含量升高而递增。提示会宁高一学生血清碘亚临床缺乏状态者较多,尤其是女乍,血清TSH和FT4低下检出率比例较大,碘缺乏已经对调查对象的生长发育造成一定的影响。建议采取相应措施,如强化碘盐的供应和管理,普及碘营养知识,提倡摄入含碘丰富的食物,在集中供餐的学校食堂中增加含碘丰富食物的供给,促使该地区学生碘营养状况的改善及人口素质提高。     

高中生原电池模型认知能力测评工具开发及其应用研究*

基于模型认知能力的内涵、原电池核心知识内容、布鲁姆教育目标分类学,构建原电池模型认知能力研究框架,设计开发测评工具。该测评工具经过试测、修正、再测、质量论证,最终确定。选取S市2所县级中学419名高中生为研究对象展开调查,基于所获得的有效数据,对高中生原电池模型认知能力水平进行分析,重点对高二、高三学生原电池模型认知能力进行了比对,依据研究结果,提出发展高中生原电池模型认知能力的建议。     

Manipulating electronic and magnetic properties of black phosphorene with 4d series transition metal adsorption

We carry out first-principles calculations within density-functional theory to investigate the structural, electronic and magnetic properties of 4d transition metal (TM) decorated monolayer black phosphorene (BP). The results indicate that the TM adsorption on BP can have dilute magnetic semiconductor (DMS) properties. The spin polarized semiconducting state is realized in BP by adsorption of Y, Nb and Ru, while a half-metal state is obtained by Tc adsorption. In the case of two same types of TMs adsorption on BP, only [email protected] shows DMS state. In particular, two different types of TMs decorated BP can induce magnetic moments, localized mainly on the 4d TMs and the neighboring P atoms. Furthermore, the 4d TMs may enrich the electronic properties of BP, such as half-metallic, metallic and semiconducting features. These findings suggest that the 4d TM adsorbed BP can be used as a potential next-generation spintronics and magnetic storage material.     

Entropies of a Toroidal Black Hole Due to Scalar and Dirac Fields

Using the thin film brick-wall model, the entropies of a toroidal black hole due to scalar and Dirac fields are investigated. The entropy due to the scalar field is one fourth of the horizon area, and that due to the Dirac field is seven eighth of the area. These results are similar to that in black holes with horizon topology S ². The cutoff in toroidal black hole is chosen as the same as one in black holes with horizon topology S ², which seems to mean that the thin film brick-wall model is universal.