全文获取类型
收费全文 | 32314篇 |
免费 | 2251篇 |
国内免费 | 5020篇 |
专业分类
化学 | 26871篇 |
晶体学 | 548篇 |
力学 | 193篇 |
综合类 | 289篇 |
数学 | 6956篇 |
物理学 | 4728篇 |
出版年
2024年 | 50篇 |
2023年 | 323篇 |
2022年 | 705篇 |
2021年 | 649篇 |
2020年 | 801篇 |
2019年 | 1773篇 |
2018年 | 924篇 |
2017年 | 1718篇 |
2016年 | 1066篇 |
2015年 | 938篇 |
2014年 | 1255篇 |
2013年 | 2737篇 |
2012年 | 1840篇 |
2011年 | 2055篇 |
2010年 | 1557篇 |
2009年 | 1960篇 |
2008年 | 2145篇 |
2007年 | 2093篇 |
2006年 | 2031篇 |
2005年 | 1755篇 |
2004年 | 1710篇 |
2003年 | 1385篇 |
2002年 | 1203篇 |
2001年 | 1020篇 |
2000年 | 982篇 |
1999年 | 768篇 |
1998年 | 711篇 |
1997年 | 586篇 |
1996年 | 472篇 |
1995年 | 452篇 |
1994年 | 322篇 |
1993年 | 287篇 |
1992年 | 279篇 |
1991年 | 198篇 |
1990年 | 125篇 |
1989年 | 115篇 |
1988年 | 96篇 |
1987年 | 56篇 |
1986年 | 49篇 |
1985年 | 62篇 |
1984年 | 49篇 |
1983年 | 23篇 |
1982年 | 51篇 |
1981年 | 45篇 |
1980年 | 26篇 |
1979年 | 45篇 |
1978年 | 19篇 |
1977年 | 20篇 |
1976年 | 16篇 |
1975年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
201.
S. Sarkar A. D. Thakur C. V. Tomy G. Balakrishnan D. McK Paul S. Ramakrishnan A. K. Grover 《Pramana》2006,66(1):193-207
New experimental data are presented on the scan rate dependence of the magnetization hysteresis width ΔM(H) (∞ critical current densityJ
c(H)) in isothermalMH scans in a weakly pinned single crystal of Ca3Rh4Sn13, which displays second magnetization peak (SMP) anomaly as distinct from the peak effect (PE). We observe an interesting
modulation in the field dependence of a parameter which purports to measure the dynamical annealing of the disordered bundles
of vortices injected through the sample edges towards the destined equilibrium vortex state at a givenH. These data, in conjunction with the earlier observations made while studying the thermomagnetic history dependence inJ
c(H) in the tracing of the minor hysteresis loops, imply that the partially disordered state heals towards the more ordered state
between the peak field of the SMP anomaly and the onset field of the PE. The vortex phase diagram in the given crystal of
Ca3Rh4Sn13 has been updated in the context of the notion of the phase coexistence of the ordered and disordered regions between the
onset field of the SMP anomaly and the spinodal line located just prior to the irreversibility line. A multi-critical point
and a critical point in the (H,T) region of the Bragg glass phase have been marked in this phase diagram and the observed behavior is discussed in the light
of recent data on multi-critical point in the vortex phase diagram in a single crystal of Nb. 相似文献
202.
203.
V. I. Saloutin I. T. Bazyl' Z. E. Skryabina P. N. Kondrat'ev O. N. Chupakhin 《Russian Chemical Bulletin》1994,43(2):279-282
Reactions of pentafluorobenzoylpyruvic acid with amines afford the respective enamines. The intramolecular cyclization of the latter results inN-substituted 4-quinolone-2-carboxylic acids. Ammonia and triethylamine favor the cyclization of pentafluorobenzoylpyruvic acid to 2-carboxychromone.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 299–302, February, 1994. 相似文献
204.
Maria Carmelita Kasuya 《Journal of fluorine chemistry》2007,128(5):562-565
A series of fluorinated galactosides, dodecyl 2-deoxy-2-fluoro-β-d-galactopyranoside (2F Gal), dodecyl 4-deoxy-4-fluoro-β-d-galactopyranoside (4F Gal) and dodecyl 6-deoxy-6-fluoro-β-d-galactopyranoside (6F Gal), was chemically synthesized and introduced to B16 cells to serve as scaffolds for cellular enzyme glycosylation. Results showed that the presence of fluorine exercised significant effects on cell viability. Among the fluorinated galactosides used, 2F Gal was glycosylated to afford a GM4 analogue. 相似文献
205.
R. Souzy B. Ameduri B. Boutevin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(20):5077-5097
The radical co‐ and terpolymerization of 4‐[(α,β,β‐trifluorovinyl)oxy]bromo benzene (TFVOBB) with 1,1‐difluoroethylene (or vinylidene fluoride, VDF, or VF2), hexafluoropropene (HFP), perfluoromethyl vinyl ether (PMVE), and chlorotrifluroroethylene (CTFE) is presented. Although TFVOBB could be thermocyclodimerized, it could not homopolymerize under radical initiation. TFVOBB could be copolymerized in solution under a radical initiator with VDF or CTFE comonomers, while its copolymerization with HFP or PMVE were unsuccessful. The terpolymerization of TFVOBB with VDF and HFP, or VDF and PMVE, or VDF and CTFE also led to original fluorinated terpolymers bearing bromoaromatic side‐groups. The conditions of co‐ and terpolymerization were optimized in terms of the nature of the radical initiators, and of the nature of solvents (fluorinated or nonhalogenated). Various monomer concentrations in the co‐ and terpolymers were assessed by 19F and 1H‐NMR spectroscopy. The thermal and physico chemical properties were also studied. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5077–5097, 2004 相似文献
206.
207.
208.
We prove that if T is a tournament of order n > 6 in which any 4-sub-tournament is hamiltonian or transitive, then T is reconstructible in the sense of Ulam. 相似文献
209.
A. S. Peregudov L. N. Usatova E. I. Smyslova E. I. Fedin D. N. Kravtsov 《Russian Chemical Bulletin》1995,44(8):1513-1519
It has been shown by the19F NMR method that the relative polarities of nitrogenelement bonds in 2-(4-fluorophenyl)benzimidazole and its PhHg and PPh3Au derivatives increase in the order N-H19F NMR. It has been found that these reactions occur by a bimolecular associative mechanism and that the N-H bond is substantially less reactive than the N-Hg and N-Au bonds, which have identical reactivities within the limits of sensitivity of the method used.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1574–1580, August, 1995.This work was carried out with financial support from the Russian Foundation for Basic Research (Project No. 93-03-5528). 相似文献
210.
Lingsheng Shi 《Journal of Graph Theory》2005,50(3):175-185
The Ramsey number R(G1,G2) of two graphs G1 and G2 is the least integer p so that either a graph G of order p contains a copy of G1 or its complement Gc contains a copy of G2. In 1973, Burr and Erd?s offered a total of $25 for settling the conjecture that there is a constant c = c(d) so that R(G,G)≤ c|V(G)| for all d‐degenerate graphs G, i.e., the Ramsey numbers grow linearly for d‐degenerate graphs. We show in this paper that the Ramsey numbers grow linearly for degenerate graphs versus some sparser graphs, arrangeable graphs, and crowns for example. This implies that the Ramsey numbers grow linearly for degenerate graphs versus graphs with bounded maximum degree, planar graphs, or graphs without containing any topological minor of a fixed clique, etc. © 2005 Wiley Periodicals, Inc. J Graph Theory 相似文献