全文获取类型
收费全文 | 41465篇 |
免费 | 5413篇 |
国内免费 | 5530篇 |
专业分类
化学 | 13730篇 |
晶体学 | 414篇 |
力学 | 3986篇 |
综合类 | 659篇 |
数学 | 19749篇 |
物理学 | 13870篇 |
出版年
2024年 | 119篇 |
2023年 | 489篇 |
2022年 | 822篇 |
2021年 | 973篇 |
2020年 | 1296篇 |
2019年 | 1153篇 |
2018年 | 1106篇 |
2017年 | 1276篇 |
2016年 | 1448篇 |
2015年 | 1229篇 |
2014年 | 1999篇 |
2013年 | 3155篇 |
2012年 | 2143篇 |
2011年 | 2563篇 |
2010年 | 2377篇 |
2009年 | 2816篇 |
2008年 | 2924篇 |
2007年 | 3082篇 |
2006年 | 2701篇 |
2005年 | 2336篇 |
2004年 | 2010篇 |
2003年 | 2080篇 |
2002年 | 1717篇 |
2001年 | 1405篇 |
2000年 | 1420篇 |
1999年 | 1247篇 |
1998年 | 1131篇 |
1997年 | 914篇 |
1996年 | 736篇 |
1995年 | 579篇 |
1994年 | 509篇 |
1993年 | 358篇 |
1992年 | 312篇 |
1991年 | 281篇 |
1990年 | 215篇 |
1989年 | 175篇 |
1988年 | 171篇 |
1987年 | 132篇 |
1986年 | 130篇 |
1985年 | 151篇 |
1984年 | 117篇 |
1983年 | 58篇 |
1982年 | 117篇 |
1981年 | 89篇 |
1980年 | 74篇 |
1979年 | 70篇 |
1978年 | 39篇 |
1977年 | 40篇 |
1976年 | 31篇 |
1974年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Yaron Paz Ellina Kesselman Lulu Fahoum Irina Portnaya Ory Ramon 《Journal of Polymer Science.Polymer Physics》2004,42(1):33-46
The effect of two strong salting-out salts (Na2SO4 and K2SO4) on the temperature-induced phase-separation process in aqueous solutions of poly(N-isopropylacrylamide) (PNIPA) was examined by attenuated total reflectance/Fourier transform infrared spectroscopy, differential scanning calorimetry, and viscosity measurements. On the basis of these measurements, a detailed scenario of the phase-separation process was deduced. The phase-separation scenario of solutions containing PNIPA and water was altered in the presence of sulfate ions. Here, the sulfate ions induced partial intrachain collapse, manifested by a relatively compact structure well below the lower critical solution temperature. This led to a more gradual, smooth phase transition, with temperature-resolved intrachain collapse and interchain aggregation and a lesser extent of hysteresis. Although at the macrolevel one may not be able to differentiate among various scenarios altering the solvent into a poor solvent, the aforementioned microlevel measurements provided a way to expose the difference between raising the temperature and adding cosolutes. Follow-up studies on the effect of salting-in salts will be presented. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 33–46, 2004 相似文献
42.
Won Keun Son Ji Ho Youk Taek Seung Lee Won Ho Park 《Journal of Polymer Science.Polymer Physics》2004,42(1):5-11
Electrospinning of cellulose acetate (CA) in a new solvent system and the deacetylation of the resulting ultrafine CA fibers were investigated. Ultrafine CA fibers (∼2.3 μm) were successfully prepared via electrospinning of CA in a mixed solvent of acetone/water at water contents of 10–15 wt %, and more ultrafine CA fibers (0.46 μm) were produced under basic pH conditions. Ultrafine cellulose fibers were regenerated from the homogeneous deacetylation of ultrafine CA fibers in KOH/ethanol. It was very rapid and completed within 20 min. The crystal structure, thermal properties, and morphology of ultrafine CA fibers were changed according to the degree of deacetylation, finally to those of pure cellulose, but the nonwoven fibrous mat structure was maintained. The activation energy for the deacetylation of ultrafine CA fibers was 10.3 kcal/mol. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 5–11, 2004 相似文献
43.
