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991.
ABSTRACT High-resolution emission spectrum of the 1–4 band of the B 2Σ+–X 2Σ+ transition of 14C16O+ was observed for the first time by conventional emission spectroscopy. The band spectrum was excited in a water-cooled Geissler lamp filled with commercial gaseous carbon monoxide enriched in about 80% of the radiocarbon 14C. A rotational analysis has been carried out and obtained molecular constants have been merged with previously published data for the B 2Σ+–A 2Πi and A 2Πi–X 2Σ+ transitions. The principal equilibrium constants for the ground X 2Σ+ state obtained from this work are ωe = 2121.7726(98), ωe x e = 13.9055(27), B e = 1.815290(30), αe = 1.6594(33) × 10?2, and γe = ? 0.377(73) × 10?4 cm?1. Also, presently known experimental equilibrium molecular constants of the X 2Σ+ states of the CO+ isotopic molecules are summarized and isotopic dependence of the B e and ω e constants is discussed. 相似文献
992.
Sonia Stita Marta Galera Martínez Huynh Pham Xuan Ange Nzihou Patrick Sharrock 《Composite Interfaces》2013,20(6):503-515
With the expansion of human activities, there are more and more living areas adjacent to industrial and/or agricultural activities such as chemical processes, petroleum processes, paint finishing, food processing, livestock farming, composting plants etc. Bad odor is part of several nuisances caused by industrial and/or agricultural activities. Hydrogen sulfide (H2S) is a typical odorous molecule which causes foul odor at very low concentration. This molecule is formed in different industrial installations, in particular in coal combustion, and petrochemical refinery. The separation and/or transformation of H2S from gas phase to odorless products are important processes for sustainable development. In this paper, we communicate the preparation of new sorbents for the sorption of H2S from a synthetic gas effluent. These sorbents consist in an inorganic phase (hydroxyapatite) as host particles, and well-dispersed particles of a metal oxide as guest particles which are the active phase for the removal of H2S. At room conditions, iron, lead, and zinc doped calcium phosphates were found to be effective for the removal of H2S. The performance of the sorbents depends on preparation method and the nature of active phases. This opens new prospects for the treatment of H2S from gas phase. 相似文献
993.
Himadri Kumar Mukerjee 《Topology and its Applications》2006,153(18):3467-3495
Complete PL and topological classification and partial smooth classification of manifolds homotopy equivalent to a Wall's manifold (defined as a mapping torus of a Dold manifold), introduced by Wall in his 1960 Annals paper on cobordism, have been done by determining: (1) the normal invariants of Wall's manifolds, (2) the surgery obstruction of a normal invariant and (3) the action of the Wall surgery obstruction groups on the smooth, PL and homeomorphism classes of homotopy Wall's manifolds (to be made precise in the body of the paper). Consequently classification results of automorphisms (self homeomorphisms, and self PL-homeomorphisms) of Dold manifolds follow. 相似文献
994.
995.
A synthesized cyclometalated palladium-azo complex was explored as a multifunctional probe for visual detection of SO2, H2S and NH3 in water. In acidic aqueous environment, the sensing solution underwent a sharp color change from poor violet to deep blue when titrated with Na2SO3 standard solution. But the color changed from poor violet to bright yellow when titrated with Na2S standard solution. In basic environment, the sensing solution rapidly changed to magenta when titrated by NH4Cl-NH3 standard buffer solution at high concentration. However, the color of sensing solution changed to blue when titrated by NH4Cl-NH3 standard buffer solution at low concentration although the pH was kept constant during the titration. Different species of these hazardous gases at environmentally relevant concentration levels were differentiated by independent optical signal outputs, and the interference from other inorganic ions commonly existing in water was very small. 相似文献
996.
Amine Asselah Fabienne Castell 《Annales de l'Institut Henri Poincaré (B) Probabilités et Statistiques》2007,43(2):163
We consider a random walk in random scenery {Xn=η(S0)+?+η(Sn),n∈N}, where a centered walk {Sn,n∈N} is independent of the scenery {η(x),x∈Zd}, consisting of symmetric i.i.d. with tail distribution P(η(x)>t)∼exp(−cαtα), with 1?α<d/2. We study the probability, when averaged over both randomness, that {Xn>ny} for y>0, and n large. In this note, we show that the large deviation estimate is of order exp(−ca(ny)), with a=α/(α+1). 相似文献
997.
998.
999.
单模光纤陀螺正交锁相检测方法的研究 总被引:3,自引:0,他引:3
研究了用于干涉型单模光纤陀螺系统的正交锁相检测方法,采用双参考信号,使输出的信号与噪声分离,不仅提高了光学系统信号的信噪比,同时可以引入移相反馈控制,大大减小了系统的漂移,系统的零点漂移已达到0.2deg/h。 相似文献
1000.
We explore the consequences of certain commutativity hypotheses on a single nilpotent element or the set N of all nilpotent elements. We give several sufficient conditions for N to be an ideal. We present some nontrivial examples, including an example in which N is commutative (in fact, N
2 = {0}) and N is not an ideal.
Received: April 27, 2006. Revised: July 31, 2006. 相似文献