全文获取类型
收费全文 | 24141篇 |
免费 | 811篇 |
国内免费 | 594篇 |
专业分类
化学 | 3818篇 |
晶体学 | 135篇 |
力学 | 650篇 |
综合类 | 75篇 |
数学 | 15417篇 |
物理学 | 5451篇 |
出版年
2024年 | 33篇 |
2023年 | 182篇 |
2022年 | 275篇 |
2021年 | 280篇 |
2020年 | 448篇 |
2019年 | 634篇 |
2018年 | 611篇 |
2017年 | 478篇 |
2016年 | 440篇 |
2015年 | 450篇 |
2014年 | 854篇 |
2013年 | 1342篇 |
2012年 | 729篇 |
2011年 | 1813篇 |
2010年 | 1325篇 |
2009年 | 1649篇 |
2008年 | 1838篇 |
2007年 | 1746篇 |
2006年 | 1322篇 |
2005年 | 1022篇 |
2004年 | 894篇 |
2003年 | 759篇 |
2002年 | 709篇 |
2001年 | 456篇 |
2000年 | 465篇 |
1999年 | 512篇 |
1998年 | 426篇 |
1997年 | 350篇 |
1996年 | 414篇 |
1995年 | 372篇 |
1994年 | 378篇 |
1993年 | 341篇 |
1992年 | 257篇 |
1991年 | 188篇 |
1990年 | 171篇 |
1989年 | 163篇 |
1988年 | 113篇 |
1987年 | 113篇 |
1986年 | 113篇 |
1985年 | 145篇 |
1984年 | 114篇 |
1983年 | 77篇 |
1982年 | 106篇 |
1981年 | 88篇 |
1980年 | 84篇 |
1979年 | 53篇 |
1978年 | 69篇 |
1977年 | 51篇 |
1976年 | 54篇 |
1974年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
《Magnetic resonance in chemistry : MRC》2003,41(9):731-734
An NMR study of one new and several known abietane diterpenes isolated from the roots of Aegiphila lhotzkyana is described. In addition to 1D NMR, several 2D shift‐correlated NMR pulse sequences (1H–1H‐COSY, NOESY, HMQC and HMBC) were used to establish all the structures, and unambiguously perform the 1H and 13C chemical shift assignments of the new natural diterpene and three derivatives, the NMR data for which have not been reported previously. Revision of current data assignment for teuvincenone H is also suggested. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
72.
A solution to the phase problem in optics is considered within the context of registration and analysis of two-dimensional stationary optical fields transformed by the object under study or fields forming an image. To obtain information on amplitude and phase distributions of the light field analyzed, a method of registration of two intensity distributions is used. The first distribution corresponds directly to the amplitude distribution. The other is formed for the sum of the initial field and the field shifted along a certain direction. The intensity distributions obtained allow one to calculate the two-dimensional structure of the field under study. It is noteworthy that the method requires no iteration procedures in solving the problem. This leads to speeding up of the processing and analysis of the information. Two variants of optical schemes for the analysis of light fields are considered. The first one corresponds to registration of the image of the analyzed plane and the second to registration of the spectrum of the spatial frequencies. 相似文献
73.
Bi12TiO20纳米粉体的制备及其光吸收特性研究 总被引:3,自引:0,他引:3
以钛酸四丁酯和硝酸铋为原料 ,利用化学溶液分解法制备了Bi12 TiO2 0 纳米多晶粉体 .采用XRD和TEM对其结构和形貌进行了表征 .结合热重 差热 (TG DTA)分析 ,探讨了Bi12 TiO2 0 晶相的形成机理 .通过UV Vis漫反射谱的测定 ,研究了Bi12 TiO2 0 纳米晶粉体的光吸收特性 .结果显示 ,从组成为化学计量比的前驱液中可以很容易制得纯Bi12 TiO2 0 纳米晶粉体 ,该Bi12 TiO2 0 纳米晶粉体呈现了在很宽的波长范围内 (5 6 0~ 385nm )对光的吸收的特性 . 相似文献
74.
75.
