The thermodynamic functions and the regions of (P,T)-states of dense carbon and boron nitride modifications

Abstract

For the first time the thermodynamic functions for boron nitride and carbon were defined in the temperature range 300 to 4000K by a computational procedure which was impossible in the previous empirical approach. This involved the application of the theoretical functions from Refs. 1, 2, and 3. There the temperature dependence of the heat capacity is characterized by a sum of two Debye functions that reflect the contribution of vibration modes of different characteristic temperature to the heat capacity. The above-mentioned theoretical functions make it possible to calculate the thermodynamic function without allowing for the anharmonic effect in the temperature range rather wider th-an the one wherein the initial experiments were conducted. It is sufficient for their computation to define Debye characteristic temperatures. One of the procedures of their calculation using experimental enthalpy data is described in Ref. 4. Besides, this work contains the majority of known experimental and theoretical data which enable various methods of the thermodynamic function characterizations for carbon and boron nitride to be compared.     

Spectroscopy of rotating linear dilaton black holes from boxed quasinormal modes

Numerical studies of the coupled Einstein‐Klein‐Gordon system have recently revealed that confined scalar fields generically collapse to form caged black holes. In the light of this finding, we analytically study the characteristic resonance spectra of the confined scalar fields in rotating linear dilaton black hole geometry. Confining mirrors (cage) are assumed to be placed in the near‐horizon region of a caged rotating linear dilaton black hole ( is the radius of the cage and r₂ represents the event horizon). The radial part of the Klein‐Gordon equation is written as a Schrödinger‐like wave equation, which reduces to a Bessel differential equation around the event horizon. Using analytical tools and proper boundary conditions, we obtain the boxed‐quasinormal mode frequencies of the caged rotating linear dilaton black hole. Finally, we employ Maggiore's method, which evaluates the transition frequency in the adiabatic invariant quantity from the highly damped quasinormal modes, in order to investigate the entropy/area spectra of the rotating linear dilaton black hole.     

New Double-Periodic Soliton Solutions for the (2+1)-Dimensional Breaking Soliton Equation

Under investigation is the (2+1)-dimensional breaking soliton equation. Based on a special ansätz functions and the bilinear form, some entirely new double-periodic soliton solutions for the (2+1)-dimensional breaking soliton equation are presented. With the help of symbolic computation software Mathematica, many important and interesting properties for these obtained solutions are revealed with some figures.     

Confidence intervals and ellipsoids for estimable functions and estimable vectors in models with orthogonal block structure

Sub-models of mixed linear models are considered. The independence of these sub-models leads to sufficient statistics for the parameters relevant for their densities. Using pivot variables, confidence regions are obtained as well hypothesis testing for variance components, estimable functions, and estimable vectors. In addition, to compare the estimators and the models, we present the histograms with the empirical joint densities for positive and negative parts of the estimators. The figures, for the two-dimensional charts, contain the corresponding UMVUE and are all unimodal with the UMVUE near the mode. The nearness of the estimators and the modes validates the presented methodology and allows the safe use of induced densities. A numerical example applied to real data is presented.     

Which sets are images of disk-algebra functions?

We give a characterization of those compact sets in the plane with finitely many holes that are images of disk-algebra functions. We also show that the image of the closed unit disk via a polynomial is, in general, not polynomially convex.     

An Extremal Problem Arising in the Dynamics of Two-Phase Materials That Directly Reveals Information about the Internal Geometry

In two-phase materials, each phase having a non-local response in time, it has been found that for some driving fields the response somehow untangles at specific times, and allows one to directly infer useful information about the geometry of the material, such as the volume fractions of the phases. Motivated by this, and to obtain an algorithm for designing appropriate driving fields, we find approximate, measure independent, linear relations between the values that Markov functions take at a given set of possibly complex points, not belonging to the interval [-1,1] where the measure is supported. The problem is reduced to simply one of polynomial approximation of a given function on the interval [-1,1] and, to simplify the analysis, Chebyshev approximation is used. This allows one to obtain explicit estimates of the error of the approximation, in terms of the number of points and the minimum distance of the points to the interval [-1,1]. Assuming this minimum distance is bounded below by a number greater than 1/2, the error converges exponentially to zero as the number of points is increased. Approximate linear relations are also obtained that incorporate a set of moments of the measure. In the context of the motivating problem, the analysis also yields bounds on the response at any particular time for any driving field, and allows one to estimate the response at a given frequency using an appropriately designed driving field that effectively is turned on only for a fixed interval of time. The approximation extends directly to Markov-type functions with a positive semidefinite operator valued measure, and this has applications to determining the shape of an inclusion in a body from boundary flux measurements at a specific time, when the time-dependent boundary potentials are suitably tailored. © 2022 Wiley Periodicals, Inc.     

Relations between the Coulomb gas picture and conformal invariance of two-dimensional critical models

Partition functions of critical 2D models on a torus can be derived from their microscopic formulation and their free field representation in the continuum limit. This is worked out explicitly for theO(n) andQ-state Potts model. Forn orQ integer we recover results obtained from conformal invariance, but our procedure also extends to nonintegral values. In the latter case the expansion on characters of the Virasoro algebra involves real coefficients of either sign. The operator content of both models is discussed in detail.     

The time-local view of nonequilibrium statistical mechanics. I. Linear theory of transport and relaxation

The various approaches to nonequilibrium statistical mechanics may be subdivided into convolution and convolutionless (time-local) ones. While the former, put forward by Zwanzig, Mori, and others, are used most commonly, the latter are less well developed, but have proven very useful in recent applications. The aim of the present series of papers is to develop the time-local picture (TLP) of nonequilibrium statistical mechanics on a new footing and to consider its physical implications for topics such as the formulation of irreversible thermodynamics. The most natural approach to TLP is seen to derive from the Fourier-Laplace transform ) of pertinent time correlation functions, which on the physical sheet typically displays an essential singularity at z= and a number of macroscopic and microscopic poles in the lower half-plane corresponding to long- and short-lived modes, respectively, the former giving rise to the autonomous macrodynamics, whereas the latter are interpreted as doorway modes mediating the transfer of information from relevant to irrelevant channels. Possible implications of this doorway mode concept for socalled extended irreversible thermodynamics are briefly discussed. The pole structure is used for deriving new kinds of generalized Green-Kubo relations expressing macroscopic quantities, transport coefficients, e.g., by contour integrals over current-current correlation functions obeying Hamiltonian dynamics, the contour integration replacing projection. The conventional Green-Kubo relations valid for conserved quantities only are rederived for illustration. Moreover, may be expressed by a Laurent series expansion in positive and negative powers ofz, from which a rigorous, general, and straightforward method is developed for extracting all macroscopic quantities from so-called secularly divergent expansions of as obtained from the application of conventional many-body techniques to the calculation of . The expressions are formulated as time scale expansions, which should rapidly converge if macroscopic and microscopic time scales are sufficiently well separated, i.e., if lifetime (memory) effects are not too large.