稳态荧光探针法测定临界胶束聚集数

以芘为荧光探针、二苯甲酮为猝灭剂,用稳态荧光探针法测定了SDS和AS的胶束聚集数(Nm).以芘的饱和水溶液为溶剂配制表面活性剂溶液,二苯甲酮的适宜浓度取小于1.00 mmol•L－1时,可以获得满意的实验结果.当表面活性剂溶液浓度为5～9倍cmc时,Nm随表面活性剂浓度增大而线性增大,而随温度的变化略有波动.cSAA=cmc时,Nm值为一本征值,定义为临界胶束聚集数[Nm].[Nm]值可从Nm－cSAA实验曲线外延得到.25℃时SDS的临界胶束聚集数[Nm]为57;40℃时SDS的[Nm]为49,AS的[Nm]为55.     

壬基酚聚氧乙烯醚型Gemini季铵盐表面活性剂的合成 及其表面性质的研究

合成了系列壬基酚聚氧乙烯醚型Gemini季铵盐表面活性剂(GNPQA), 用核磁、红外和元素分析对它们的结构进行了表征, 考察了反应条件对转化率的影响, 并用表面张力法和稳态荧光探针法对GNPQA的表面性能及胶束聚集数(N)进行了研究. 结果表明, 较优的反应条件: 反应时间为12 h, 反应温度为70 ℃, 反应原料摩尔比为n(双聚壬基酚聚氧乙烯醚)∶n(三乙胺)∶n(环氧氯丙烷)＝1∶1∶1; GNPQA的临界胶束浓度(CMC)值较相应的单体壬基酚聚氧乙烯醚型季铵盐表面活性剂(NPQA)降低了1～2个数量级, 显示了较高的表面活性; 当GNPQA溶液浓度为5～9倍CMC时, N值随浓度增大而线性增大; 随着氧乙烯(EO)单元数的增长, GNPQA的CMC和N值均逐渐减小; 结合GNPQA的表面性能参数和N值的变化规律, 探讨了这类表面活性剂表面及胶束聚集体的结构形态.     

Mutual solubilities of hydrocarbons and water with the CPA EoS

The knowledge of hydrocarbon/water phase equilibria is important in the design and operation of equipment for petroleum transport and refining and petrochemical plants. The presence of water in a hydrocarbon mixture can affect the product quality and damage the operation equipment due to corrosion and formation of gas hydrates. Tracing the concentration of hydrocarbons in aqueous media is also important for technical purposes like preventing oil spills and for ecological concerns such as predicting the fate of these organic pollutants in the environment.     

Modal part analysis of slosh of the liquid in a cylindrical container in the case of small bond number

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｍｏｔｉｏｎｏｆｔｈｅｉｎｖｉｓｃｉｄ,ｉｒｒｏｔａｔｉｏｎａｌａｎｄｉｎｃｏｍｐｒｅｓｓｉｂｌｅｆｌｕｉｄｉｎａｃｙｌｉｎｄｒｉｃａｌｃｏｎｔａｉｎｅｒｗｉｔｈｒａｄｉｕｓａｉｓｇｏｖｅｒｎｅｄｂｙＦｉｇ．１Ｓｌｏｓｈｏｆａｌｉｑｕｉｄｉｎａｃｙｌｉｎｄｒｉｃａｌｃｏｎｔａｉｎｅｒ２＝０　　（ｉｎＶ）,（１）ｒ＝０　　（ｏｎｒ＝ａ）,（２）ｚ＝０　　（ｏｎｚ＝－ｈ）,（３）ηｔ＋·η＝ｚ　　（ｏｎｚ＝η）,（４）ｔ＋１２｜…     

黄金数的整数次幂与Fibonacci-Lucas数的若干关系式

给出Fibonacci等距子列定义,由此入手得到黄金数的整数次幂与Fibonacci数以及Lucas数的若干关系式.     

模糊多属性群决策一致性分析研究

群决策过程中各成员可能以不同的方式给出决策信息,讨论了四种不同决策信息的统一方法,设置了模糊环境下进行一致性判断的准则,介绍了梯形模糊数在群决策过程中的运算方法,举例说明了这种方法的应用步骤.     

Vertex-distinguishing E-total Coloring of Complete Bipartite Graph K_(7,n) when 7≤n≤95

Let G be a simple graph. A total coloring f of G is called an E-total coloring if no two adjacent vertices of G receive the same color, and no edge of G receives the same color as one of its endpoints. For an E-total coloring f of a graph G and any vertex x of G, let C(x) denote the set of colors of vertex x and of the edges incident with x, we call C(x) the color set of x. If C(u)≠ C(v) for any two different vertices u and v of V(G), then we say that f is a vertex-distinguishing E-total coloring of G or a VDET coloring of G for short. The minimum number of colors required for a VDET coloring of G is denoted by χ_(vt)~e(G) and is called the VDET chromatic number of G. The VDET coloring of complete bipartite graph K_(7,n)(7 ≤ n ≤ 95) is discussed in this paper and the VDET chromatic number of K_(7,n)(7 ≤ n ≤ 95) has been obtained.     

High Photon-Number Squeezing in Strong Field Limit

We show that high photon-number squeezing in bright light can be generated in both lasers and optical bistabilities by the injections of a squeezed vacuum and a classical field, and the high squeezing is maintained for very strong field.     

Topological aspect of Chern--Simons p-branes

By generalizing the topological current of Abelian Chern--Simons (CS) vortices, we present a topological tensor current of CS p-branes based on the \phi -mapping topological current theory. It is revealed that CS p-branes are located at the isolated zeros of the vector field \phi(x), and the topological structure of CS p-branes is characterized by the winding number of the \phi-mappings. Furthermore, the Nambu--Goto action and the equation of motion for multi CS p-branes are obtained.     

N,N',N"-三(2,6-二异丙基苯胺基)-2,5-二亚胺吡咯的合成及其结构

在多聚磷酸三甲基硅酯(PPSE)的存在下,2,6-二异丙基苯胺和丁二酸缩合可以高产率地得到N,N',N'-三(2,6-二异丙基苯胺基)-2,5-二亚胺吡咯(1).化合物1经过了元素分析、红外光谱、氢谱、高分辨质谱和单晶结构衍射的表征.