超声波辅助提取-HG-ICP-AES法测定中草药雷公藤中可溶态Sb(Ⅲ)和Sb(Ⅴ)

本文建立了用超声波辅助提取,氢化物发生-电感耦合等离子体原子发射光谱法测定中草药雷公藤中可溶态Sb(Ⅲ)和Sb(Ⅴ)的分析方法。研究了超声波辅助提取的影响因素、锑形态分离的最佳pH值、仪器工作条件对锑氢化物发生的影响及五价锑的还原条件,探讨了共存离子对锑测定的干扰及消除方法。Sb(Ⅲ)和Sb(Ⅴ)的检出限分别为0.3和2.4 μg·L-1, 相对标准偏差分别为3.9%和4.5%,样品加标回收率为93%～105%。     

Upshot of Chemical Species and Nonlinear Thermal Radiation on Oldroyd-B Nanofluid Flow Past a Bi-directional Stretched Surface with Heat Generation/Absorption ina Porous Media

A three-dimensional mathematical model is developed to examine the flow of nonlinear thermal radiation Oldroyd-B nanofluid past a bidirectional linearly stretched surface in a porous medium. The flow is induced by temperature dependent thermal conductivity, chemical reaction and convective heat and mass conditions. Novel characteristics of Brownian motion and thermophoresis are accompanied by magnetohydrodynamic and heat generation/absorption. Self-similar transformations are employed to convert the system of nonlinear partial differential equations to a system of ordinary differential equations with high nonlinearity and are solved by strong analytic technique named as Homotopy Analysis method (HAM). Effects of varied arising parameters on involved distributions are reflected through graphical illustrations. From this study, it is perceived that strong magnetic field hinders the fluid's motion and leads to rise in temperature that eventually lowers heat transfer rate from the surface. Further, decrease in heat transfer rate is also observed for enhanced values of thermal radiation parameter. To validate our results, a comparison with already published paper in limiting case is also given and results are found in excellent oncurrence; hence reliable results are being presented.     

偶氮聚合物薄膜的全光极化研究

报告了分散红共聚物膜HMMM-DR1,HMMM-DR19和偶氮侧链聚合物膜PCN6和PCN2的合成和制备, 并以HMMM-DR1和PCN6为代表比较研究了这两种具有不同吸收性质材料的全光极化特性,研究了他们的实时极化和弛豫过程,对他们的全光极化性质作了最基本的表征.研究了倍频光吸收对薄膜光极化效率的影响,讨论了偶氮聚合物材料光诱导二阶非线性极化率的效率和倍频光透射率之间的折衷关系,这对实用化的全光器件的研制是至关重要的.实验确证了在PCN6薄膜中实现了准相位匹配.对厚膜中光诱导二阶非线性极化率的弛豫抑制效应作出解释.     

槽式DSG太阳能集热系统模拟分析

以采用真空集热管的一次通过式槽式DSG太阳能集热器为研究对象。基于集热器管内水工质的流型与传热特性,建立了集热器稳态传热模型,并验证了模型及计算方法的合理性。分析了当出口为400℃过热蒸汽时,集热器传热受太阳辐射强度、管径、水工质入口参数等的影响规律。结果表明集热器的传热效果取决于周围环境的边界条件以及集热器结构参数和水工质运行参数的选取,本文结论为DSG集热器的设计及运行提供了理论参考依据。     

A novel MI-insensitive and filterless frequency octupling scheme based on two parallel dual-parallel Mach–Zehnder modulators

A novel MI-insensitive and filterless frequency octupling scheme based on two parallel dual-parallel Mach–Zehnder modulators (DP-MZMs) is proposed. The proposed scheme is not sensitive to modulation index and relatively strong MMW signal with good radio frequency spurious suppression ratio (RFSSR) can be obtained without strict requirement on modulation index. Filterless feature makes the scheme quite suitable for wavelength division multiplexing (WDM) applications. For verification, a 60 GHz millimeter wave with 44 dB RFSSR is generated from a 7.5 GHz radio frequency wave by simulation. Performance of the proposed scheme has been characterized under different conditions including DC-bias drifts of MZMs, different amplitudes of RF inputs and different extinction ratios of MZMs.     

Entropy resistance analyses of a two-stream parallel flow heat exchanger with viscous heating

Heat exchangers are widely used in industry, and analyses and optimizations of the performance of heat exchangers are important topics. In this paper, we define the concept of entropy resistance based on the entropy generation analyses of a one-dimensional heat transfer process. With this concept, a two-stream parallel flow heat exchanger with viscous heating is analyzed and discussed. It is found that the minimization of entropy resistance always leads to the maximum heat transfer rate for the discussed two-stream parallel flow heat exchanger, while the minimizations of entropy generation rate, entropy generation numbers, and revised entropy generation number do not always.     

Energy transfers in dynamos with small magnetic Prandtl numbers

We perform numerical simulation of dynamo with magnetic Prandtl number Pm = 0.2 on 1024³ grid, and compute the energy fluxes and the shell-to-shell energy transfers. These computations indicate that the magnetic energy growth takes place mainly due to the energy transfers from large-scale velocity field to large-scale magnetic field and that the magnetic energy flux is forward. The steady-state magnetic energy is much smaller than the kinetic energy, rather than equipartition; this is because the magnetic Reynolds number is near the dynamo transition regime. We also contrast our results with those for dynamo with Pm = 20 and decaying dynamo.     

Generation of hard X-ray radiation using the triboelectric effect by peeling adhesive tape

The triboelectric effect describes electrical charging when bringing different materials into contact. We report on the generation of hard X-ray radiation by peeling various adhesive tapes under medium vacuum conditions. Beside vacuum housing and pumps as instrumentation only an electric motor, two rolls and a metal foil as target material are necessary. The spectral distribution of generated X-rays was analyzed using an energy-dispersive detector. Depending on peeling speed, pressure and choice of material combination, electrons with energies sufficient to excite emission in the hard X-ray region are produced. The results are discussed in terms of triboelectric separation of charge carriers.     

Raman Scattering Tensors in Biological Molecules and Their Assemblies

INTRODUCTION

The tensor associated with a Raman band plays an important role in determining the band intensity and its structural significance. Each Raman tensor interrelates two electric vectors, that of the exciting radiation (i.e. laser photon) and that of the Raman scattered radiation (i.e. the inelastically scattered photon which results from the exchange of a vibrational quantum between the exciting photon and the molecule). The Raman tensor is obtained formally as the first derivative of the molecular polarizability tensor, the derivative being taken with respect to the vibrational normal coordinate. In other words, the Raman tensor associated with a vibrational Raman band is an indicator of how the polarizability of the molecule oscillates with the molecular normal mode of vibration.     

Theoretical investigation of high-order harmonic generation from asymmetric molecular ions in the chirped laser field

High-order harmonic generation from the asymmetric helium hydrogen molecular ion exposed to a few-cycle chirped laser field is theoretically investigated by numerically solving the reduced one-dimension non-Born–Oppenheimer time dependent Schrödinger equation. The numerical results show that the plateau of the high-order harmonic spectrum is dramatically broadened and smoother with the introduction of the chirp. Further study presents that only the short quantum path contributes to harmonic emission and the long quantum path disappears in the chirped laser. In addition, an 80-as isolated attosecond pulse is obtained by superposing the harmonics from the 100th to the 130th order in the chirped field. The time-frequency distributions and the electronic probability distributions are presented to explain the underlying physical mechanism.