全文获取类型
收费全文 | 8658篇 |
免费 | 235篇 |
国内免费 | 230篇 |
专业分类
化学 | 1263篇 |
晶体学 | 108篇 |
力学 | 57篇 |
综合类 | 23篇 |
数学 | 6173篇 |
物理学 | 1499篇 |
出版年
2023年 | 34篇 |
2022年 | 85篇 |
2021年 | 110篇 |
2020年 | 77篇 |
2019年 | 208篇 |
2018年 | 184篇 |
2017年 | 126篇 |
2016年 | 75篇 |
2015年 | 86篇 |
2014年 | 231篇 |
2013年 | 467篇 |
2012年 | 251篇 |
2011年 | 469篇 |
2010年 | 402篇 |
2009年 | 558篇 |
2008年 | 660篇 |
2007年 | 643篇 |
2006年 | 555篇 |
2005年 | 445篇 |
2004年 | 359篇 |
2003年 | 274篇 |
2002年 | 284篇 |
2001年 | 226篇 |
2000年 | 244篇 |
1999年 | 257篇 |
1998年 | 203篇 |
1997年 | 166篇 |
1996年 | 197篇 |
1995年 | 158篇 |
1994年 | 162篇 |
1993年 | 126篇 |
1992年 | 99篇 |
1991年 | 78篇 |
1990年 | 55篇 |
1989年 | 68篇 |
1988年 | 48篇 |
1987年 | 58篇 |
1986年 | 42篇 |
1985年 | 52篇 |
1984年 | 41篇 |
1983年 | 36篇 |
1982年 | 43篇 |
1981年 | 28篇 |
1980年 | 41篇 |
1979年 | 21篇 |
1978年 | 22篇 |
1977年 | 16篇 |
1976年 | 20篇 |
1974年 | 9篇 |
1973年 | 10篇 |
排序方式: 共有9123条查询结果,搜索用时 15 毫秒
191.
192.
Koji Hashimoto 《Applied Surface Science》2011,257(19):8141-8150
Amorphous alloys have many attractive characteristics including extremely high corrosion resistance if the sufficient amounts of corrosion-resistant elements are added. The superiority of amorphous alloys is based on the homogeneous single phase nature without any chemical and physical heterogeneities. Although there are processing limitations to avoid the formation of heterogeneous crystalline structure in addition to no welding technology without crystallization, the application of corrosion-resistant amorphous alloys is expected particularly to the very aggressive environments, where any conventional crystalline metallic materials cannot be used. Some amorphous bulk alloys showed zero corrosion mass loss due to spontaneous passivation even in 12 M HCl. Production of amorphous bulk alloys became possible for selected compositions. The homogeneous single phase nature is also effective to form useful catalysts with unique composition and structure. An example of catalysts is for carbon dioxide methanation useful for supply of renewable energy in the form of methane. 相似文献
193.
In this report, we demonstrate scanning tunneling microscopy and spectroscopy on thin films of lauryl amine (LAM) and octadecane thiol (ODT) protected gold nanoparticles. We show that the zero current in the I-V curves (measure of Coulomb blockade (CB) of the nanoparticles) depends on the properties of the spacer molecule. In both the cases the gap voltage and the tunneling current at which the images are obtained are quite different which is further confirmed from the fitting performed based on the orthodox theory. The values for the capacitance and charging energy obtained from the fitting for ODT capped particles are comparable to the values obtained using spherical capacitor model. In contrast, values of these parameters were found to differ for LAM capped nanoparticles. While imaging, ODT capped nanoparticles were observed to drag along the scan direction leading to ordering of particles. Images of LAM capped gold nanoparticles show local ordering in self-assembly of particles although no evidence of large scale ordering in spatial Fourier transform was seen. These observations suggest that nanoparticles with larger CB would be imaged nonevasively in contrast to small CB systems for which tip induced effects will be dominant. In both the systems the current was found to rise faster than theoretical curves based on the orthodox theory suggesting that mechanism of charge transfer in this case may involve field emission rather than tunneling through a rectangular barrier. An attempt has been made to explain charge transfer based on Fowler-Nordheim (F-N) plots of the I-V curves. 相似文献
194.
