氩气/空气介质阻挡放电自组织超六边形斑图实验研究

采用双水电极介质阻挡放电装置,在氩气/空气混合气体放电中,在三种边界条件下得到了一种新型的超六边形斑图.给出了超六边形斑图的傅里叶变换及其不同模强度随旋转角的变化.实验测量了超六边形斑图随空气含量和外加电压变化的相图.研究了超六边形斑图的时空动力学,发现超六边形斑图是由两套子结构嵌套而成.在四边形边界条件下,研究了放电面积的大小对斑图模式选择的影响.发现超四边形斑图的形成受边界条件影响很大,而超六边形斑图则是自组织的结果. 关键词： 介质阻挡放电 超六边形斑图 时空动力学 边界条件     

Elastic behavior of composites containing multi-layer coated particles with imperfect interface bonding conditions and application to size effects and mismatch in these composites

This paper proposes a procedure to deal with n-layered inclusion based composites with imperfect interfaces (which conditions consist of displacement or stress vector jumps) respecting spherical symmetry. For that purpose, “discontinuity matrices” have been introduced. These matrices have been derived for several classical interface-models and an asymptotic method has been used to determine some of them. A self-consistent condition based on a strain-energy equivalence in the case of inclusion-matrix type composite materials is restated for n-layered inclusions with imperfect interfaces and applied to get estimates of such composites materials. The remarkable feature of the presently self consistent approach is that it does not need any tedious algebra providing the attached interface models respect the spherical symmetry. The present Generalized Self Consistent Model (GSCM) is then used to study size effects and mismatch in composites reinforced by coated inclusions.     

Piperidine‐functionalized silica: an efficient and environmentally benign catalyst for Claisen–Schmidt condensation

Piperidine‐functionalized silica as a basic heterogeneous catalyst was synthesized via a simple protocol by condensing silica chloride with piperidine. The catalyst was characterized with various techniques (FT‐IR, solid state NMR, scanning electron microscopy, energy‐dispersive X‐ray, thermogravimetric, elemental, and NH₃ and CO₂ temperature‐programmed desorption analyses). Surface area was also evaluated through Brunauer–Emmett–Teller analysis. Its catalytic activity was evaluated for Claisen–Schmidt condensation under solvent‐free conditions. The catalyst was easily recovered and reused up to five cycles without considerable loss of activity and was not deactivated due to amide formation. Also, this method has attractive advantages such as short reaction time, mild reaction conditions, good to excellent yield of products, easy handling of the catalyst and simple operational procedure. Copyright © 2014 John Wiley & Sons, Ltd.     

可积开边界条件下的q形变玻色子模型

利用代数Bethe Ansatz方法在可积开边界条件下推广了q形变玻色子模型，得到可积开边界条件下此模型的哈密顿量及其本征方程.该工作可为在更小尺度下研究具有相互作用的玻色子系统提供有效的理论基础. 关键词： 代数Bethe Ansatz q形变玻色子模型')" href="#">q形变玻色子模型 开边界 可积系统     

Theory and computation for multiple positive solutions of non-local problems at resonance

Resonance non-positone and non-isotone problems for first order differential systems subjected to non-local boundary conditions are reduced to the non-resonance positone and isotone case by changes of variables. This allows us to prove the existence of multiple positive solutions. The theory is illustrated by two examples for which three positive numerical solutions are obtained using the Mathematica shooting program.     

高比表面积窄孔分布氧化铝的制备研究 Ⅰ.沉淀条件的影响

 以硫酸铝液为原料，以氨水、氢氧化钠和铝酸钠为碱沉淀剂，采用pH摆动法制备了高比表面积、大孔径、窄孔分布、大孔体积氧化铝，考察了沉淀剂、沉淀温度及沉淀时酸侧pH值对氧化铝物性的影响，并对pH摆动法与等pH沉淀法的结果进行了比较．结果表明，通过改变制备参数可以获得高比表面积、大孔体积的氧化铝，当沉淀温度为70℃，pH摆动3或4次时，氧化铝的孔体积可高达1．0ml／g，比表面积仍大于300m2／g．用pH摆动法制得的样品比用等pH沉淀法制得的样品容易酸溶，对挤压成型有利．不同样品在酸溶液中的分散性表明，用氨水沉淀剂可获得相对较小的沉淀粒子．改变沉淀时酸侧的pH值，可导致沉淀粒子的结构发生变化．     

