热等离子体裂解天然气制备C2烃

采用氮气热等离子体来裂解天然气制备乙炔乙烯,着重研究了天然气转化率和乙炔、乙烯收率随氮气流量和天然气流量的变化.结果表明,天然气流量与氮气流量之比为11时,可得到较好的结果.当等离子体功率为15kW、天然气流量为3Nm3*h-1、氮气流量为3Nm3*h-1时得到最好的结果.这时天然气转化率为57%,乙炔、乙烯的收率分别为34%和9%;乙炔在反应气中的体积浓度为7.5%,与部分氧化法相似;扣除不参加反应的氮气,乙炔在气相产品中的体积浓度为13.2%,与热力学平衡计算结果基本符合.     

A model for the interaction of near-infrared laser pulses with metal powders in selective laser sintering

A thermal model of the interaction of pulsed near-infrared laser radiation from a Nd:YAG laser was made, taking the measured powder properties such as reflectance, optical penetration depth and thermal conductivity into account. It allows an estimation of the evolution of two different temperatures: the average temperature of the powder (taken over the grains in a volume given by the laser beam diameter and the optical penetration depth) and the temperature distinction within a single grain. It showed that in pulsed mode consolidation can be achieved at much lower average power as the surface of the powder particles are molten but their cores remain at nearly room temperature. This leads to a much lower average temperature and therefore a dramatic decrease in residual thermal stresses in the finished piece. The results of the model were experimentally tested and confirmed. Received: 26 July 2001 / Accepted: 23 November 2001 / Published online: 23 January 2002     

Bidendriform bialgebras, trees, and free quasi-symmetric functions

We introduce bidendriform bialgebras, which are bialgebras such that both product and coproduct can be split into two parts satisfying good compatibilities. For example, the Malvenuto-Reutenauer Hopf algebra and the non-commutative Connes-Kreimer Hopf algebras of planar decorated rooted trees are bidendriform bialgebras. We prove that all connected bidendriform bialgebras are generated by their primitive elements as a dendriform algebra (bidendriform Milnor-Moore theorem) and then is isomorphic to a Connes-Kreimer Hopf algebra. As a corollary, the Hopf algebra of Malvenuto-Reutenauer is isomorphic to the Connes-Kreimer Hopf algebra of planar rooted trees decorated by a certain set. We deduce that the Lie algebra of its primitive elements is free in characteristic zero (G. Duchamp, F. Hivert and J.-Y. Thibon conjecture).     

Symplectic Yang–Mills theory,Ricci tensor,and connections

A Yang–Mills theory in a purely symplectic framework is developed. The corresponding Euler–Lagrange equations are derived and first integrals are given. We relate the results to the work of Bourgeois and Cahen on preferred symplectic connections.     

On the maximum multiplicity of an eigenvalue in a matrix whose graph contains exactly one cycle

We consider the general problem of determining the maximum possible multiplicity of an eigenvalue in a Hermitian matrix whose graph contains exactly one cycle. For some cases we express that maximum multiplicity in terms of certain parameters associated with the graph.     

Ordered OLPS and CF Nth numerators

Definitions, theorems and examples are established for a general model of Laurent polynomial spaces and ordered orthogonal Laurent polynomial sequences, ordered with respect to ordered bases and orthogonal with respect to inner products ·=L°⊙ decomposed into transition functional ⊙ and strong moment functional, or, more generally, sample functional L couplings. Under this formulation that is shown to subsume those in the existing literature, new fundamental results are produced, including necessary and sufficient conditions for ordered OLPS to be sequences of nth numerators of continued fractions, in contrast to the classical result concerning nth denominators which is shown to hold only in special cases.     

Periodic and subharmonic solutions of a class of subquadratic second-order Hamiltonian systems

Some solvability conditions of periodic and subharmonic solutions are obtained for a class of subquadratic nonautonomous second-order Hamiltonian systems by the minimax methods in critical point theory.     

Estimation of intrinsic processes affected by additive fractal noise

Fractal Gaussian models have been widely used to represent the singular behavior of phenomena arising in different applied fields; for example, fractional Brownian motion and fractional Gaussian noise are considered as monofractal models in subsurface hydrology and geophysical studies Mandelbrot [The Fractal Geometry of Nature, Freeman Press, San Francisco, 1982 [13]]. In this paper, we address the problem of least-squares linear estimation of an intrinsic fractal input random field from the observation of an output random field affected by fractal noise (see Angulo et al. [Estimation and filtering of fractional generalised random fields, J. Austral. Math. Soc. A 69 (2000) 1-26 [2]], Ruiz-Medina et al. [Fractional generalized random fields on bounded domains, Stochastic Anal. Appl. 21 (2003a) 465-492], Ruiz-Medina et al. [Fractional-order regularization and wavelet approximation to the inverse estimation problem for random fields, J. Multivariate Anal. 85 (2003b) 192-216]. Conditions on the fractality order of the additive noise are studied to obtain a bounded inversion of the associated Wiener-Hopf equation. A stable solution is then obtained in terms of orthogonal bases of the reproducing kernel Hilbert spaces associated with the random fields involved. Such bases are constructed from orthonormal wavelet bases (see Angulo and Ruiz-Medina [Multiresolution approximation to the stochastic inverse problem, Adv. in Appl. Probab. 31 (1999) 1039-1057], Angulo et al. [Wavelet-based orthogonal expansions of fractional generalized random fields on bounded domains, Theoret. Probab. Math. Stat. (2004), in press]). A simulation study is carried out to illustrate the influence of the fractality orders of the output random field and the fractal additive noise on the stability of the solution derived.     

Hopf monads

We introduce and study Hopf monads on autonomous categories (i.e., monoidal categories with duals). Hopf monads generalize Hopf algebras to a non-braided (and non-linear) setting. In particular, any monoidal adjunction between autonomous categories gives rise to a Hopf monad. We extend many fundamental results of the theory of Hopf algebras (such as the decomposition of Hopf modules, the existence of integrals, Maschke's criterium of semisimplicity, etc.) to Hopf monads. We also introduce and study quasitriangular and ribbon Hopf monads (again defined in a non-braided setting).     

A Fubini theorem

Let I₀ be the σ-ideal of subsets of a Polish group generated by Borel sets which have perfectly many pairwise disjoint translates. We prove that a Fubini-type theorem holds between I₀ and the σ-ideals of Haar measure zero sets and of meager sets. We use this result to give a simple proof of a generalization of a theorem of Balcerzak-Ros?anowski-Shelah stating that I₀ on N² strongly violates the countable chain condition.