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Min-zhi Chen Xiao-liang Wang Fang-fang Tao Qi Xue Ping-chuan 《高分子科学》2007,(1):107-111
The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only provide indirectly the information of the degree of entanglement in a relatively large scale (several to tens of nanometer). In this article, we report ^1H-NMR spectroscopy with dipolar filters under fast magic angle spinning for probing chain interpenetration of polymer glasses at the molecular level. 相似文献
43.
Jae‐Woon Nah Mi‐Kyeong Jang 《Journal of polymer science. Part A, Polymer chemistry》2002,40(21):3796-3803
Low molecular, water‐soluble chitosan (LMWSC) with a free amine group was prepared by the novel salts‐removal method described in this study. A weight‐average molecular weight and degree of deacetylation (DDA) of LMWSC were determined by viscometry and Kina titration, resulting in 18,579 Da and 93% DDA, respectively. In the Fourier transform infrared spectroscopic, 1H NMR, and 13C NMR spectra the absorption band by the carboxyl group derived from lactic acid and the impurities formed in the enzymatic process disappeared or were significantly lower than that of the control chitosan. Also, from the 1H NMR and 13C NMR spectra the empirical value for the area ratio of the proton and carbon corresponds nearly to its theoretical values. The matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrum identified the difference in the two adjacent peaks as 161. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 3796–3803, 2002 相似文献
44.
《Arabian Journal of Chemistry》2022,15(12):104368
Protein hydrolysates have the potential to be natural and safer sources of bioactive peptides. In this study, two proteases were used to hydrolyze Chinese sturgeon (Acipenser sinensis) protein, and the hydrolysates were then purified to yield antioxidant peptides. The degree of hydrolysis of 23.56 % and 18.14 % was obtained using papain and alcalase 2.4L, respectivly, and hydrolysates had 96.80 % and 87.24 % total amino acid content, respectivly. The papain hydrolysate (PH) and alcalase 2.4L hydrolysate (AH) showed good antioxidant activity against DPPH? (IC50 of 3.64 and 3.15 mg/mL) and ABTS?+ (IC50 of 1.92 and 1.58 mg/mL), respectively. The low-molecular-weight (<1000 Da) fraction of both hydrolysates demonstrated the highest antiradical activity (IC50 of 2.59 and 2.31 mg/mL, DPPH) and (IC50 of 1.54 and 1.36 mg/mL, ABTS), respectively. Nine peptides were separated from both hydrolysates using reverse phase high performance liquid chromatography (RP-HPLC). The IC50 for ABTS?+ scavenging activity of peptide P5 with valine, glycine and asparagine (MW of 282.13 Da) from PH, and peptide P3 with histidine, glycine and alanine (MW of 302.74 Da) from AH was 0.89 and 0.72 mg/mL, respectively. The fractions and purified peptides obtained from Chinese sturgeon hydrolysates could be utilized as natural antioxidant substitutes in pharmaceuticals and food products. 相似文献
45.
The kinetics of suspended emulsion polymerization of methyl methacrylate (MMA), in which water acted as the dispersed phase and the mixture of MMA and cyclohexane as the continuous phase, was investigated. It showed that the initial polymerization rate (Rp0) and steady-state polymerization rate (Rp) were proportional to the mass ratio between water and oil phase, and increased as the polymerization temperature, the potassium persulphate concentration ([I]) and the Tween20 emulsifier concentration ([S]) increased. The relationships between the polymerization rate and [I] and [S] were obtained as follows: Rp0 ∝ [I]0.73[S]0.32 and Rp ∝ [I]0.71[S]0.23. The above exponents were close to those obtained from normal MMA emulsion polymerization. It also showed that the average molecular weight of the resulting poly(methyl methacrylate) decreased as the polymerization temperature, [I] and [S] increased. Thus, MMA suspended emulsion polymerization could be considered as a combination of many miniature emulsion polymerizations proceeding in water drops and obeyed the classical kinetics of MMA emulsion polymerization. 相似文献
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Utilizing fountain codes to control the peak-to-average power ratio (PAPR) is a classic scheme in Orthogonal Frequency Division Multiplexing (OFDM) wireless communication systems. However, because the robust soliton distribution (RSD) produces large-degree values, the decoding performance is severely reduced. In this paper, we design statistical degree distribution (SD) under a scenario that utilizes fountain codes to control the PAPR. The probability of the PAPR produced is combined with RSD to design PRSD, which enhances the smaller degree value produced. Subsequently, a particle swarm optimization (PSO) algorithm is used to search the optimal degree value between the binary exponential distribution (BED) and PRSD distribution according to the minimum average degree principle. Simulation results demonstrate that the proposed method outperforms other relevant degree distributions in the same controlled PAPR threshold, and the average degree value and decoding efficiency are remarkably improved. 相似文献
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基于之前减速电场能量分析的设计与实验,针对实验中出现的绝缘性不好、能量分辨率不高等问题,对原结构进行了改进与仿真分析,以更好地实现行波管电子枪电子注及注波互作用后电子注参数的精确测量和分析,为行波管的设计、性能改进和研制提供参考。该可控聚焦型减速场能量分析器结构将高压圆筒与减速栅网进行电气绝缘隔离,并在二者之间设置一个可控的小电压,产生的第二个静电透镜对发散的电子注产生加速会聚的作用,以削弱在第一个透镜聚焦作用的薄弱区域空间电荷效应及电子注发射角等因素对注发散的影响,调整粒子轨迹倾斜度和分辨率。同时,整体结构在不影响测试精度的情况下向小型化和轻型化发展。应用CST粒子工作室对不同粒子界面处粒子分布及整体场结构进行模拟,然后用Matlab软件进行数据处理并导出关键参数。着重分析结构性能的优化和提升在分辨率及半峰值全宽度等参数上的体现。结果表明该能量分析器适用于几keV到10 keV的强流电子注的测量。 相似文献
50.
选择腰椎间盘突出症(LDH)患者60例,分为轻度退变组、中度退变组、重度退变组.患者均行MRI检查,比较3组的MRI参数,包括髓核(NP)区、纤维环(AF)区T2值.检测比较发现,3组LDH患者NP区、AF区T2值间存在明显差异,且与腰椎功能评分(JOA)呈正相关,与腰部疼痛评分(VAS)呈负相关(P<0.05).NP... 相似文献