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71.
Yasuhiko Iwasaki Keiko Shimakata Nobuyuki Morimoto Kimio Kurita 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):68-75
To obtain a hydrogel‐like elastic membrane, we prepared semi‐interpenetrating polymer networks (IPNs) by the radical polymerization of methacrylates such as 2‐methacryloyloxyethyl phosphorylcholine (MPC), 2‐hydroxyethylmethacrylate, and triethyleneglycol dimethacrylate diffused into segmented polyurethane (SPU) membranes swollen with a monomer mixture. The values of Young's modulus for the hydrated semi‐IPN membranes were less than that for an SPU membrane because of higher hydration, but they were much higher than that for a hydrated MPC polymer gel (non‐SPU). According to a thermal analysis, the MPC polymer influenced the segment association of SPU. The diffusion coefficient of 8‐anilino‐1‐naphthalenesulfonic acid sodium salt from the semi‐IPN membrane could be controlled with different MPC unit concentrations in the membrane, and it was about 7 × 102 times higher than that of the SPU membrane. Fibroblast cell adhesion on the semi‐IPN membrane was effectively reduced by the MPC units. We concluded that semi‐IPNs composed of the MPC polymer and SPU may be novel polymer materials possessing attractive mechanical, diffusive‐release, and nonbiofouling properties. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 68–75, 2003 相似文献
72.
Vladimir E. Bondarenko 《Complexity》2005,11(2):39-52
Information processing and two types of memory in an analog neural network model with time delay that produces chaos similar to the human and animal EEGs are considered. There are two levels of information processing in this neural network: the level of individual neurons and the level of the neural network. Similar to the state of brain, the state of chaotic neural network is defined. It is characterized by two types of memories (memory I and memory II) and correlation structure between the neurons. In normal (unperturbed) state, the neural network generates chaotic patterns of averaged neuronal activities (memory I) and patterns of oscillation amplitudes (memory II). In the presence of external stimulation, the activity patterns change, showing changes in both types of memory. As in experiments on stimulation of the brain, the neural network model shows synchronization of neuronal activities due to stimulus measured by Pearson's correlation coefficient. An increase in neural network asymmetry (increase of the neural network excitability) leads to the phenomenon similar to the epilepsy. Modeling of brain injury, Parkinson's disease, and dementia is performed by removing and weakening interneuron connections. In all cases, the chaotic neural network shows a decrease of the degree of chaos and changes in both types of memory similar to those observed in experiments with healthy human subjects and patients with Parkinson's disease and dementia. © 2005 Wiley Periodicals, Inc. Complexity 11:39–52, 2005 相似文献
73.
74.
Efrosyni Themistou Amelia Kanari Costas S. Patrickios 《Journal of polymer science. Part A, Polymer chemistry》2007,45(24):5811-5823
A compact, cleavable acylal dimethacrylate cross‐linker, 1,1‐ethylenediol dimethacrylate (EDDMA), was synthesized from the anhydrous iron(III) chloride‐catalyzed reaction between methacrylic anhydride and acetaldehyde. The ability of EDDMA to act as cross‐linker was demonstrated by using it for the preparation of one neat cross‐linker network, four star polymers of methyl methacrylate (MMA), and four randomly cross‐linked MMA polymer networks using group transfer polymerization (GTP). For comparison, the corresponding polymer structures based on the commercially available ethylene glycol dimethacrylate (EGDMA) cross‐linker (isomer of EDDMA) were also prepared via GTP. The number of arms of the EDDMA‐based star polymers was lower than that of the corresponding EGDMA polymers, whereas the degrees of swelling in tetrahydrofuran of the EDDMA‐based MMA networks were higher than those of their EGDMA‐based counterparts. Although none of the EDDMA‐containing polymers could be cleanly hydrolyzed under basic or acidic conditions, they could be thermolyzed at 200 °C within 1 day giving lower molecular weight products. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5811–5823, 2007 相似文献
75.
S. A. Patlazhan 《Journal of Polymer Science.Polymer Physics》1993,31(12):1649-1665
A statistical theory of light scattering from deformed isotropic and textured heterogeneous polymer materials is formulated. Two types of textured structures are analyzed: assemblies of optically isotropic and anisotropic rods and a spatially anisotropic distribution of isotropic spherical inclusion centers. The small-angle Hv light-scattering patterns are calculated. The appearance of scattering from isotropic rods and spheres in deformed materials has been demonstrated. The changes of the Hv scattering patterns as a function of elongation and strucuture parameters are discussed. © 1993 John Wiley & Sons, Inc. 相似文献
76.
3族新的不含紧优与几乎紧优的有向双环网络无限族 总被引:2,自引:0,他引:2
给出了3族新的不含紧优与几乎紧优的有向双环网络. 相似文献
77.
本文分析了传统的网络可靠性优化设计方法所存在的问题 ,给出了网络的通信通路数的定义 ,并基于网络的通信通路数给出了更能反映网络运行的实际情况的网络可靠性的定量模型 ,从而解决了传统网络可靠性优化设计方法所存在的问题 . 相似文献
78.
In this paper, we propose the treatment of complex reservoir operation problems via our newly developed tool of fuzzy criterion
decision processes. This novel approach has been shown to be a more flexible and useful analysis tool especially when it is
desirable to incorporate an expert’s knowledge into the decision models. Additionally, it has been demonstrated that this
form of decision models will usually result in an optimal solution, which guarantees the highest satisfactory degree. We provide
a practical exemplification procedure for the models presented as well as an application example. 相似文献
79.
J. Daum G. Erdodi J. P. Kennedy 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4053-4062
The synthesis and characterization of two groups of novel networks prepared from cyclolinear polysiloxanes are described. The first group of networks from cyclolinear polysiloxanes (N‐CLPSs) was synthesized by the hydrosilation of vinyl‐terminated cyclolinear polyorganosiloxanes [prepared from diacetoxydiethyltetramethylcyclotetrasiloxane (D4Et2OAc2) or diacetoxytriethylpentamethylcyclopentasiloxane (D5Et3OAc2)] with a copolymer of dimethylsiloxane and methylhydrosiloxane as the crosslinking agent. Hydrosilation was effected with a platinum carbonyl catalyst with a cyclovinylsiloxane moderator. The second group of networks (N‐eCLPSs) was prepared similarly with extended cyclolinear polysiloxanes. The mechanical properties of the novel networks were comparable to those of polydimethylsiloxane networks (N‐PDMS). The oxygen permeabilities were similar to or slightly higher than that of N‐PDMS. The glass‐transition temperatures of D4Et2OAc2‐ and D5Et3OAc2‐based N‐CLPSs were ?67.8 and ?90.8 °C, respectively, whereas the incorporation of polydimethylsiloxane spacers into similar N‐eCLPSs lowered their glass‐transition temperatures to ?109.7 and ?115.0 °C. Upon heating to 800 °C in air, N‐CLPSs yielded more residue than N‐eCLPSs, which in turn yielded more residue than N‐PDMS. These results may have been due to the presence of T units in the cyclic siloxane units, which may have inhibited chain degradation or the formation of volatile products. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4053–4062, 2006 相似文献
80.
本文给出了一种方法用于构造k-紧优双环网络无限族(k≥1),并用此方法构造出了4族3-紧优无限族,3族新的4-紧比无限族,3族5-紧优无限族及2族6-紧优无限族. 相似文献