全文获取类型
收费全文 | 1277篇 |
免费 | 183篇 |
国内免费 | 95篇 |
专业分类
化学 | 935篇 |
晶体学 | 3篇 |
力学 | 32篇 |
综合类 | 10篇 |
数学 | 327篇 |
物理学 | 248篇 |
出版年
2023年 | 19篇 |
2022年 | 29篇 |
2021年 | 27篇 |
2020年 | 63篇 |
2019年 | 64篇 |
2018年 | 39篇 |
2017年 | 41篇 |
2016年 | 65篇 |
2015年 | 59篇 |
2014年 | 73篇 |
2013年 | 123篇 |
2012年 | 100篇 |
2011年 | 86篇 |
2010年 | 86篇 |
2009年 | 64篇 |
2008年 | 80篇 |
2007年 | 68篇 |
2006年 | 69篇 |
2005年 | 49篇 |
2004年 | 44篇 |
2003年 | 40篇 |
2002年 | 30篇 |
2001年 | 17篇 |
2000年 | 24篇 |
1999年 | 21篇 |
1998年 | 28篇 |
1997年 | 33篇 |
1996年 | 14篇 |
1995年 | 15篇 |
1994年 | 10篇 |
1993年 | 6篇 |
1992年 | 13篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1976年 | 5篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有1555条查询结果,搜索用时 296 毫秒
91.
《Angewandte Chemie (International ed. in English)》2017,56(13):3699-3702
The first single‐component N‐heterocyclic silylene borane 1 (LSi‐R‐BMes2; L=PhC(Nt Bu)2; R=1,12‐xanthendiyl spacer; Mes=2,4,6‐Me3C6H2), acting as a frustrated Lewis pair (FLP) in small‐molecule activation, can be synthesized in 65 % yields. Its HOMO is largely localized at the silicon(II) atom and the LUMO has mainly boron 2p character. In small‐molecule activation 1 allows access to the intramolecular silanone–borane 3 featuring a Si=O→B interaction through reaction with O2, N2O, or CO2, and formation of silanethione borane 4 from reaction with S8. The SiII center in 1 undergoes immediate hydrogenation if exposed to H2 at 1 atm pressure in benzene, affording the silane borane 5‐H2 , L(H2)Si‐R‐BMes2. Remarkably, no H2 activation occurs if the single silylene LSiPh and Mes3B intermolecularly separated are exposed to dihydrogen. Unexpectedly, the pre‐organized Si–B separation in 1 enables a metal‐free dehydrogenation of H2O to give the silanone–borane 3 as reactive intermediate. 相似文献
92.
93.
Anita Routaray Somanath Mantri Nibedita Nath Alekha Kumar Sutar Tungabidya Maharana 《中国化学快报》2016,27(12):1763-1766
In the present investigation, the novel copper Schiff base complex was synthesized and its catalytic activity was evaluated for the ring-opening polymerization (ROP) of lactide and block polymerization of poly(lactide) with poly(ethylene glycol)methyl ether. 相似文献
94.
Insertion Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated Lewis Pair Territory
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Adrien T. Normand Dr. Gerald Kehr Prof. Pierre Le Gendre Prof. Gerhard Erker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(12):4285-4293
Neutral phosphidozirconocene complexes [Cp2Zr(PR2)Me] (Cp=cyclopentadienyl; 1a : R=cyclohexyl (Cy); 1b : R=mesityl (Mes); 1c : R=tBu) undergo insertion into the Zr?P bond by non‐enolisable carbonyl building blocks (O=CR′R′′), such as benzophenone, aldehydes, paraformaldehyde or CO2, to give [Cp2Zr(OCR′R′′PR2)Me] ( 3 – 7 ). Depending on the steric bulk around P, complexes 3 – 7 react with B(C6F5)3 to give O‐bridged cationic zirconocene dimers that display typical frustrated Lewis pair (FLP)/ambiphilic ligand behaviour. Thus, the reaction of {[Cp2Zr(μ‐OCHPhPCy2)][MeB(C6F5)3]}2 ( 10a ) with chalcone results in 1,4 addition of the Zr+/P FLP, whereas the reaction of {[Cp2Zr(μ‐OCHFcPCy2)][MeB(C6F5)3]}2 ( 11a ; Fc=(C5H4)CpFe) with [Pd(η3‐C3H5)Cl]2 yields the unique Zr?Fe?Pd trimetallic complex 13a , which has been characterised by XRD analysis. 相似文献
95.
In view of the Bailey lemma and the relations between Hecke-type sums and Appell–Lerch sums given by Hickerson and Mortenson, we find that many Bailey pairs given by Slater can be used to deduce mock theta functions. Therefore, by constructing generalized Bailey pairs with more parameters, we derive some new families of mock theta functions. Meanwhile, some identities between new mock theta functions and classical ones are established. Furthermore, based on the proofs of the main theorems, many q-hypergeometric transformations are obtained. 相似文献
96.
97.
98.
Structure and Photoelectric Characteristics of Functional Polymers and of Compositions Based on Them 总被引:1,自引:0,他引:1
The electronic processes in disordered organic solids were analyzed, classified, and summarized. They include the photogeneration of charge pairs, electron transport, geminal and bimolecular recombination, and the capture of charge carriers in local electronic states. General criteria were formulated for the targeted search for and the creation of new prospective polymers and their compositions with organic pigments and related compounds having specific photoelectric characteristics for electrographic and holographic media, photoelectric converters, and electroluminescent and photorefractive devices. 相似文献
99.
100.