不同退火条件对PEALD制备的Ga2O3薄膜特性的影响

利用等离子增强原子层沉积技术(PEALD)在c面蓝宝石衬底上制备了氧化镓(Ga₂O₃)薄膜,研究了退火气氛(v(N₂)∶v(O₂)=1∶1(体积比)、空气和N₂)及退火时间对Ga₂O₃薄膜晶体结构、表面形貌和光学性质的影响。研究结果表明,退火前的氧化镓处于亚稳态,不同退火气氛下退火后晶体结构发生明显改变,而且退火气氛中N₂比例增加有利于Ga₂O₃重结晶。在N₂气氛下退火达到30 min,薄膜结构已由亚稳态转变成择优取向的β-Ga₂O₃。而且表面形貌分析表明,退火30 min后表面形貌开始趋于稳定,表面晶粒密度不再增加。另外实验样品在 400~800 nm的平均透射率几乎是100%,且光吸收边陡峭。采用N₂气氛退火,对于富氧环境下沉积的Ga₂O₃更利于薄膜表面原子迁移,以及择优取向Ga₂O₃重结晶。     

Issue Information ‐ TOC

Numerical modeling of multiphase flow generally requires a special procedure at the solid wall in order to be consistent with Young's law for static contact angles. The standard approach in the lattice Boltzmann method, which consists of imposing fictive densities at the solid lattice sites, is shown to be deficient for this task. Indeed, fictive mass transfer along the boundary could happen and potentially spoil the numerical results. In particular, when the contact angle is less than 90 degrees, the deficiencies of the standard model are major. Various videos that demonstrate this behavior are provided (Supporting Information). A new approach is proposed and consists of directly imposing the contact angle at the boundaries in much the same way as Dirichlet boundary conditions are generally imposed. The proposed method is able to retrieve analytical solutions for static contact angles in the case of straight and curved boundaries even when variable density and viscosity ratios between the phases are considered. Although the proposed wetting boundary condition is shown to significantly improve the numerical results for one particular class of lattice Boltzmann model, it is believed that other lattice Boltzmann multiphase schemes could also benefit from the underlying ideas of the proposed method. The proposed algorithm is two‐dimensional, and the D2Q9 lattice is used. Copyright © 2016 John Wiley & Sons, Ltd.     

束-气条件下He(23S)与CH3Cl及CH3I的传能研究

在束-气条件下，通过检测产物的化学发光，研究了亚稳电子激发态He（23S）原子与CH3Cl、CH3I传能反应.采用参比反应的方法，测得了由上述反应产生的主要碎片CH（A2△）、CH（B2∑-）、CH（C2∑+）和H*形成速率常数．通过对测得的CH（A2△－X2∏r）和CH（B2∑-－X2∏r）色散谱进行计算机模拟，获得了初生态的CH（A2△，v＝0－2）和CH（B2∑-，v＝0态）的振动-转动布居，实验结果表明，CH（A2△，v＝0）态的转动布居是呈双Boltzman分布的，并且反应的可资用能大部分将转变成产物的平动能．根据实验结果和反应阈能的分析，本文对He（23S）与CH3Cl／CH3I传能反应机理进行了探讨。     

核为G(nλ1xλ2)(λ1λ2 > 0)的半离散Hilbert型不等式成立的等价参数条件及应用*

利用权函数方法和实分析技巧, 在λ₁λ₂ > 0 的条件下,讨论具有非齐次核K(n,x)=G(n^λ₁x^λ₂)的半离散Hilbert型不等式成立的等价参数条件及最佳常数因子问题, 最后讨论其在算子理论中的应用.