Matthew D. Horton 《Linear algebra and its applications》2007,425(1):130-142
After defining and exploring some of the properties of Ihara zeta functions of digraphs, we improve upon Kotani and Sunada’s bounds on the poles of Ihara zeta functions of undirected graphs by considering digraphs whose adjacency matrices are directed edge matrices. 相似文献
76.
本文采用高分辨率格式和多块多网格方法求解雷诺平均Navier-Stokes方程,数值模拟多排叶片内的三维粘性流动;使用数值激盘模拟叶片排的存在,研究叶片排与非轴对称排气部件之间的相互作用以及复杂的内部流动。文中描述了数值方法,给出了NASA透平导叶和单级透平内部流场的数值结果及其与相应实验结果的对比,也给出了多级透平内部流场的数值结果,以及透平与排气部件之间的耦合流场的结果。 相似文献
77.
Yong Joon Park Min Gyu KimYoung-Sik Hong Xianglan WuKwang Sun Ryu Soon Ho Chang 《Solid State Communications》2003,127(7):509-514
Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 (X=0.17, 0.25, 0.33, 0.5) compounds are prepared by a simple combustion method. The Rietvelt analysis shows that these compounds could be classified as having the α-NaFeO2 structure. The initial charge-discharge and irreversible capacity increases with the decrease of x in Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2. Indeed, Li[Ni0.50Mn0.50]O2 compound shows relatively low initial discharge capacity of 200 mAh/g and large capacity loss during cycling, with Li[Ni0.17Li0.22Mn0.61]O2 and Li[Ni0.25Li0.17Mn0.58]O2 compounds exhibit high initial discharge capacity over 245 mAh/g and stable cycle performance in the voltage range of 4.8 -2.0 V. On the other hand, XANES analysis shows that the oxidation state of Ni ion reversibly changes between Ni2+ and about Ni3+, while the oxidation state of Mn ion sustains Mn4+ during charge-discharge process. This result does not agree with the previously reported ‘electrochemistry model’ of Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2, in which Ni ion changes between Ni2+ and NI4+. Based on these results, we modified oxidation-state change of Mn and Ni ion during charge-discharge process. 相似文献
78.
We generalize several results on bounded analytic interpolation of Fitzgerald and Horn, which work by majorization by positive
definite kernels, to the cases of several complex variables and operator-valued interpolation. Using a lemma of Kolmogorov,
we complement a simplification due to Szafraniec in the proofs of the theorems.
Received: November 21, 2006. Accepted: August 03, 2007. 相似文献
79.
Joseph Majdalani Sjoerd W. Rienstra 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2007,58(2):289-308
The bidirectional vortex refers to the bipolar, coaxial swirling motion that can be triggered, for example, in cyclone separators
and some liquid rocket engines with tangential aft-end injectors. In this study, we present an exact solution to describe
the corresponding bulk motion in spherical coordinates. To do so, we examine both linear and nonlinear solutions of the momentum
and vorticity transport equations in spherical coordinates. The assumption will be that of steady, incompressible, inviscid,
rotational, and axisymmetric flow. We further relate the vorticity to some power of the stream function. At the outset, three
possible types of similarity solutions are shown to fulfill the momentum equation. While the first type is incapable of satisfying
the conditions for the bidirectional vortex, it can be used to accommodate other physical settings such as Hill’s vortex.
This case is illustrated in the context of inviscid flow over a sphere. The second leads to a closed-form analytical expression
that satisfies the boundary conditions for the bidirectional vortex in a straight cylinder. The third type is more general
and provides multiple solutions. The spherical bidirectional vortex is derived using separation of variables and the method
of variation of parameters. The three-pronged analysis presented here increases our repertoire of general mean flow solutions
that rarely appear in spherical geometry. It is hoped that these special forms will permit extending the current approach
to other complex fluid motions that are easier to capture using spherical coordinates. 相似文献
80.
A subgroup H of a finite group G is said to have the semi cover-avoiding property in G if there is a normal series of G such that H covers or avoids every normal factor of the series. In this paper, some new results are obtained based on the assumption that some subgroups have the semi cover-avoiding property in the group. 相似文献