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91.
催化荧光法测定痕量草酸 总被引:3,自引:0,他引:3
在硫酸介质中 ,草酸能催化重铬酸钾氧化罗丹明B褪色 ,使体系荧光猝灭 ,建立了催化荧光法测定草酸的新方法。催化反应在 50℃水浴中进行 1 0min ,为假零级反应。测定草酸的线性范围为 0 4~ 1 2 0mg·L- 1 ,其回归方程为ΔF =8 42c(mg·L- 1 ) 3 81 ,r=0 9983 ,检出限为 0 1 6mg·L- 1 。试验了 30种共存物质的干扰情况。此法用于生物样品中草酸含量的测定 ,结果满意。 相似文献
92.
Fan Chung 《Annals of Combinatorics》2005,9(1):1-19
We consider Laplacians for directed graphs and examine their eigenvalues. We introduce a notion of a circulation in a directed graph and its connection with the Rayleigh quotient. We then define a Cheeger constant and establish the Cheeger inequality for directed graphs. These relations can be used to deal with various problems that often arise in the study of non-reversible Markov chains including bounding the rate of convergence and deriving comparison theorems.Received September 8, 2004 相似文献
93.
Lanthanum modified lead titanate (PLT) thin films are one of the potential candidates for the pyroelectric and memory applications due to their excellent dielectric, pyroelectric and ferroelectric properties. PLT thin films with 25 at.% of La were deposited on platinum coated Si substrates by the laser ablation technique. The phase transition studies were done in the temperature range of −40 to 150 °C as a function of frequency and ac field. A diffused phase transition with the shifting of the maximum dielectric permittivity (?max) to higher temperatures with the increase of frequency and dielectric dispersion with frequency at the lower temperatures were observed. The variation of the temperature corresponding to maximum dielectric constant Tm, with frequency follows the Vogel-Fulcher relation, which is the characteristic of the relaxor-like behavior of the material. With the increase of ac drive, the Tmax was shifted to lower value. 相似文献
94.
Bi12TiO20纳米粉体的制备及其光吸收特性研究 总被引:3,自引:0,他引:3
以钛酸四丁酯和硝酸铋为原料 ,利用化学溶液分解法制备了Bi12 TiO2 0 纳米多晶粉体 .采用XRD和TEM对其结构和形貌进行了表征 .结合热重 差热 (TG DTA)分析 ,探讨了Bi12 TiO2 0 晶相的形成机理 .通过UV Vis漫反射谱的测定 ,研究了Bi12 TiO2 0 纳米晶粉体的光吸收特性 .结果显示 ,从组成为化学计量比的前驱液中可以很容易制得纯Bi12 TiO2 0 纳米晶粉体 ,该Bi12 TiO2 0 纳米晶粉体呈现了在很宽的波长范围内 (5 6 0~ 385nm )对光的吸收的特性 . 相似文献
95.
Yong-Gao Chen 《Journal of Number Theory》2003,98(2):310-319
In this paper we prove that if (r,12)?3, then the set of positive odd integers k such that kr−2n has at least two distinct prime factors for all positive integers n contains an infinite arithmetic progression. The same result corresponding to kr2n+1 is also true. 相似文献
96.
97.
Matthew D. Horton 《Linear algebra and its applications》2007,425(1):130-142
After defining and exploring some of the properties of Ihara zeta functions of digraphs, we improve upon Kotani and Sunada’s bounds on the poles of Ihara zeta functions of undirected graphs by considering digraphs whose adjacency matrices are directed edge matrices. 相似文献
98.
A conjecture of Toft [17] asserts that any 4-critical graph (or equivalently, every 4-chromatic graph) contains a fully odd subdivision ofK
4. We show that if a graphG has a degree three nodev such thatG-v is 3-colourable, then eitherG is 3-colourable or it contains a fully oddK
4. This resolves Toft's conjecture in the special case where a 4-critical graph has a degree three node, which is in turn used to prove the conjecture for line-graphs. The proof is constructive and yields a polynomial algorithm which given a 3-degenerate graph either finds a 3-colouring or exhibits a subgraph that is a fully odd subdivision ofK
4. (A graph is 3-degenerate if every subgraph has some node of degree at most three.) 相似文献
99.
We generalize several results on bounded analytic interpolation of Fitzgerald and Horn, which work by majorization by positive
definite kernels, to the cases of several complex variables and operator-valued interpolation. Using a lemma of Kolmogorov,
we complement a simplification due to Szafraniec in the proofs of the theorems.
Received: November 21, 2006. Accepted: August 03, 2007. 相似文献
100.
Joseph Majdalani Sjoerd W. Rienstra 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2007,58(2):289-308
The bidirectional vortex refers to the bipolar, coaxial swirling motion that can be triggered, for example, in cyclone separators
and some liquid rocket engines with tangential aft-end injectors. In this study, we present an exact solution to describe
the corresponding bulk motion in spherical coordinates. To do so, we examine both linear and nonlinear solutions of the momentum
and vorticity transport equations in spherical coordinates. The assumption will be that of steady, incompressible, inviscid,
rotational, and axisymmetric flow. We further relate the vorticity to some power of the stream function. At the outset, three
possible types of similarity solutions are shown to fulfill the momentum equation. While the first type is incapable of satisfying
the conditions for the bidirectional vortex, it can be used to accommodate other physical settings such as Hill’s vortex.
This case is illustrated in the context of inviscid flow over a sphere. The second leads to a closed-form analytical expression
that satisfies the boundary conditions for the bidirectional vortex in a straight cylinder. The third type is more general
and provides multiple solutions. The spherical bidirectional vortex is derived using separation of variables and the method
of variation of parameters. The three-pronged analysis presented here increases our repertoire of general mean flow solutions
that rarely appear in spherical geometry. It is hoped that these special forms will permit extending the current approach
to other complex fluid motions that are easier to capture using spherical coordinates. 相似文献