Asymptotic expansions of Kummer hypergeometric functions with three asymptotic parameters a,b and z

In a recent paper (Temme, 2021) new asymptotic expansions are given for the Kummer functions $M(a,b,z)$ and $U(a,b+1,z)$ for large positive values of $a$ and $b$, with $z$ fixed and special attention for the case $a～b$. In this paper we extend the approach and also accept large values of $z$. The new expansions are valid when at least one of the parameters $a$, $b$, or $z$ is large. We provide numerical tables to show the performance of the expansions.     

Trace formulas for additive and non-additive perturbations

Trace formulas for pairs of self-adjoint, maximal dissipative and accumulative as well as other types of resolvent comparable operators are obtained. In particular, the existence of a complex-valued spectral shift function for a pair {H^′,H}$\{H^{\prime },H\}$ of maximal accumulative operators has been proved. We investigate also the existence of a real-valued spectral shift function. Moreover, we treat in detail the case of additive trace class perturbations. Assuming that H   and H^′=H+V$H^{\prime }=H+V$ are maximal accumulative and V is trace class, we prove the existence of a summable   complex-valued spectral shift function. We also obtain trace formulas for pairs {H,H^?}$\{H,H^{?}\}$assuming only that H and  H^?$H^{?}$are resolvent comparable. In this case the determinant of the characteristic function of H is involved in trace formulas.     

Relevance between the Chemical Structure Modifications and Physicochemical Descriptors of Chemical Reactivity for Series of Nitroxide Radicals

This work presents an experimental and theoretical study to address the chemical reactivity of series of nitroxide radicals. For that purpose two physicochemical properties: the half-wave potential and the hyperfine coupling constants of the nitrogen nuclei, were analyzed. Experimental values are compared with electronic structure calculations at the BHandHLYP/6-311++G(2d,2p) level. E_1/2 values were in good agreement with the adiabatic ionization potential when including the solvent effects by the Cramer and Truhlar Solvation Model. Preeliminar experimental electron spin deslocalization studies suggest that structural hindrance plays an important role in their deslocatization mechanism.     

Modeling of pair distribution functions for XAFS in disordered systems

A commonly used expression for modeling the XAFS of highly disordered systems is shown to generate substantial systematic errors in the coordination number in many cases of practical interest. This expression is corrected and generalized. Further, a simpler and more flexible model distribution is proposed, and the corresponding XAFS expression is derived. Comparison with experimental and simulated data show that the new expressions are useful in cases of high disorder for which the cumulant expansion loses its utility, and they explicitly account for the k-dependence of the mean free path.     

Gap Functions for Equilibrium Problems

The theory of gap functions, developed in the literature for variational inequalities, is extended to a general equilibrium problem. Descent methods, with exact an inexact line-search rules, are proposed. It is shown that these methods are a generalization of the gap function algorithms for variational inequalities and optimization problems.     

A generalized preimage theorem in global analysis

The concept of locally fine point and generalized regular value of a C¹ map between Banach spaces were carried over C¹ map between Banach manifolds. Hence the preimage theorem, a principle constructing Banach manifolds in global analysis, is generalized.     

Properties of an exact crystalline many-body ground state

A new quantum many-body Hamiltonian is introduced, for which the exact ground state is a Jastrow-type product. This Hamiltonian is interpreted as a one-component |x|-potential Coulomb system in free boundary conditions, and by explicit calculation it is shown that the ground state is crystalline. The generaln-body density matrix is calculated, and is related to then-body density matrix calculated in periodic boundary conditions.     

Some properties of bivariate Gumbel Type A distributions with proportional hazard rates

We call a set of univariate distributions with the same mathematical form but different parameter values a family $\text{J}$. Consider a bivariate Gumbel Type A survival distribution, S₁₂(x₁, x₂), defined in (2.1), for which both marginal distributions, S₁(x₁), S₂(x₂), belong to the same family, $\text{J}$ of distributions. It is proved in this paper that subject to weak conditions, the crude hazard rates, h₁(t) and h₂(t), are proportional if and only if the marginal hazard rates, λ₁(t) and λ₂(t), are proportional (Theorem 1). It is also shown that the survival functions of W = min(X₁, X₂), and of the identified minimum, W_i = X_i, for X_i < X_j, j ≠ i, belong to the same family $\text{J}$ as do S₁(x₁), S₂(x₂) (Corollary 1). Counter-examples of distributions other than Gumbel Type A, for which these properties do not hold, are given. Some applications to the analysis of competing risks, using a family of Gompertz distributions, are discussed.