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61.
Deposition of TiSiN coatings by arc ion plating process 总被引:2,自引:0,他引:2
Titanium silicon nitride (TiSiN) thin films were deposited on tungsten cemented carbide tools by cathode arc ion plating (AIP) process using alloy TiSi targets. The effects of silicon addition and negative substrate bias on the development of the textures of films were studied systematically by varying the bias voltage from −20 to −200 V. The structural features of the films were investigated in detail using X-ray diffraction. The effect of the texture on such mechanical properties as hardness and adhesion of the films was also studied. A maximum hardness of 42 GPa was obtained at a DC substrate bias of −150 V. The characteristics of TiSiN thin films exhibited excellent adhesion of over 150 N. The cutting performance of end-mills and drillers was evaluated by milling and drilling of highly hardened material under high-speed cutting conditions. The results reveal that cutting tools with TiSiN coatings markedly outperformed those with TiN coatings, and the uncoated cutting tools. TiSiN coating increased the cutting lifetime to seven times that of the uncoated one. 相似文献
62.
I. Ksia̧żek 《等离子体物理论文集》2008,48(4):347-356
Plasmas produced in a wall stabilized arc in mixtures of argon and nitrogen, containing different amounts of these elements have been studied. The plasma composition turns out to be very important to the process of demixing in radial direction. In plasmas containing mainly argon, the argon mass fraction reveals a local minimum on the arc axis while in plasmas containing large amount of nitrogen the argon mass fraction have a maximum on the arc axis. The increase of nitrogen amount in Ar–N plasma influences the radial temperature profile causing a decrease of the temperature in plasma layers close to the stabilizing wall and an increase on the axis of plasma column. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
63.
用密度泛函理论的杂化密度泛函B3LYP方法在6-31G*基组水平上对[Mg(NH2)2]n(n=1—5)团簇各种可能的构型进行几何结构优化,预测了各团簇的最稳定结构.对最稳定结构的振动特性、成键特性、电荷特性等进行了理论研究.结果表明:团簇易形成链状结构,Mg—N键长为0.190—0.234 nm,N—H键长为0.101—0.103 nm,H—N—H键角为100.2°—107.5°;团簇中M
关键词:
2)2]n(n=1—5)团簇')" href="#">[Mg(NH2)2]n(n=1—5)团簇
密度泛函理论
结构与性质
储氢材料 相似文献
64.
《Discrete Mathematics》2022,345(10):112999
Ryser proved that any two tournaments with the same score sequence are -equivalent while Beineke and Moon proved the -equivalence for any two bipartite tournaments with the same score lists. In this paper, we extend these results to orientations of G vertex-multiplications. We focus on two main areas, namely orientations with the same score list and with score-list parity. Our main tools are extensions of the refinement technique, directed difference graph and a reduction lemma. 相似文献
65.
《Comptes Rendus Chimie》2016,19(4):433-440
In this study, an experimental plasma-chemical reactor equipped with an arc discharge water steam plasma torch was used for biomass conversion to hydrogen-rich synthesis fuels. Glycerol and crushed wood were used as biomass sources. The effects of different conversion parameters including the water steam flow rate, treated material flow rate, and plasma torch power were studied. The experimentally obtained results were compared with the model based on the thermodynamic equilibrium. Additionally, the quantification of the plasma conversion system in terms of energy efficiency and specific energy requirement was performed. It has been found that the synthesis gas can be effectively produced from the biomass using water steam plasma. 相似文献
66.
A well-known method of estimating the length of a parametric curve in is to sample some points from it and compute the length of the polygon passing through them. In this paper we show that for
uniform sampling of regular smooth curves, Richardson extrapolation can be applied repeatedly giving a sequence of derivative-free
length estimates of arbitrarily high orders of accuracy. A similar result is derived for the approximation of the area of
parametric surfaces.
相似文献
67.
70%高氯酸可作为柏木油中倍半萜烃进行乙酰化反应的第二催化剂组分,用以代替部分PPA。反应在常温下进行,乙酰化产物的产率和质量与原方法相当。该方法不仅节省PPA而且也减少乙酸酐的消耗,降低原料成本20%左右。 相似文献
68.
本文介绍基于IBM—PC/XT的图象工作站仿真软件。把IBM—PC/XT变成图象工作站的仿真软件,为在IBM—PC/XT(及其兼容机)上,开发图象功能软件的用户提供了一个有效的方法。 相似文献
69.
本文研究了在稀硫酸介质中并有亚铁氰化钾存在时,锌与亚甲蓝所形成的配合物的双波长分光光度法。经摩尔比法测定,此配合物组成比为1∶2(锌∶亚甲蓝),摩尔吸光系数为1.01L·mol-1·cm-1。桑德尔灵敏度为6.45×10-4μg/cm2。在25ml容积中,0—10μgZn遵守比尔定律,配合物可稳定2 相似文献
70.
袁玉仁 《南昌大学学报(理科版)》1989,13(3):1
本文探讨了在常规CMOS集成电路基础上设计三值逻辑电路的方法。从三值倒相器入手,结合常规CMOS门电路,给出了CMOS三值译码器的设计方案及应用电路。 相似文献