Vanishing structure set of 3-manifolds

In this short note we update a result proved in Roushon (2007) [17]. This will complete our program of Roushon (2000) [13] showing that the structure set vanishes for compact aspherical 3-manifolds.     

Correlation between proton transfer and 35Cl NQR frequency as well as molecular geometry of chloranilic acid in co‐crystals with some organic bases

Proton transfer in hydrogen‐bonded organic co‐crystals of chloranilic acid with some organic bases was investigated by nuclear quadrupole resonance (NQR) spectroscopy. The ³⁵Cl NQR frequencies of chloranilic acid molecule as well as ¹⁴N NQR frequencies of the organic base molecule were measured with the conventional pulse methods as well as double‐resonance methods, respectively. The extent of proton transfer in the O···H···N hydrogen bond was estimated from Townes–Dailey analysis of the ¹⁴N NQR parameters. The ³⁵Cl NQR frequency and molecular geometry of chloranilic acid are correlated to the extent of proton transfer in the protonation process of the organic base molecule. It is shown that the hydrogen bond affects the π‐electron system of chloranilic acid. Geometry dependence of the O···H···N hydrogen bond, i.e. the H? N valence bond order versus the hydrogen‐bond geometry correlation is also discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

Approach theory meets probability theory

In this paper we reconsider the basic topological and metric structures on spaces of probability measures and random variables, such as e.g. the weak topology and the total variation metric, replacing them with more intrinsic and richer approach structures. We comprehensibly investigate the relationships among, and basic facts about these structures, and prove that fundamental results, such as e.g. the portmanteau theorem and Prokhorov?s theorem, can be recaptured in a considerably stronger form in the new setting.     

Stitching pairs of Lévy processes into harnesses

We consider natural exponential families of Lévy processes with randomized parameter. Such processes are Markov, and under suitable assumptions, pairs of such processes with shared randomization can be “stitched together” into a single harness. The stitching consists of deterministic reparametrization of the time for both processes, so that they run on adjacent time intervals, and of the choice of the appropriate law at the boundary.     

NON-EXISTENCE OF A COGENERATOR FOR ORDERED VECTOR SPACES

Abstract

See title.     

Estimation of isotropic nuclear magnetic shieldings in the CCSD(T) and MP2 complete basis set limit using affordable correlation calculations

A linear correlation between isotropic nuclear magnetic shielding constants for seven model molecules (CH₂O, H₂O, HF, F₂, HCN, SiH₄ and H₂S) calculated with 37 methods (34 density functionals, RHF, MP2 and CCSD(T)), with affordable pcS‐2 basis set and corresponding complete basis set results, estimated from calculations with the family of polarization‐consistent pcS‐n basis sets is reported. This dependence was also supported by inspection of profiles of deviation between CBS estimated nuclear shieldings and shieldings obtained with the significantly smaller basis sets pcS‐2 and aug‐cc‐pVTZ‐J for the selected set of 37 calculation methods. It was possible to formulate a practical approach of estimating the values of isotropic nuclear magnetic shielding constants at the CCSD(T)/CBS and MP2/CBS levels from affordable CCSD(T)/pcS‐2, MP2/pcS‐2 and DFT/CBS calculations with pcS‐n basis sets. The proposed method leads to a fairly accurate estimation of nuclear magnetic shieldings and considerable saving of computational efforts. Copyright © 2013 John Wiley & Sons, Ltd.     

Gain of regularity for semilinear Schrödinger equations

We discuss local existence and gain of regularity for semilinear Schr?dinger equations which generally cause loss of derivatives. We prove our results by advanced energy estimates. More precisely, block diagonalization and Doi's transformation, together with symbol smoothing for pseudodifferential operators with nonsmooth coefficients, apply to systems of Schr?dinger-type equations. In particular, the sharp G?rding inequality for pseudodifferential operators whose coefficients are twice continuously differentiable, plays a crucial role in our proof. Received: 14 December 1998     

SOME OF MY FAVORITE SOLVED AND UNSOLVED PROBLEMS IN GRAPH THEORY

Abstract

During my long life I published many papers with related titles. To keep this paper short I will not give proofs and will restrict myself to problems in graph theory, but I will try to give references and make these as complete as possible.

I will start with Turk type problems in extremal graph theory.     

A generalization of gamma functions and Kronecker's limit formulas

We obtain a “Kronecker limit formula” for the Epstein zeta function. This is done by introducing a generalized gamma function attached to the Epstein zeta function. The methods involve generalizing ideas of Shintani and Stark. We first show that a generalized gamma function appears as the value at s=0 of the first derivative of the associated Epstein zeta function. Then this is used to yield Kronecker's limit formula and its “s=0”-version.     

The rank of the covariance matrix of an evanescent field

Evanescent random fields arise as a component of the 2D Wold decomposition of homogeneous random fields. Besides their theoretical importance, evanescent random fields have a number of practical applications, such as in modeling the observed signal in the space-time adaptive processing (STAP) of airborne radar data. In this paper we derive an expression for the rank of the low-rank covariance matrix of a finite dimension sample from an evanescent random field. It is shown that the rank of this covariance matrix is completely determined by the evanescent field spectral support parameters, alone. Thus, the problem of estimating the rank lends itself to a solution that avoids the need to estimate the rank from the sample covariance matrix. We show that this result can be immediately applied to considerably simplify the estimation of the rank of the interference covariance matrix in the STAP problem.