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951.
952.
Vyacheslav Ya. Sosnovskikh Boris I. Usachev Mikhail I. Kodess 《Tetrahedron letters》2004,45(39):7351-7354
Reactions of chromones with dilithiooximes proceed via nucleophilic 1,2-addition to give, on acidification, 4H-chromene-4-spiro-5′-isoxazoline derivatives in high yields. On treatment with concentrated H2SO4 the isoxazoline ring of this novel spiroannulated heterocyclic system opens to give α,β-unsaturated oximes, which undergo nitrosation, bromination, and the Beckmann rearrangement to the corresponding spiroisoxazolines and α,β-unsaturated amides, respectively. The latter can be obtained directly by the Beckmann rearrangement of 4H-chromene-4-spiro-5′-isoxazolines. 相似文献
953.
954.
报道了四种不同P/Pd摩尔比的膦化聚2,6-二甲基1,4-苯醚负载把催化剂的加氢和异构化性能;通过XPS、电镜和远红外对催化剂进行了表征;并考察了溶剂和温度对催化剂活性的影响. 相似文献
955.
Two ferrates, K2FeO4 and BaFeO4, had been prepared and characterized by XRD, IR and SEM. The electrochemical tests of the samples were carried out in the voltage range of 0.8~2.0 V and current density of 0.5~3.0 mA·cm-2. The results indicated that performance of Zn-BaFeO4 battery was superior to that of Zn-MnO2 and Zn-K2FeO4 batteries. Nanometer SrTiO3 prepared by Sol-gel methode with different ratio was added to the BaFeO4 cathode in order to improve the discharge performance. The discharge capacity of the BaFeO4 cathode was increased from 224 mAh·g-1 to 246 mAh·g-1 by addition of 5% nanometer SrTiO3. The reason of enhancing BaFeO4 electrochemical performance was discussed. 相似文献
956.
Wanxing Wei Yuanjiang Pan Yaozu Chen Cuiwu Lin Tengyou Wei Shukai Zhao 《Chemistry of Natural Compounds》2005,41(1):17-21
Five compounds, terephthalic acid mono-[2-(4-carboxy-phenoxycarbonyl)-vinyl] ester (1), (E)-3-(5′-hydroperoxy-2,2′-dihydroxy[1,1′-biphenyl]-4-yl)-2-propenoic acid (2), 3,4,5-trihydroxybenzoic acid (3), succinic acid (or butanedioic acid) (4), and 2,3,4,5,6-pentahydroxybenzoic acid (5), were isolated from Phyllanthus urinaria. The structures of these compounds were elucidated by means of spectral techniques including IR, MS, and 1D/2D NMR. 1 and 2 are new compounds.__________Published in Khimiya Prirodnykh Soedinenii, No. 1, pp. 14–17, January–February, 2005. 相似文献
957.
The dependence of the frequency factor on the temperature (A=A
0
T
m) has been examined and the errors involved in the activation energy calculated from some integral methods without considering
such dependence have been estimated. Investigated integral methods are the Coats-Redfern method, the Gorbachev-Lee-Beck method,
the Wanjun-Yuwen method and the Junmeng-Fusheng method. The results have shown that the error in the determination of the
activation energy calculated ignoring the dependence of the frequency factor on the temperature can be rather large and it
is dependent on x=E/RT and the exponent m. 相似文献
958.
Zhengbin Zhang Liansheng Liu Hongbin Zhao Youjun Fu Fengyun Cheng Weihong Zhao 《中国科学B辑(英文版)》1997,40(4):353-364
A new method for the study of ternary surface complexes at liquid-solid interface, theE(%) -pH curve method, was proposed. Four types ofE(%)-pH curves, namely, phenomenon of left-right shifts of S-shaped curve, V-shaped curve, monodirection shift curve and X-shaped
curve, were discovered. Correspondingly, apart from type (I) ternary surface complex
and type (II) ternary surface complex
, a new type of ternary surface complex
was discovered.
Project supported by the National Natural Science Foundation of China and the Fund of Doctoral Degree’s Spot. 相似文献
959.
报道了8个2,4-二氨基-5-取代苄基嘧啶衍生物的电子轰击质谱及碰撞活化解离和质量分析离子动能谱.该谱提供了化合物醚键及2,4-二氨基-5-取代苄基嘧啶环的主要碎裂途径,总结了一些裂解规律,将有助于这类化合物的结构推断。 相似文献
960.
Akihiko Kanazawa Tomiki Ikeda Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》1993,31(2):335-343
Various polymeric phosphonium salts and the corresponding low-molecular-weight model compounds were prepared and their antibacterial activities against Staphylococcus aureus and Escherichia coli were explored by the viable cell counting method in sterile distilled water. Antibacterial activity of the polymers was found to be higher than that of the corresponding model compounds, particularly against S. aureus. Furthermore, the polymeric phosphonium salt exhibited a higher activity by 2 orders of magnitude than the polymeric quaternary ammonium salt with the same structure except the cationic part. Compounds with the longest alkyl chain (octyl) studied were found to exhibit particularly high activity, and this finding may be ascribed to the contribution of the increased hydrophobicity of the compounds to the cidal activity. © 1993 John Wiley & Sons, Inc. 相似文献