Behavior of cellulose in NaOH/Urea aqueous solution characterized by light scattering and viscometry
Cellulose was dissolved in 6 wt % NaOH/4 wt % urea aqueous solution, which was proven by a 13C NMR spectrum to be a direct solvent of cellulose rather than a derivative aqueous solution system. Dilute solution behavior of cellulose in a NaOH/urea aqueous solution system was examined by laser light scattering and viscometry. The Mark–Houwink equation for cellulose in 6 wt % NaOH/4 wt % urea aqueous solution at 25 °C was [η] = 2.45 × 10?2 weight‐average molecular weight (Mw)0.815 (mL g?1) in the Mw region from 3.2 × 104 to 12.9 × 104. The persistence length (q), molar mass per unit contour length (ML), and characteristic ratio (C∞) of cellulose in the dilute solution were 6.0 nm, 350 nm?1, and 20.9, respectively, which agreed with the Yamakawa–Fujii theory of the wormlike chain. The results indicated that the cellulose molecules exist as semiflexible chains in the aqueous solution and were more extended than in cadoxen. This work provided a novel, simple, and nonpollution solvent system that can be used to investigate the dilute solution properties and molecular weight of cellulose. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 347–353, 2004 相似文献
44.
Tae Young Kim Dong Myung Kim Won Jung Kim Tae Hee Lee Kwang S. Suh 《Journal of Polymer Science.Polymer Physics》2004,42(15):2813-2820
The effect of the triblock copolymer poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] (SEBS) on the formation of the space charge of immiscible low‐density polyethylene (LDPE)/polystyrene (PS) blends was investigated. Blends of 70/30 (wt %) LDPE/PS were prepared through melt blending in an internal mixer at a blend temperature of 220 °C. The amount of charge that accumulated in the 70% LDPE/30% PS blends decreased when the SEBS content increased up to 10 wt %. For compatibilized and uncompatibilized blends, no significant change in the degree of crystallinity of LDPE in the blends was observed, and so the effect of crystallization on the space charge distribution could be excluded. Morphological observations showed that the addition of SEBS resulted in a domain size reduction of the dispersed PS phase and better interfacial adhesion between the LDPE and PS phases. The location of SEBS at a domain interface enabled charges to migrate from one phase to the other via the domain interface and, therefore, resulted in a significant decrease in the amount of space charge for the LDPE/PS blends with SEBS. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2813–2820, 2004 相似文献
45.
L. A. Utracki 《Journal of Polymer Science.Polymer Physics》2004,42(15):2909-2915
The Simha and Somcynsky (S–S) statistical thermodynamics theory was used to compute the solubility parameters as a function of temperature and pressure [δ = δ(T, P)], for a series of polymer melts. The characteristic scaling parameters required for this task, P*, T*, and V*, were extracted from the pressure–temperature–volume (PVT) data. To determine the potential polymer–polymer miscibility, the dependence of δ versus T (at ambient pressure) was computed for 17 polymers. Close proximity of the δ versus T curves for four miscible polymer pairs: PPE/PS, PS/PVME, and PC/PMMA signaled the usefulness of this approach. It is noteworthy, that the tabulated solubility parameters (derived from the solution data under ambient conditions) propounded the immiscibility of the PVC/PVAc pair. The computed values of δ also suggested miscibility for polymer pairs of unknown miscibility, namely PPE/PVC, PPE/PVAc, and PET/PSF. In recognizing the limitations of the solubility parameter approach (the omission of several thermodynamic contributions), these preliminary results are auspicious because they indicate a new route for estimating the miscibility of any polymeric material at a given temperature and pressure. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2909–2915, 2004 相似文献
46.
For vector quasivariational inequalities involving multifunctions in topological vector spaces, an existence result is obtained without a monotonicity assumption and with a convergence assumption weaker than semicontinuity. A new type of quasivariational inequality is proposed. Applications to quasicomplementarity problems and traffic network equilibria are considered. In particular, definitions of weak and strong Wardrop equilibria are introduced for the case of multivalued cost functions. 相似文献
47.
Wolfgang Knirsch 《Mathematische Nachrichten》2004,265(1):15-23
On weighted spaces with strictly plurisubharmonic weightfunctions the canonical solution operator of and the ‐Neumann operator are bounded. In this paper we find a class of strictly plurisubharmonic weightfunctions with certain growth conditions, so that they are Hilbert‐Schmidt operators between weighted spaces with different weightfunctions, if they are restricted to forms with holomorphic coefficients. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
48.
We construct a universal space for the class of proper metric spaces of bounded geometry and of given asymptotic dimension. As a consequence of this result, we establish coincidence of asymptotic dimension with asymptotic inductive dimension. 相似文献
49.
Boris Goldfarb 《Topology and its Applications》2004,140(2-3):267-294
New compactifications of symmetric spaces of noncompact type X are constructed using the asymptotic geometry of the Borel–Serre enlargement. The controlled K-theory associated to these compactifications is used to prove the integral Novikov conjecture for arithmetic groups. 相似文献
50.
Hans TRIEBEL 《应用数学学报(英文版)》2004,(4)
The paper deals with multifractal quantities for some types of Radon measures,especiallyself-similar probability measures,and their relations to Besov spaces. 相似文献