全文获取类型
收费全文 | 744篇 |
免费 | 45篇 |
国内免费 | 46篇 |
专业分类
化学 | 51篇 |
力学 | 10篇 |
综合类 | 4篇 |
数学 | 694篇 |
物理学 | 76篇 |
出版年
2023年 | 9篇 |
2022年 | 18篇 |
2021年 | 11篇 |
2020年 | 16篇 |
2019年 | 20篇 |
2018年 | 17篇 |
2017年 | 15篇 |
2016年 | 11篇 |
2015年 | 11篇 |
2014年 | 29篇 |
2013年 | 149篇 |
2012年 | 28篇 |
2011年 | 37篇 |
2010年 | 31篇 |
2009年 | 63篇 |
2008年 | 69篇 |
2007年 | 49篇 |
2006年 | 43篇 |
2005年 | 32篇 |
2004年 | 28篇 |
2003年 | 20篇 |
2002年 | 21篇 |
2001年 | 14篇 |
2000年 | 14篇 |
1999年 | 14篇 |
1998年 | 19篇 |
1997年 | 10篇 |
1996年 | 13篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有835条查询结果,搜索用时 15 毫秒
11.
12.
Synthesis of thermally stable aromatic poly(spiroorthocarbonate)s having a Cardo or bent structure
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Masaki Moritsugu Ryota Seto Kozo Matsumoto Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2016,54(10):1409-1416
Novel poly(spiroorthocarbonate)s [poly(SOC)]s having a Cardo or bent structure were synthesized by polycondensation of several bis‐catechols having fluorene (BCFL), spirobisindane (BCSPI), or spirobischromane (BCSPC) in the structure with 2,2,6,6‐tetrachlorobenzo[1,2‐d:4,5‐d’]bis[1,3]dioxole (4ClBD). Synthesis of poly(SOC)s was confirmed by NMR and IR spectrometry. The poly(SOC)s obtained from BCFL or BCSPC were soluble in common organic solvents. The glass transition temperature of the poly(SOC)s was not detected by differential scanning calorimetry (DSC) in the range of 50–300 °C. The 10 wt % decomposition temperature of the poly(SOC)s was found to be above 400 °C. These results indicated the high thermal stability of the poly(SOC)s. Soluble poly(SOC)s could be possessed to form a film on a glass plate by the spin coat method. The obtained polymer films were 0.2 μm in thickness with 95% light transmission in the optical wavelength range. These results suggested that the Cardo or bent structure may block the packing of the main‐chain of the structure, which improves the solubility of the polymers, increases transparency, and enhances the thermal stability of SOCs. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1409‐1416 相似文献
13.
We show that the only rational homology spheres which can admit almost complex structures occur in dimensions two and six. Moreover, we provide infinitely many examples of six-dimensional rational homology spheres which admit almost complex structures, and infinitely many which do not. We then show that if a closed almost complex manifold has sum of Betti numbers three, then its dimension must be a power of two. 相似文献
14.
Vladimíra Novotná Věra Hamplová Miroslav Kašpar Milada Glogarová Karel Knížek Siegmar Diele 《Liquid crystals》2013,40(8):967-975
New mesogens composed of achiral bent molecules with thermally stable ester linkages, and laterally substituted by a methoxy group symmetrically near the central benzene ring, were synthesized. Texture, calorimetric, electro‐optical, X‐ray and dielectric measurements were performed. In most of studied compounds the antiferroelectric B2 phase was found on cooling from the isotropic phase, followed by the B7 phase at lower temperatures. Undulation of layers in the B7 phase was confirmed by precise synchrotron studies. 相似文献
15.
Md Lutfor Rahman Jahimin Asik Sandeep Kumar Carsten Tschierske 《Liquid crystals》2013,40(11):1263-1270
Three banana‐shaped monomers, i.e. 2,7‐naphthalene bis[4‐(4‐allyloxyphenylazo)‐benzoate], 2,7‐naphthalene bis[4‐(4‐allyloxy‐3‐fluorophenylazo)benzoate] and 2,7‐naphthalene bis{4‐[4‐(10‐undecenyloxy)phenylazo]benzoate}, containing azobenzene as side arms, 2,7‐dihydroxynaphthalene as central units and terminal double bonds as polymerisable functional groups, were synthesised and their mesophase behaviour investigated. Polarizing optical microscopy and DSC measurements reveal that all compounds exhibit nematic mesophases. The absorption spectrum of the trans‐azobenzene groups displays a high‐intensity π–π* transition at about 365 nm and a low‐intensity n–π* transition at around 450 nm for all compounds. Hence, photochromism can be achieved by the introduction of the azo linkage to banana‐shaped liquid crystals molecules. 相似文献
16.
17.
Lotka-Volterra型N-种群竞争系统的持久性和稳定性 总被引:6,自引:0,他引:6
本文研究一类具有无穷时滞的概周期Lotka-Volterra型N-种群竞争系统的持久性和全局渐近稳定性.一些新的充分条件被得到. 相似文献
18.
This paper defines and examines the basic properties of non-commutative analogues of almost complex structures, integrable almost complex structures, holomorphic curvature, cohomology, and holomorphic sheaves. The starting point is a differential structure on a non-commutative algebra defined in terms of a differential graded algebra. This is compared to current ideas on non-commutative algebraic geometry. 相似文献
19.
Let M
n
denote the partial maximum of a strictly stationary sequence (X
n
). Suppose that some of the random variables of (X
n
) can be observed and let [(M)\tilde]n\tilde M_n
stand for the maximum of observed random variables from the set {X
1, ..., X
n
}. In this paper, the almost sure limit theorems related to random vector ([(M)\tilde]n\tilde M_n
, M
n
) are considered in terms of i.i.d. case. The related results are also extended to weakly dependent stationary Gaussian sequence as its covariance function satisfies
some regular conditions. 相似文献
20.
André Adler 《Journal of Theoretical Probability》2002,15(4):939-949
Consider independent and identically distributed random variables {X,X
nj
, 1jn,n1} with density f(x)=px
–p–1
I(x1), where p>0. We show that there exist unusual generalized Laws of the Iterated Logarithm involving the larger order statistics from our array. 相似文献