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101.
V. N. Sorokoumov S. N. Morozkina I. A. Balova 《Chemistry of Heterocyclic Compounds》2006,42(5):615-624
An investigation of the reaction of 1-lithio-1,3-diynes, generated in situ, with nitriles has been carried out. In the case
of aromatic nitriles 1-arylalk-1-ene-3,5-diynylamines are formed, which undergo dimerization and cyclization on isolation,
giving 3-(alka-1,3-diynyl)-4-(alk-2-ynyl)-2,6-diarylpyridines. The effect of the nature of the substituent in the benzonitrile
molecule on the selectivity of the reaction and the yield of the products has been determined. A scheme is proposed for the
conversions and the structures of the intermediates have been established.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 701–710, May, 2006. 相似文献
102.
Active flow-separation control is an effective and efficient mean for drag reduction and unsteady load alleviation resulting
from locally or massively separated flow. Such a situation occurs in configurations where the aerodynamic performance is of
secondary importance to functionality. The performance of heavy transport helicopters and aeroplanes, having a large, and
almost flat, aft loading ramp suffer from the poor aerodynamics of the aft body. Hence, a combined experimental and numerical
investigation was undertaken on a generic transport aeroplane/helicopter configuration. The experimental study provided surface
pressures, direct drag measurements, surface and smoke flow visualization. The baseline flow was numerically analyzed, using
finite volume solutions of the RANS equations. The baseline flow around the model was insensitive to the Reynolds number in
the range it was tested. The flow separating from the aft body was characterized by two main sources of drag and unsteadiness.
The first is a separation bubble residing at the lower ramp corner and the second is a pair of vortex systems developing and
separating from the sides of the ramp. As the model incidence is decreased, the pair of vortex systems also penetrates deeper
towards the centerline of the ramp, decreasing the pressure and increasing the drag. As expected, the ramp lower corner bubble
was highly receptive to periodic excitation introduced from four addressable piezo-fluidic actuators situated at the ramp
lower corner. Total drag was reduced by 3–11%, depending on the model incidence. There are indications that the flow in the
wake of the model is also significantly steadier when the bubble at the lower ramp corner is eliminated. The vortex system
is tighter and steadier when the ramp-corner bubble is eliminated. 相似文献
103.
Specific molecules in cardiac tissue of spontaneously hypertensive rats are studied by using time-of-flight secondary ion mass spectrometry (TOF-SIMS). The investigation determines phospholipids, cholesterol, fatty acids and their fragments in the cardiac tissue, with special focus on cardiolipin. Cardiolipin is a unique phospholipid typical for cardiomyocyte mitochondrial membrane and its decrease is involved in pathologic conditions. In the positive polarity, the fragments of phosphatydilcholine are observed in the mass region of 700-850 u. Peaks over mass 1400 u correspond to intact and cationized molecules of cardiolipin. In animal tissue, cardiolipin contains of almost exclusively 18 carbon fatty acids, mostly linoleic acid. Linoleic acid at 279 u, other fatty acids, and phosphatidylglycerol fragments, as precursors of cardiolipin synthesis, are identified in the negative polarity. These data demonstrate that SIMS technique along with Au3+ cluster primary ion beam is a good tool for detection of higher mass biomolecules providing approximately 10 times higher yield in comparison with Au+. 相似文献
104.
A. A. Maleev 《Computational Mathematics and Mathematical Physics》2006,46(12):2031-2039
Stationary and nonstationary Jacobi-like iterative processes for solving systems of linear algebraic equations are examined. For a system whose coefficient matrix A is an H-matrix, it is shown that the convergence rate of any Jacobi-like process is at least as high as that of the point Jacobi method as applied to a system with 〈A〉 as the coefficient matrix, where 〈A〉 is a comparison matrix of A. 相似文献
105.
A new sample business survey for agriculture, the REA survey, and a project of integration with the FADN network (RICA in
Italy) have significantly changed the production of statistical information nowadays available with reference to the agricultural
sector. On the basis of this relevant information, new economic analyses are being developed on farms’ performance, agricultural
households’ income and the Common Agricultural Policy (CAP). In this paper the authors estimate the relationship between the
levels of variables of interest and their sampling errors using models in order to improve the accessibility of the information
on estimates accuracy to the final users (agricultural analysts, policy makers).
The paper is the result of a joint research of the three authors. Sections 1–3 and 6 by Pizzoli, Sects. 4 and 5 by Rondinelli,
Sect. 7 by Filiberti, conclusions joint to the three authors. 相似文献
106.
We prove a conjecture by F. Ferrari. Let X be the total space of a nonlinear deformation of a rank two holomorphic vector bundle on a smooth rational curve, such that X has trivial canonical bundle and has sections. Then the normal bundle to such sections is computed in terms of the rank of the Hessian of a suitably defined superpotential at its critical points. 相似文献
107.
We present a framework for extending Stone's representation theorem for distributive lattices to representation theorems for distributive lattices with operators. We proceed by introducing the definition of algebraic theory of operators over distributive lattices. Each such theory induces a functor on the category of distributive lattices such that its algebras are exactly the distributive lattices with operators in the original theory. We characterize the topological counterpart of these algebras in terms of suitable coalgebras on spectral spaces. We work out some of these coalgebraic representations, including a new representation theorem for distributive lattices with monotone operators. 相似文献
108.
In the present paper, a Lotka–Volterra type mutualism system with several delays is studied. Some new and interesting sufficient conditions are obtained for the global existence of positive periodic solutions of the mutualism system. Our method is based on Mawhin’s coincidence degree and novel estimation techniques for the a priori bounds of unknown solutions. Our results are different from the existing ones such as those in of Yang et al. [F. Yang, D. Jiang, A. Ying, Existence of positive solution of multidelays facultative mutualism system, J. Eng. Math. 3 (2002) 64–68] and Chen et al. [F. Chen, J. Shi, X. Chen, Periodicity in a Lotka–Volterra facultative mutualism system with several delays, J. Eng. Math. 21 (3) (2004) 403–409]. 相似文献
109.
Maria Mamalui Chien-Yueh Huang 《Physica E: Low-dimensional Systems and Nanostructures》2004,22(4):912-920
We present the theoretical study of the effect of external random field characterized by a Gaussian probability distribution function on the continuous phonon spectrum of one-dimensional (1D) chain, based on the Jacobian matrix method. The cumulative effect of the random field and simple isotopic defect is studied analytically and numerically. The Gaussian random field removes a square-root divergence appearing in the phonon spectrum of ideal 1D chain. The impurity phonon DOS shows strong dependence on the variance and the mean of the random field and exhibits very different behavior from the non-random case: the continuous spectrum is expanded and the δ-peak, describing discrete impurity vibrations in the non-random chain with the impurity, falls into a continuous zone. 相似文献
110.
We give counterexamples to the following conjecture of Auslander: given a finitely generated module M over an Artin algebra Λ, there exists a positive integer nM such that for all finitely generated Λ-modules N, if ExtΛi(M,N)=0 for all i?0, then ExtΛi(M,N)=0 for all i?nM. Some of our examples moreover yield homologically defined classes of commutative local rings strictly between the class of local complete intersections and the class of local Gorenstein rings. 相似文献