A.K.M. Akther Hossain K. Khirul Kabir T. Kawai 《Journal of Physics and Chemistry of Solids》2007,68(10):1933-1939
Structural, AC and DC magnetic properties of polycrystalline Zn1−xCoxFe2O4 (x=0.2, 0.4) samples sintered at various temperatures (1100-1300 °C), and various dwell times (0.2-15 h) have been investigated thoroughly. The bulk density of the Zn0.60Co0.40Fe2O4 samples increases as the sintering temperature (Ts) increases from 1100 to 1250 °C, and above 1250 °C the bulk density decreases slightly. The Zn0.80Co0.20Fe2O4 samples show similar behavior of changes to that of Zn0.60Co0.40Fe2O4 samples except that the bulk density is found to be highest at 1200 °C. The DC magnetization as a function of temperature curves show that the Zn0.60Co0.40Fe2O4 sample is ferrimagnetic at room temperature while the Zn0.80Co0.20Fe2O4 sample is paramagnetic at room temperature. The Tc of Zn0.80Co0.20Fe2O4 sample is found to be 170 K from DC magnetization measurement. Separate measurement (AC magnetization), initial permeability as a function of temperature shows that the Tc of the Zn0.60Co0.40Fe2O4 sample is 353 K. Slight variation of Tc is observed depending on sintering condition. The initial permeability for the Zn0.60Co0.40Fe2O4 composition sintered at 1250 °C is found to be maximum. 相似文献
195.
Sr4Al14O25:RE3+(RE=Eu,Ce,Tb)中稀土离子的发光性质 总被引:4,自引:0,他引:4
采用高温固相反应合成了Sr4Al14O25:RE^3 (RE=Eu,Ce,Tb)样品,研究了其中Eu^3 ,Ce^3 和Tb^3 的光谱性质,以及Ce^3 与Tb^3 共掺时的能量传递现象;发现Eu^3 ,Ce^3 和Tb^3 占有两个格位,与Eu^2 在此基质中的情况相似;在Tb^3 的发射光谱中同时观察到了来自^5D3与^5D4的发射,表明两能级间无辐射跃迁过程不显著;Ce^3 对Tb^3 有敏化作用。 相似文献
196.
利用块三对角矩阵的嵌套局部块分解构造了一个不完全分解预条件子,并考虑了其修正型变种,分析了两者的存在性及若干性质.针对标准七点差分矩阵,给出了预条件后的实际条件数.结果表明,采用局部块分解预条件时条件数与矩阵阶数的2/3次幂成正比,而采用修正型预条件时条件数与矩阵阶数的立方根成正比.最后考虑了预条件的高效实现并在主频为550MHz、内存为256M的微机上作了若干数值实验,并与其它较有效的预条件方法进行了比较. 相似文献
197.
Bright-field transmission electron microscopy (TEM) images, high-resolution TEM (HRTEM) images, and fast-Fourier transformed electron-diffraction patterns showed that n-butyl terminated Si nanoparticles were aggregated. The formation of Si1−xCx nanocomposites was mixed with Si nanoparticles and C atoms embedded in a SiO2 layer due to the diffusion of C atoms from n-butyl termination shells into aggregated Si nanoparticles. Atomic force microscopy (AFM) images showed that the Si1−xCx nanocomposites mixed with Si nanoparticles and C atoms existed in almost all regions of the SiO2 layer. The formation mechanism of Si nanoparticles and the transformation mechanism of n-butyl terminated Si nanoparticles embedded into Si1−xCx nanocomposites mixed with Si nanoparticles and C atoms are described on the basis of the TEM, HRTEM, and AFM results. These results can help to improve the understanding of the formation mechanism of Si nanoparticles. 相似文献
198.
Objective
Fully automatic tissue characterization in intravascular ultrasound systems is still a challenge for the researchers. The present work aims to evaluate the feasibility of using the Higuchi fractal dimension of intravascular ultrasound radio frequency signals as a feature for tissue characterization.Methods
Fractal dimension images are generated based on the radio frequency signals obtained using mechanically rotating 40 MHz intravascular ultrasound catheter (Atlantis SR Plus, Boston Scientific, USA) and compared with the corresponding correlation images.Conclusion
An inverse relation between the fractal dimension images and the correlation images was revealed indicating that the hard or slow moving tissues in the correlation image usually have low fractal dimension and vice-versa. Thus, the present study suggests that fractal dimension images may be used as a feature for intravascular ultrasound tissue characterization and present better resolution then the correlation images. 相似文献199.
In this Letter, synchronization of switched system is investigated based on Lyapunov method. A sufficient condition is derived to ensure the synchronization between two switched systems, and a new communication scheme is also proposed based on this. Furthermore, some secure analysis works, such as return map attack and moving average error attack, are also given to show the security of the proposed scheme. Finally, simulation examples are constructed to verify the theoretical analysis and its application for communication. 相似文献
200.
Hyperfine Interactions - The 57Fe Mössbauer spectra recorded in situ from 5% ruthenium-doped maghemite show parameters typical for maghemite up to 600 K and a hyperfine field distribution... 相似文献