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31.
Shu Fen Wang Wen Guo Zou Su Wen Liu Dong Xu Duo Rong Yuan Guang Jun Zhou 《Journal of Physics and Chemistry of Solids》2004,65(7):1243-1245
The photoluminescence properties of the Bi3+ in sol-gel derived ZnTiO3 nanocrystals have been investigated. An ultra-violet emission at 360 nm and a visible emission band at 506 nm have been observed, originating from two kinds of emission centers. The former is ascribed to the 3P1-1S0 transition of Bi3+ and the latter to the recombination of the electrons with the photo-generated holes trapped in the zinc vacancies. In all cases the latter contribution is predominant. 相似文献
32.
Maculalactones A, B and C from the marine cyanobacterium Kyrtuthrix maculans are amongst the only compounds based on the tribenzylbutyrolactone skeleton known in nature and (+) maculalactone A from the natural source possesses significant biological activity against various marine herbivores and marine settlers. We now report a concise synthesis of racemic maculalactone A in five steps from inexpensive starting materials. Maculalactones B and C were synthesized by a minor modification to this procedure, and the synthetic design also permitted an asymmetric synthesis of maculalactone A to be achieved in around 85% ee. The (+) and (−) enantiomers of maculalactone A were assigned, respectively, to the S and R configurations on the basis of the chiral selectivity expected for catecholborane reduction of an unsymmetrical ketone in the presence of Corey's oxazoborolidine catalyst. Surprisingly, it appeared that natural (+) maculalactone A was biosynthesized in K. maculans in a partially racemic form, comprising ca. 90-95% of the (S) enantiomer and 5-10% of its (R) enantiomer. Coincidentally therefore, the percentage enantiomeric excess of the product obtained from asymmetric synthesis almost exactly matched that found in nature. 相似文献
33.
The synthesis of enantiopure bis-THF is described, starting from d-mannitol. Bis-THF is used as chiral ligand for organolithium reagents in four different reactions. The enantioselectivity provided by this ligand is moderate, and the asymmetric induction is in line with the expected model. 相似文献
34.
Some previous works show that symmetric fixed- and variable-stepsize linear multistep methods for second-order systems which do not have any parasitic root in their first characteristic polynomial give rise to a slow error growth with time when integrating reversible systems. In this paper, we give a technique to construct variable-stepsize symmetric methods from their fixed-stepsize counterparts, in such a way that the former have the same order as the latter. The order and symmetry of the integrators obtained is proved independently of the order of the underlying fixed-stepsize integrators. As this technique looks for efficiency, we concentrate on explicit linear multistep methods, which just make one function evaluation per step, and we offer some numerical comparisons with other one-step adaptive methods which also show a good long-term behaviour.
35.
A. M. Povolotsky V. B. Priezzhev Chin-Kun Hu 《Journal of statistical physics》2003,111(5-6):1149-1182
An asymmetric stochastic process describing the avalanche dynamics on a ring is proposed. A general kinetic equation which incorporates the exclusion and avalanche processes is considered. The Bethe ansatz method is used to calculate the generating function for the total distance covered by all particles. It gives the average velocity of particles which exhibits a phase transition from an intermittent to continuous flow. We calculated also higher cumulants and the large deviation function for the particle flow. The latter has the universal form obtained earlier for the asymmetric exclusion process and conjectured to be common for all models of the Kardar–Parisi–Zhang universality class. 相似文献
36.
The use of high-throughput techniques allowed the rapid identification of new catalysts for the enantioselective reduction of imines using polymethylhydrosiloxane (PMHS) as a reducing agent. By a simple modification of the chiral ligand structure that came out of the screening, the enantioselectivity of the reduction was increased from 40% ee to 60% ee. 相似文献
37.
38.
Shahla Yekta 《Journal of fluorine chemistry》2004,125(4):517-525
New partially fluorinated binaphthols were obtained using a copper-catalyzed oxidative coupling. The corresponding enantiomerically pure compounds were prepared by fractional crystallization of the corresponding bis(menthyl)carbamates. Nucleophilic aromatic substitution using oxygen- and carbon-based nucleophiles resulted in functionalized derivatives without concomitant racemization. The titanium(IV) complexes of these ligands are catalytically active in the asymmetric oxidation of sulfides. 相似文献
39.
文章建立一个随机内生增长模型来阐明主要政策参数对经济增长与社会福利的影响.若对生产函数、效用函数、偏好及随机干扰作一些特殊的假设,我们证明了主要政策参数的均衡值能被模型参数唯一决定.进一步我们还得到了期望增长率与储蓄的清晰解.文章的最后,我们证明了政府支出直接影响个体决策者的决策:即提高经济增长率将减少福利;反之,增加福利将减少增长率. 相似文献
40.
Effect of Deborah number and phase difference on peristaltic transport of a third-order fluid in an asymmetric channel 总被引:1,自引:0,他引:1
The effect of a third-order fluid on the peristaltic transport in an asymmetric channel is studied. The wavelength of the peristaltic waves is assumed to be large compared to the varying channel width, whereas the wave amplitudes need not be small compared to the varying channel width. The channel asymmetry is produced by choosing the peristaltic wave train on the walls to have different amplitudes and phase. The flow is investigated in a wave frame of reference moving with velocity of the wave. The effects of Deborah number, phase difference, varying channel width and wave amplitudes on the pumping characteristics, streamline pattern and trapping phenomena are investigated. It is observed that the trapping regions increase as the channel becomes more and more symmetric and the trapped bolus volume decreases for increasing Deborah number, phase difference and varying channel width whereas it increases for increasing flow rate and wave amplitudes. Furthermore, the obtained results could also have applications to a range of peristaltic flows for a variety of non-Newtonian fluids such as aqueous solutions of high-molecular weight polyethylene oxide and polyacrylamide. 相似文献